Sub-millisecond 125Te NMR spin-lattice relaxation times and large Knight shifts in complex tellurides: Validation of a quadratic relation across the spectrum
- Ames Lab., Ames, IA (United States). Division of Materials Sciences and Engineering
- Iowa State Univ., Ames, IA (United States). Department of Chemistry
125Te NMR spectra and spin-lattice relaxation times, T1, have been measured for several GeTe-based materials with Te excess. In this paper, the spectra show inhomogeneous broadening by several thousand ppm and a systematic variation in T1 relaxation time with resonance frequency. The quadratic dependence of the spin-lattice relaxation rate, 1/T1, on the Knight shift in the Korringa relation is found to be valid over a wide range of Knight shifts. This result confirms that T1 relaxation in GeTe-based materials is mostly dominated by hyperfine interaction between nuclei and free charge carriers. In GeTe with 2.5% excess of Te, about 15% of the material exhibits a Knight shift of ≥4500 ppm and a T1 of only 0.3 ms, indicating a high hole concentration that could correspond to close to 50% vacancies on the Ge sublattice in this component. Lastly, our findings provide a basis for determining the charge carrier concentration and its distribution in complex thermoelectric and phase-change tellurides, which should lead to a better understanding of electronic and thermal transport properties as well as chemical bonding in these materials.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- AC02-07CH11358
- OSTI ID:
- 1355399
- Alternate ID(s):
- OSTI ID: 1359893
- Report Number(s):
- IS-J-9110; PII: S0926204016300571
- Journal Information:
- Solid State Nuclear Magnetic Resonance, Vol. 78; ISSN 0926-2040
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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