Comparison of the Morphology Development of Polymer-Fullerene and Polymer-Polymer Solar Cells during Solution-Shearing Blade Coating

Gu, Xiaodan; Yan, Hongping; Kurosawa, Tadanori; Schroeder, Bob C.; Gu, Kevin L.; Zhou, Yan; To, John W.  F.; Oosterhout, Stefan D.; Savikhin, Victoria; Molina-Lopez, Francisco; Tassone, Christopher J.; Mannsfeld, Stefan C.  B.; Wang, Cheng; Toney, Michael F.; Bao, Zhenan

doi:10.1002/aenm.201601225

Title: Comparison of the Morphology Development of Polymer-Fullerene and Polymer-Polymer Solar Cells during Solution-Shearing Blade Coating

Journal Article · Mon Aug 22 00:00:00 EDT 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201601225· OSTI ID:1360189

Gu, Xiaodan ^[1]; Yan, Hongping ^[2]; Kurosawa, Tadanori ^[3]; Schroeder, Bob C. ^[4]; Gu, Kevin L. ^[3]; Zhou, Yan ^[3]; To, John W. F. ^[3]; Oosterhout, Stefan D. ^[2]; Savikhin, Victoria ^[2]; Molina-Lopez, Francisco ^[3]; Tassone, Christopher J. ^[2]; Mannsfeld, Stefan C. B. ^[5]; Wang, Cheng ^[6]; Toney, Michael F. ^[2]; Bao, Zhenan ^[3]

Stanford Univ., CA (United States). Dept. of Chemical Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Stanford Univ., CA (United States). Dept. of Chemical Engineering
Stanford Univ., CA (United States). Dept. of Chemical Engineering; Queen Mary Univ. of London (United Kingdom). School of Biological and Chemical Sciences and Materials Research Inst.
Dresden Univ. of Technology (Germany). Center for Advancing Electronics Dresden
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

In this work, the detailed morphology studies of polymer poly(3-hexylthiophene-2,5-diyl) (P3HT):fullerene(PCBM) and polymer(P3HT):polymer naphthalene diimide thiophene (PNDIT) solar cell are presented to understand the challenge for getting high performance all-polymer solar cells. The in situ X-ray scattering and optical interferometry and ex situ hard and soft X-ray scattering and imaging techniques are used to characterize the bulk heterojunction (BHJ) ink during drying and in dried state. The crystallization of P3HT polymers in P3HT:PCBM bulk heterojunction shows very different behavior compared to that of P3HT:PNDIT BHJ due to different mobilities of P3HT in the donor:acceptor glass. Supplemented by the ex situ grazing incidence X-ray diffraction and soft X-ray scattering, PNDIT has a lower tendency to form a mixed phase with P3HT than PCBM, which may be the key to inhibit the donor polymer crystallization process, thus creating preferred small phase separation between the donor and acceptor polymer.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: AC02-76SF00515; AC02-05CH11231; 6932623

OSTI ID:: 1360189

Alternate ID(s):: OSTI ID: 1440001

Journal Information:: Advanced Energy Materials, Vol. 6, Issue 22; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 60 works

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References (77)

