One-Pot Process for Hydrodeoxygenation of Lignin to Alkanes Using Ru-Based Bimetallic and Bifunctional Catalysts Supported on Zeolite Y

Wang, Hongliang; Ruan, Hao; Feng, Maoqi; Qin, Yuling; Job, Heather; Luo, Langli; Wang, Chongmin; Engelhard, Mark H.; Kuhn, Erik; Chen, Xiaowen; Tucker, Melvin P.; Yang, Bin

doi:10.1002/cssc.201700160

Title: One-Pot Process for Hydrodeoxygenation of Lignin to Alkanes Using Ru-Based Bimetallic and Bifunctional Catalysts Supported on Zeolite Y

Journal Article · Thu Mar 16 00:00:00 EDT 2017 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201700160· OSTI ID:1361984

Wang, Hongliang ^[1]; Ruan, Hao ^[1]; Feng, Maoqi ^[2]; Qin, Yuling ^[1]; Job, Heather ^[3]; Luo, Langli ^[4]; Wang, Chongmin ^[4]; Engelhard, Mark H. ^[4]; Kuhn, Erik ^[5]; Chen, Xiaowen ^[5]; Tucker, Melvin P. ^[5];

^[1]

Department of Biological Systems Engineering, Washington State University, Richland WA 99354 USA
Chemistry & Chemical Engineering Division, Southwest Research Institute, San Antonio TX 78238 USA
Pacific Northwest National Laboratory, 902 Battelle Blvd Richland WA 99354 USA
Environmental Molecular Sciences Laboratory, 3335 Q Ave Richland WA 99354 USA
National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway Golden CO. 80401 USA

The synthesis of high-efficiency and low-cost multifunctional catalysts for hydrodeoxygenation (HDO) of waste lignin into advanced biofuels is crucial for enhancing current biorefinery processes. Inexpensive transition metals, including Fe, Ni, Cu, Zn, were severally co-loaded with Ru on HY zeolite to form bimetallic and bifunctional catalysts. These catalysts were subsequently tested for HDO conversion of softwood lignin and several lignin model compounds. Results indicated that the inexpensive earth abundant metals could modulate the hydrogenolysis activity of Ru and decrease the yield of low molecular weight gaseous side-products. Among all the prepared catalysts, Ru-Cu/HY showed the best HDO performance, giving the highest selectivity to hydrocarbon products. The improved catalytic performance of Ru-Cu/HY was probably due to the following three factors: (1) high total and strong acid sites, (2) good dispersion of metal species and limited segregation, (3) high adsorption capacity for polar fractions, including hydroxyl groups and ether bonds. Moreover, all the bifunctional catalysts were proven to be superior over the combination catalysts of Ru/Al2O3 and HY zeolite, and this could be attributed to the “intimacy criterion”. The practical use of the designed catalysts would be promising in lignin valorization.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1361984

Report Number(s):: PNNL-SA-120890; 48379; KP1704020

Journal Information:: ChemSusChem, Vol. 10, Issue 8; ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

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