Solubility in the UO{sub 2}SeO{sub 4}-(CH{sub 3}){sub 2}NCONH{sub 2}-H{sub 2}O system
Journal Article
·
· Radiochemistry
OSTI ID:136024
Complexation in the UO{sub 2}SeO{sub 4}-(CH{sub 3}){sub 2}NCONH{sub 2}-H{sub 2}O system is studied by isothermal solubility at 25{degrees}C. Congruently soluble UO{sub 2}SeO{sub 4}{center_dot}2(CH{sub 3}){sub 2}NCONH{sub 2}{center_dot}2H{sub 2}O (I) is detected. The unit-cell constants of I found by a single-crystal X-ray diffraction study are a = 14.251, b = 13.896, c = 17.789 {angstrom}, {beta} = 104.74{degrees}, Z = 8, and space group P2{sub 1}/c. Compound I is a representative of the AT{sup 3}M{sub 2}{sup 1} crystal-chemical group of uranyl complexes.
- OSTI ID:
- 136024
- Journal Information:
- Radiochemistry, Journal Name: Radiochemistry Journal Issue: 5 Vol. 36; ISSN RDIOEO; ISSN 1066-3622
- Country of Publication:
- United States
- Language:
- English
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