Crystallization-Induced 10-nm Structure Formation in P3HT/PCBM Blends Kohn, Peter; Rong, Zhuxia; Scherer, Kai H. Macromolecules, Vol. 46, Issue 10 https://doi.org/10.1021/ma400403c	journal	April 2013
Resonant soft X-ray scattering for polymer materials Liu, Feng; Brady, Michael A.; Wang, Cheng European Polymer Journal, Vol. 81 https://doi.org/10.1016/j.eurpolymj.2016.04.014	journal	August 2016
On the Glass Transition of Polymer Semiconductors and Its Impact on Polymer Solar Cell Stability Müller, Christian Chemistry of Materials, Vol. 27, Issue 8 https://doi.org/10.1021/acs.chemmater.5b00024	journal	March 2015
Fast Printing and In Situ Morphology Observation of Organic Photovoltaics Using Slot-Die Coating Liu, Feng; Ferdous, Sunzida; Schaible, Eric Advanced Materials, Vol. 27, Issue 5 https://doi.org/10.1002/adma.201404040	journal	December 2014
Compact Roll-to-Roll Coater for in Situ X-ray Diffraction Characterization of Organic Electronics Printing Gu, Xiaodan; Reinspach, Julia; Worfolk, Brian J. ACS Applied Materials & Interfaces, Vol. 8, Issue 3 https://doi.org/10.1021/acsami.5b09174	journal	January 2016
Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells Choi, Joonhyeong; Kim, Ki-Hyun; Yu, Hojeong Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b01274	journal	July 2015
Fast charge separation in a non-fullerene organic solar cell with a small driving force Liu, Jing; Chen, Shangshang; Qian, Deping Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.89	journal	June 2016
Miscibility, Crystallinity, and Phase Development in P3HT/PCBM Solar Cells: Toward an Enlightened Understanding of Device Morphology and Stability Collins, Brian A.; Tumbleston, John R.; Ade, Harald The Journal of Physical Chemistry Letters, Vol. 2, Issue 24 https://doi.org/10.1021/jz2014902	journal	November 2011
A High-Mobility Electron-Transport Polymer with Broad Absorption and Its Use in Field-Effect Transistors and All-Polymer Solar Cells Zhan, Xiaowei; Tan, Zhan'ao; Domercq, Benoit Journal of the American Chemical Society, Vol. 129, Issue 23, p. 7246-7247 https://doi.org/10.1021/ja071760d	journal	June 2007
Controlling the Field-Effect Mobility of Regioregular Polythiophene by Changing the Molecular Weight Kline, R. J.; McGehee, M. D.; Kadnikova, E. N. Advanced Materials, Vol. 15, Issue 18 https://doi.org/10.1002/adma.200305275	journal	September 2003
Some unique features of polymer crystallisation Reiter, Günter Chem. Soc. Rev., Vol. 43, Issue 7 https://doi.org/10.1039/C3CS60306G	journal	January 2014
Following the Morphology Formation In Situ in Printed Active Layers for Organic Solar Cells Pröller, Stephan; Liu, Feng; Zhu, Chenhui Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501580	journal	October 2015
Fluoro-Substituted n-Type Conjugated Polymers for Additive-Free All-Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71% Jung, Jae Woong; Jo, Jea Woong; Chueh, Chu-Chen Advanced Materials, Vol. 27, Issue 21 https://doi.org/10.1002/adma.201501214	journal	April 2015
Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis Gann, E.; Young, A. T.; Collins, B. A. Review of Scientific Instruments, Vol. 83, Issue 4 https://doi.org/10.1063/1.3701831	journal	April 2012
All-Polymer Solar Cells from Perylene Diimide Based Copolymers: Material Design and Phase Separation Control Zhou, Erjun; Cong, Junzi; Wei, Qingshuo Angewandte Chemie International Edition, Vol. 50, Issue 12, p. 2799-2803 https://doi.org/10.1002/anie.201005408	journal	February 2011
High-performance ternary blend all-polymer solar cells with complementary absorption bands from visible to near-infrared wavelengths Benten, Hiroaki; Nishida, Takaya; Mori, Daisuke Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE03460D	journal	January 2016
Nanomorphology of Bulk Heterojunction Photovoltaic Thin Films Probed with Resonant Soft X-ray Scattering Swaraj, Sufal; Wang, Cheng; Yan, Hongping Nano Letters, Vol. 10, Issue 8 https://doi.org/10.1021/nl1009266	journal	August 2010
