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Metal-organic frameworks for adsorption and separation of noble gases

Patent ·
OSTI ID:1360970

A method including exposing a gas mixture comprising a noble gas to a metal organic framework (MOF), including an organic electron donor and an adsorbent bed operable to adsorb a noble gas from a mixture of gases, the adsorbent bed including a metal organic framework (MOF) including an organic electron donor.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation
Patent Number(s):
9,662,632
Application Number:
14/662,098
OSTI ID:
1360970
Country of Publication:
United States
Language:
English

References (30)

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VUV spectroscopy of luminescent materials for plasma display panels and Xe discharge lamps journal July 2001
Growth and properties of alumina films obtained by low-pressure metal–organic chemical vapor deposition journal November 2001
Heat-transfer correlations for natural convection boiling journal January 1980
Metal–Organic Framework Materials as Chemical Sensors journal September 2011
Synthesis and Characterization of a Porous Magnetic Diamond Framework, Co3(HCOO)6, and Its N2 Sorption Characteristic journal March 2005
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis journal September 2011
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks journal August 2011
Using molecular simulation to characterise metal–organic frameworks for adsorption applications journal January 2009
Identification of Metal–Organic Framework Materials for Adsorption Separation of Rare Gases: Applicability of Ideal Adsorbed Solution Theory (IAST) and Effects of Inaccessible Framework Regions
  • Van Heest, Timothy; Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13183-13195 https://doi.org/10.1021/jp302808j
journal June 2012
Connecting structure with function in metal–organic frameworks to design novel photo- and radioluminescent materials journal January 2012
The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases journal January 2014
Metal–organic framework materials as catalysts journal January 2009
Excimers and excimer lasers journal February 1980
Enantioselective catalysis with homochiral metal–organic frameworks journal January 2009
Metal–Organic Frameworks in Biomedicine journal September 2011
Liquid phase separations by crystalline microporous coordination polymers journal January 2010
Capacitive and barrier discharge excilamps and their applications (Review) journal October 2006
Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks journal September 2011
Hydrogen storage in metal–organic frameworks journal January 2009
Scintillating Metal-Organic Frameworks: A New Class of Radiation Detection Materials journal January 2009
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? journal August 2012
Metal–Organic Frameworks for Separations journal September 2011
Nanoporous metal formates for krypton/xenon separation journal January 2013
High power ultrafast excimer lasers journal January 1991
Switching Kr/Xe Selectivity with Temperature in a Metal–Organic Framework
  • Fernandez, Carlos A.; Liu, Jian; Thallapally, Praveen K.
  • Journal of the American Chemical Society, Vol. 134, Issue 22, p. 9046-9049 https://doi.org/10.1021/ja302071t
journal May 2012
One teflon®-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties journal January 2005
A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions journal September 2011
Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and Three-Dimensional Magnetic Ordering journal August 2008

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