Evaluation of Mn and Sn-Modified Pd-Ce-Based Catalysts for Low-Temperature Diesel Exhaust Oxidation

Wang, Chao; Binder, Andrew J.; Toops, Todd J.; Lauterbach, Jochen; Sasmaz, Erdem

doi:10.1007/s40825-016-0056-9

Evaluation of Mn and Sn-Modified Pd-Ce-Based Catalysts for Low-Temperature Diesel Exhaust Oxidation

Journal Article · Wed Dec 07 00:00:00 EST 2016 · Emission Control Science & Technology

DOI:https://doi.org/10.1007/s40825-016-0056-9· OSTI ID:1356945

Wang, Chao ^[1]; Binder, Andrew J. ^[2]; Toops, Todd J. ^[2]; Lauterbach, Jochen ^[1]; ^[1]

Univ. of South Carolina, Columbia, SC (United States). SmartState Center for Strategic Approaches to the Generation of Electricity (SAGE), Dept. of Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Fuels, Engines, and Emissions Research Center

Pd-impregnated Ce-based catalysts were tested for carbon monoxide (CO) and hydrocarbon (HC) oxidation under challenging low-temperature diesel combustion conditions. The results indicate that the light-off temperatures for CO over Pd/CeO₂, Pd/MnO_x-CeO₂ (Pd/MC), and Pd/SnO₂-MnO_x-CeO₂ (Pd/SMC) catalysts shift to higher temperatures in the presence of simulated diesel exhaust gas. The lowest T₅₀ for CO is observed over Pd/MC at 173 °C, whereas Pd/CeO₂ is shown to oxidize most of the HCs at temperatures below 400 °C. In all catalysts, the oxidation of HCs starts right after the onset of CO oxidation, revealing that the competitive adsorption of CO, NO, and alkenes controls the catalytic activity. Further evaluation of the catalytic activity in the presence of only CO and C₃H₆ reveals the immediate inhibiting effect of C₃H₆ at catalyst temperatures below 150 °C. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments performed over Pd/CeO₂, Pd/MC, and Pd/SMC show that C₃H₆ inhibits the formation of carbonyl species on Pdⁿ⁺ sites, which limits the catalytic activity for CO. Lastly, such inhibition is observed on all supports, implying that the activity is independent of oxygen storage capacity (OSC) or lattice oxygen reducibility of the supports in the presence of C₃H₆.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Fuels, Engines and Emissions Research Center; Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). National Transportation Research Center (NTRC)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1356945

Journal Information:: Emission Control Science & Technology, Journal Name: Emission Control Science & Technology Journal Issue: 1 Vol. 3; ISSN 2199-3629

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Bulk Versus Surface Modification of Alumina with Mn and Ce Based Oxides for CH4 Catalytic Combustion Neatu, Stefan; Trandafir, Mihaela M.; Stănoiu, Adelina Materials, Vol. 12, Issue 11 https://doi.org/10.3390/ma12111771	journal	May 2019
In situ spectroscopic investigation of a Pd local structure over Pd/CeO ₂ and Pd/MnO _x –CeO ₂ during CO oxidation Sasmaz, Erdem; Wang, Chao; Lance, Michael J. Journal of Materials Chemistry A, Vol. 5, Issue 25 https://doi.org/10.1039/c7ta00696a	journal	January 2017

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Evaluation of Mn and Sn-Modified Pd-Ce-Based Catalysts for Low-Temperature Diesel Exhaust Oxidation

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