Look fast: Crystallization of conjugated molecules during solution shearing probed in-situ and in real time by X-ray scattering Smilgies, Detlef-M.; Li, Ruipeng; Giri, Gaurav physica status solidi (RRL) - Rapid Research Letters, Vol. 7, Issue 3 https://doi.org/10.1002/pssr.201206507	journal	December 2012
The glass transition in thin polymer films Forrest, James A.; Dalnoki-Veress, Kari Advances in Colloid and Interface Science, Vol. 94, Issue 1-3 https://doi.org/10.1016/S0001-8686(01)00060-4	journal	November 2001
A general relationship between disorder, aggregation and charge transport in conjugated polymers Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen Nature Materials, Vol. 12, Issue 11 https://doi.org/10.1038/nmat3722	journal	August 2013
Real-time X-ray scattering studies of film evolution in high performing small-molecule–fullerene organic solar cells Engmann, Sebastian; Bokel, Felicia A.; Herzing, Andrew A. Journal of Materials Chemistry A, Vol. 3, Issue 16 https://doi.org/10.1039/C5TA00935A	journal	January 2015
The Scherrer Formula for X-Ray Particle Size Determination Patterson, A. L. Physical Review, Vol. 56, Issue 10 https://doi.org/10.1103/PhysRev.56.978	journal	November 1939
Effect of Photovoltaic Polymer/Fullerene Blend Composition Ratio on Microstructure Evolution during Film Solidification Investigated in Real Time by X-ray Diffraction Sanyal, Monamie; Schmidt-Hansberg, Benjamin; Klein, Michael F. G. Macromolecules, Vol. 44, Issue 10 https://doi.org/10.1021/ma2000338	journal	May 2011
Determination of Solvent–Polymer and Polymer–Polymer Flory–Huggins Interaction Parameters for Poly(3-hexylthiophene) via Solvent Vapor Swelling Emerson, Jillian A.; Toolan, Daniel T. W.; Howse, Jonathan R. Macromolecules, Vol. 46, Issue 16 https://doi.org/10.1021/ma400597j	journal	August 2013
In Situ Morphology Studies of the Mechanism for Solution Additive Effects on the Formation of Bulk Heterojunction Films Richter, Lee J.; DeLongchamp, Dean M.; Bokel, Felicia A. Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400975	journal	September 2014
Morphology Development in Amorphous Polymer:Fullerene Photovoltaic Blend Films During Solution Casting Pearson, Andrew J.; Wang, Tao; Dunbar, Alan D. F. Advanced Functional Materials, Vol. 24, Issue 5 https://doi.org/10.1002/adfm.201301922	journal	October 2013
P3HT/PCBM Bulk Heterojunction Organic Photovoltaics: Correlating Efficiency and Morphology Chen, Dian; Nakahara, Atsuhiro; Wei, Dongguang Nano Letters, Vol. 11, Issue 2, p. 561-567 https://doi.org/10.1021/nl103482n	journal	February 2011
Green-Solvent-Processed All-Polymer Solar Cells Containing a Perylene Diimide-Based Acceptor with an Efficiency over 6.5% Li, Sunsun; Zhang, Hao; Zhao, Wenchao Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501991	journal	December 2015
Efficient organic solar cells processed from hydrocarbon solvents Zhao, Jingbo; Li, Yunke; Yang, Guofang Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.27	journal	January 2016
All-Polymer Solar Cell with High Near-Infrared Response Based on a Naphthodithiophene Diimide (NDTI) Copolymer Zhou, Erjun; Nakano, Masahiro; Izawa, Seiichiro ACS Macro Letters, Vol. 3, Issue 9 https://doi.org/10.1021/mz5004272	journal	August 2014
Influence of Aggregation on the Performance of All-Polymer Solar Cells Containing Low-Bandgap Naphthalenediimide Copolymers Schubert, Marcel; Dolfen, Daniel; Frisch, Johannes Advanced Energy Materials, Vol. 2, Issue 3 https://doi.org/10.1002/aenm.201100601	journal	January 2012
In Situ X-Ray Study of Drying-Temperature Influence on the Structural Evolution of Bulk-Heterojunction Polymer-Fullerene Solar Cells Processed by Doctor-Blading Sanyal, Monamie; Schmidt-Hansberg, Benjamin; Klein, Michael F. G. Advanced Energy Materials, Vol. 1, Issue 3 https://doi.org/10.1002/aenm.201100007	journal	April 2011
Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight Fox, Thomas G.; Flory, Paul J. Journal of Applied Physics, Vol. 21, Issue 6 https://doi.org/10.1063/1.1699711	journal	June 1950
Spin-Cast Bulk Heterojunction Solar Cells: A Dynamical Investigation Chou, Kang Wei; Yan, Buyi; Li, Ruipeng Advanced Materials, Vol. 25, Issue 13 https://doi.org/10.1002/adma.201203440	journal	February 2013
High Performance All-Polymer Solar Cell via Polymer Side-Chain Engineering Zhou, Yan; Kurosawa, Tadanori; Ma, Wei Advanced Materials, Vol. 26, Issue 22 https://doi.org/10.1002/adma.201306242	journal	March 2014
A real-time study of the benefits of co-solvents in polymer solar cell processing van Franeker, Jacobus J.; Turbiez, Mathieu; Li, Weiwei Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7229	journal	February 2015
Nature of the Glass Transition and the Glassy State Gibbs, Julian H.; DiMarzio, Edmund A. The Journal of Chemical Physics, Vol. 28, Issue 3 https://doi.org/10.1063/1.1744141	journal	March 1958
Correlating the Efficiency and Nanomorphology of Polymer Blend Solar Cells Utilizing Resonant Soft X-ray Scattering Yan, Hongping; Collins, Brian A.; Gann, Eliot ACS Nano, Vol. 6, Issue 1 https://doi.org/10.1021/nn204150f	journal	December 2011
Viscosity and glass temperature relations for polymer-diluent systems Kelley, Frank N.; Bueche, F. Journal of Polymer Science, Vol. 50, Issue 154 https://doi.org/10.1002/pol.1961.1205015421	journal	April 1961
In situ measurement of power conversion efficiency and molecular ordering during thermal annealing in P3HT:PCBM bulk heterojunction solar cells Treat, Neil D.; Shuttle, Chris G.; Toney, Michael F. Journal of Materials Chemistry, Vol. 21, Issue 39 https://doi.org/10.1039/c1jm12677f	journal	January 2011
All-Polymer Solar Cells with 3.3% Efficiency Based on Naphthalene Diimide-Selenophene Copolymer Acceptor Earmme, Taeshik; Hwang, Ye-Jin; Murari, Nishit M. Journal of the American Chemical Society, Vol. 135, Issue 40, p. 14960-14963 https://doi.org/10.1021/ja4085429	journal	September 2013
Subnanosecond Geminate Charge Recombination in Polymer-Polymer Photovoltaic Devices Hodgkiss, Justin M.; Campbell, Andrew R.; Marsh, R. Alex Physical Review Letters, Vol. 104, Issue 17 https://doi.org/10.1103/PhysRevLett.104.177701	journal	April 2010
Polymer Blend Solar Cells Based on a High-Mobility Naphthalenediimide-Based Polymer Acceptor: Device Physics, Photophysics and Morphology Moore, Jennifer R.; Albert-Seifried, Sebastian; Rao, Akshay Advanced Energy Materials, Vol. 1, Issue 2 https://doi.org/10.1002/aenm.201000035	journal	February 2011
Quantitative Determination of Organic Semiconductor Microstructure from the Molecular to Device Scale Rivnay, Jonathan; Mannsfeld, Stefan C. B.; Miller, Chad E. Chemical Reviews, Vol. 112, Issue 10 https://doi.org/10.1021/cr3001109	journal	June 2012
Rationalizing Phase Transitions with Thermal Annealing Temperatures for P3HT:PCBM Organic Photovoltaic Devices Pearson, Andrew J.; Wang, Tao; Jones, Richard A. L. Macromolecules, Vol. 45, Issue 3 https://doi.org/10.1021/ma202063k	journal	January 2012
Polarized X-ray scattering reveals non-crystalline orientational ordering in organic films Collins, B. A.; Cochran, J. E.; Yan, H. Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3310	journal	April 2012
Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7% Mori, Daisuke; Benten, Hiroaki; Okada, Izumi Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01326C	journal	January 2014
All-Polymer Solar Cells Based on Absorption-Complementary Polymer Donor and Acceptor with High Power Conversion Efficiency of 8.27% Gao, Liang; Zhang, Zhi-Guo; Xue, Lingwei Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504629	journal	December 2015
Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology Zhao, Jun; Swinnen, Ann; Van Assche, Guy The Journal of Physical Chemistry B, Vol. 113, Issue 6, p. 1587-1591 https://doi.org/10.1021/jp804151a	journal	February 2009
