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3D lattice distortions and defect structures in ion-implanted nano-crystals

Journal Article · · Scientific Reports
DOI:https://doi.org/10.1038/srep45993· OSTI ID:1349558
 [1];  [2];  [3];  [4];  [5];  [5];  [6];  [7];  [4];  [3]
  1. Univ. of Oxford (United Kingdom). Dept. of Engineering Science
  2. Univ. College, London (United Kingdom). London Centre for Nanotechnology; Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab. (RAL)
  3. Univ. of Oxford (United Kingdom). Dept. of Materials
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
  5. La Trobe Univ., Melbourne, VIC (Australia). ARC Centre of Advanced Molecular Imaging; CSIRO Manufacturing Flagship, CAN Parkville (Australia)
  6. SLAC National Accelerator Lab., Menlo Park, CA (United States); Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). Center for Free-Electron Laser Science
  7. La Trobe Univ., Melbourne, VIC (Australia). ARC Centre of Advanced Molecular Imaging
The ability of Focused Ion Beam (FIB) techniques to cut solid matter at the nano-scale revolutionized the study of material structure across the life-, earth- and material sciences. But a detailed understanding of the damage caused by the ion beam and its effect on material properties remains elusive. We examine this damage in 3D using coherent X-ray diffraction to measure the full lattice strain tensor in FIB-milled gold nano-crystals. We also found that even very low ion doses, previously thought to be negligible, cause substantial lattice distortions. At higher doses, extended self-organized defect structures appear. Combined with detailed numerical calculations, these observations allow fundamental insight into the nature of the damage created and the structural instabilities that lead to a surprisingly inhomogeneous morphology.
Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357; AC02-76SF00515
OSTI ID:
1349558
Alternate ID(s):
OSTI ID: 1360215
OSTI ID: 1390607
Report Number(s):
BNL--113662-2017-JA; KC0201060
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Vol. 7; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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