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Title: High-Selectivity Electrochemical Conversion of CO 2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode

Abstract

Carbon dioxide is a pollutant, but also a potential carbon source provided an efficient means to convert it to useful products. Herein we report a nanostructured catalyst for the direct electrochemical reduction of dissolved CO 2 to ethanol with high Faradaic efficiency (63%) and high selectivity (84%). The catalyst is comprised of Cu nanoparticle on a highly textured, N-doped graphene film. Detailed electrochemical analysis and complementary DFT calculations indicate a novel mechanism in which multiple active sites, working sequentially, control the coupling of carbon monoxide radicals and mediate the subsequent electrochemical reduction to alcohol.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [3];  [1];  [1];  [4];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) ; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Computer Science and Mathematics Division
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1360018
Grant/Contract Number:
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemistry Select
Additional Journal Information:
Journal Volume: 1; Journal Issue: 19; Journal ID: ISSN 2365-6549
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalyst; carbon dioxide; CO2; ethanol; reduction

Citation Formats

Song, Yang, Peng, Rui, Hensley, Dale K., Bonnesen, Peter V., Liang, Liangbo, Wu, Zili, Meyer, Harry M., Chi, Miaofang, Ma, Cheng, Sumpter, Bobby G., and Rondinone, Adam J.. High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode. United States: N. p., 2016. Web. doi:10.1002/slct.201601169.
Song, Yang, Peng, Rui, Hensley, Dale K., Bonnesen, Peter V., Liang, Liangbo, Wu, Zili, Meyer, Harry M., Chi, Miaofang, Ma, Cheng, Sumpter, Bobby G., & Rondinone, Adam J.. High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode. United States. doi:10.1002/slct.201601169.
Song, Yang, Peng, Rui, Hensley, Dale K., Bonnesen, Peter V., Liang, Liangbo, Wu, Zili, Meyer, Harry M., Chi, Miaofang, Ma, Cheng, Sumpter, Bobby G., and Rondinone, Adam J.. Wed . "High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode". United States. doi:10.1002/slct.201601169. https://www.osti.gov/servlets/purl/1360018.
@article{osti_1360018,
title = {High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode},
author = {Song, Yang and Peng, Rui and Hensley, Dale K. and Bonnesen, Peter V. and Liang, Liangbo and Wu, Zili and Meyer, Harry M. and Chi, Miaofang and Ma, Cheng and Sumpter, Bobby G. and Rondinone, Adam J.},
abstractNote = {Carbon dioxide is a pollutant, but also a potential carbon source provided an efficient means to convert it to useful products. Herein we report a nanostructured catalyst for the direct electrochemical reduction of dissolved CO2 to ethanol with high Faradaic efficiency (63%) and high selectivity (84%). The catalyst is comprised of Cu nanoparticle on a highly textured, N-doped graphene film. Detailed electrochemical analysis and complementary DFT calculations indicate a novel mechanism in which multiple active sites, working sequentially, control the coupling of carbon monoxide radicals and mediate the subsequent electrochemical reduction to alcohol.},
doi = {10.1002/slct.201601169},
journal = {Chemistry Select},
number = 19,
volume = 1,
place = {United States},
year = {Wed Sep 28 00:00:00 EDT 2016},
month = {Wed Sep 28 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 25works
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