Time-Resolved Structural Evolution of Additive-Processed Bulk Heterojunction Solar Cells Rogers, James T.; Schmidt, Kristin; Toney, Michael F. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja2104747	journal	February 2012
Characterization of the morphology of solution-processed bulk heterojunction organic photovoltaics Liu, Feng; Gu, Yu; Shen, Xiaobo Progress in Polymer Science, Vol. 38, Issue 12 https://doi.org/10.1016/j.progpolymsci.2013.07.010	journal	December 2013
Non-Conjugated Flexible Linkers in Semiconducting Polymers: A Pathway to Improved Processability without Compromising Device Performance Schroeder, Bob C.; Chiu, Yu-Cheng; Gu, Xiaodan Advanced Electronic Materials, Vol. 2, Issue 7 https://doi.org/10.1002/aelm.201600104	journal	May 2016
A Phase Diagram of the P3HT:PCBM Organic Photovoltaic System: Implications for Device Processing and Performance Hopkinson, Paul E.; Staniec, Paul A.; Pearson, Andrew J. Macromolecules, Vol. 44, Issue 8 https://doi.org/10.1021/ma102524a	journal	April 2011
In Situ Characterization of Polymer–Fullerene Bilayer Stability Leman, Deborah; Kelly, Mary Allison; Ness, Stuart Macromolecules, Vol. 48, Issue 2 https://doi.org/10.1021/ma5021227	journal	January 2015
Pronounced Cosolvent Effects in Polymer:Polymer Bulk Heterojunction Solar Cells with Sulfur-Rich Electron-Donating and Imide-Containing Electron-Accepting Polymers Nam, Sungho; Woo, Sungho; Seo, Jooyeok ACS Applied Materials & Interfaces, Vol. 7, Issue 29 https://doi.org/10.1021/acsami.5b04224	journal	July 2015
Stability of organic solar cells: challenges and strategies Cheng, Pei; Zhan, Xiaowei Chemical Society Reviews, Vol. 45, Issue 9 https://doi.org/10.1039/C5CS00593K	journal	January 2016
Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells Zhou, Nanjia; Lin, Hui; Lou, Sylvia J. Advanced Energy Materials, Vol. 4, Issue 3 https://doi.org/10.1002/aenm.201300785	journal	October 2013
High-Performance All-Polymer Solar Cells Based on Face-On Stacked Polymer Blends with Low Interfacial Tension Kang, Hyunbum; Kim, Ki-Hyun; Choi, Joonhyeong ACS Macro Letters, Vol. 3, Issue 10 https://doi.org/10.1021/mz500415a	journal	September 2014
Morphology characterization in organic and hybrid solar cells Chen, Wei; Nikiforov, Maxim P.; Darling, Seth B. Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee22056c	journal	January 2012
Effects of Thermal Annealing Upon the Morphology of Polymer-Fullerene Blends Verploegen, Eric; Mondal, Rajib; Bettinger, Christopher J. Advanced Functional Materials, Vol. 20, Issue 20 https://doi.org/10.1002/adfm.201000975	journal	August 2010
Effect of temperature on the morphological and photovoltaic stability of bulk heterojunction polymer:fullerene solar cells Bertho, Sabine; Janssen, Griet; Cleij, Thomas J. Solar Energy Materials and Solar Cells, Vol. 92, Issue 7, p. 753-760 https://doi.org/10.1016/j.solmat.2008.01.006	journal	July 2008
Interdiffusion of PCBM and P3HT Reveals Miscibility in a Photovoltaically Active Blend Treat, Neil D.; Brady, Michael A.; Smith, Gordon Advanced Energy Materials, Vol. 1, Issue 1, p. 82-89 https://doi.org/10.1002/aenm.201000023	journal	November 2010
Role of photoactive layer morphology in high fill factor all-polymer bulk heterojunction solar cells Fabiano, S.; Chen, Z.; Vahedi, S. Journal of Materials Chemistry, Vol. 21, Issue 16 https://doi.org/10.1039/c0jm03405c	journal	January 2011
7.7% Efficient All-Polymer Solar Cells Hwang, Ye-Jin; Courtright, Brett A. E.; Ferreira, Amy S. Advanced Materials, Vol. 27, Issue 31 https://doi.org/10.1002/adma.201501604	journal	July 2015
Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability Zhao, Wenchao; Qian, Deping; Zhang, Shaoqing Advanced Materials, Vol. 28, Issue 23 https://doi.org/10.1002/adma.201600281	journal	April 2016
High-Performance All-Polymer Solar Cells Via Side-Chain Engineering of the Polymer Acceptor: The Importance of the Polymer Packing Structure and the Nanoscale Blend Morphology Lee, Changyeon; Kang, Hyunbum; Lee, Wonho Advanced Materials, Vol. 27, Issue 15 https://doi.org/10.1002/adma.201405226	journal	March 2015
