Surface transport processes in charged porous media

Gabitto, Jorge; Tsouris, Costas

doi:10.1016/j.jcis.2017.03.009

Title: Surface transport processes in charged porous media

Journal Article · Fri Mar 03 00:00:00 EST 2017 · Journal of Colloid and Interface Science

DOI:https://doi.org/10.1016/j.jcis.2017.03.009· OSTI ID:1361353

Gabitto, Jorge ^[1]; Tsouris, Costas ^[2]

Prairie View A&M Univ., Prairie View, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Surface transport processes are important in chemistry, colloidal sciences, engineering, biology, and geophysics. Natural or externally produced charges on surfaces create electrical double layers (EDLs) at the solid-liquid interface. The existence of the EDLs produces several complex processes including bulk and surface transport of ions. In this work, a model is presented to simulate bulk and transport processes in homogeneous porous media comprising big pores. It is based on a theory for capacitive charging by ideally polarizable porous electrodes without Faradaic reactions or specific adsorption of ions. A volume averaging technique is used to derive the averaged transport equations in the limit of thin electrical double layers. Description of the EDL between the electrolyte solution and the charged wall is accomplished using the Gouy-Chapman-Stern (GCS) model. The surface transport terms enter into the average equations due to the use of boundary conditions for diffuse interfaces. Two extra surface transports terms appear in the closed average equations. One is a surface diffusion term equivalent to the transport process in non-charged porous media. The second surface transport term is a migration term unique to charged porous media. The effective bulk and transport parameters for isotropic porous media are calculated solving the corresponding closure problems.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725; AC05-0096OR22725

OSTI ID:: 1361353

Alternate ID(s):: OSTI ID: 1415308

Journal Information:: Journal of Colloid and Interface Science, Vol. 498, Issue C; ISSN 0021-9797

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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