Tuning charge transport in solution-sheared organic semiconductors using lattice strain Giri, Gaurav; Verploegen, Eric; Mannsfeld, Stefan C. B. Nature, Vol. 480, Issue 7378, p. 504-508 https://doi.org/10.1038/nature10683	journal	December 2011
Fullerenecrystallisation as a key driver of charge separation in polymer/fullerene bulk heterojunction solar cells Jamieson, Fiona C.; Domingo, Ester Buchaca; McCarthy-Ward, Thomas Chem. Sci., Vol. 3, Issue 2, p. 485-492 https://doi.org/10.1039/C1SC00674F	journal	January 2012
Polymer donor–polymer acceptor (all-polymer) solar cells Facchetti, Antonio Materials Today, Vol. 16, Issue 4 https://doi.org/10.1016/j.mattod.2013.04.005	journal	April 2013
Beyond Langevin Recombination: How Equilibrium Between Free Carriers and Charge Transfer States Determines the Open-Circuit Voltage of Organic Solar Cells Burke, Timothy M.; Sweetnam, Sean; Vandewal, Koen Advanced Energy Materials, Vol. 5, Issue 11 https://doi.org/10.1002/aenm.201500123	journal	April 2015
A New Model for the Morphology of P3HT/PCBM Organic Photovoltaics from Small-Angle Neutron Scattering: Rivers and Streams Yin, Wen; Dadmun, Mark ACS Nano, Vol. 5, Issue 6, p. 4756-4768 https://doi.org/10.1021/nn200744q	journal	May 2011
Moving through the Phase Diagram: Morphology Formation in Solution Cast Polymer–Fullerene Blend Films for Organic Solar Cells Schmidt-Hansberg, Benjamin; Sanyal, Monamie; Klein, Michael F. G. ACS Nano, Vol. 5, Issue 11 https://doi.org/10.1021/nn2036279	journal	October 2011
Effect of Solution Shearing Method on Packing and Disorder of Organic Semiconductor Polymers Giri, Gaurav; DeLongchamp, Dean M.; Reinspach, Julia Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/cm503780u	journal	March 2015
Charge Generation Dynamics in Efficient All-Polymer Solar Cells: Influence of Polymer Packing and Morphology Gautam, Bhoj R.; Lee, Changyeon; Younts, Robert ACS Applied Materials & Interfaces, Vol. 7, Issue 50 https://doi.org/10.1021/acsami.5b08531	journal	December 2015
One-dimensional self-confinement promotes polymorph selection in large-area organic semiconductor thin films Giri, Gaurav; Li, Ruipeng; Smilgies, Detlef-M Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4573	journal	April 2014
Bulk Heterojunction Solar Cells: Morphology and Performance Relationships Huang, Ye; Kramer, Edward J.; Heeger, Alan J. Chemical Reviews, Vol. 114, Issue 14 https://doi.org/10.1021/cr400353v	journal	May 2014
Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure He, Zhicai; Zhong, Chengmei; Su, Shijian Nature Photonics, Vol. 6, Issue 9, p. 591-595 https://doi.org/10.1038/nphoton.2012.190	journal	August 2012

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Benzodithiophene-modified terpolymer acceptors with reduced molecular planarity and crystallinity: improved performance and stability for all-polymer solar cells Gao, Xuyu; Gao, Jiaxin; Xue, Zhongyuan Journal of Materials Chemistry C, Vol. 7, Issue 33 https://doi.org/10.1039/c9tc03142a	journal	January 2019
Optimization of processing solvent and film morphology to achieve efficient non-fullerene polymer solar cells processed in air An, Kang; Zhong, Wenkai; Ying, Lei Journal of Materials Chemistry C, Vol. 8, Issue 1 https://doi.org/10.1039/c9tc05358a	journal	January 2020
In Situ Structure Characterization in Slot‐Die‐Printed All‐Polymer Solar Cells with Efficiency Over 9% Zhong, Wenkai; Hu, Qin; Jiang, Yufeng Solar RRL, Vol. 3, Issue 7 https://doi.org/10.1002/solr.201970073	journal	May 2019
Bulk Heterojunction Morphologies with Atomistic Resolution from Coarse-Grain Solvent Evaporation Simulations Alessandri, Riccardo; Uusitalo, Jaakko J.; de Vries, Alex H. Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.6b11717	journal	March 2017

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