Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Structural properties of scandium inorganic salts

Journal Article · · Coordination Chemistry Reviews
 [1];  [1]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Here, the structural properties of reported inorganic scandium (Sc) salts were reviewed, including the halide (Cl, Br, and I), nitrate, sulfate, and phosphate salts. Additional analytical techniques used for characterization of these complexes (metrical data, FTIR and 45Sc NMR spectroscopy) were tabulated. A structural comparison of Sc to select lanthanide (La, Gd, Lu) salt complexes was briefly evaluated.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1356829
Alternate ID(s):
OSTI ID: 1415244
Report Number(s):
SAND--2017-2794J; PII: S0010854516304441
Journal Information:
Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Journal Issue: C Vol. 340; ISSN 0010-8545
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (105)

Selten-Erd-Hydrogensulfate M(HSO4)3 (M = La, Ce-Nd): Derivate des UCl3-Typs journal October 1998
Perchlorato Complexes of Rare-Earth Elements: Syntheses and Crystal Structures of Lu(ClO4)3 · 3 H2O, Er(ClO4)3 · H2O, and Sc(OH)(ClO4)2 · H2O journal September 1999
Wasserfreie Sulfate der Selten-Erd-Elemente: Synthese und Kristallstruktur von Y2(SO4)3 und Sc2(SO4)3 journal June 2000
H3OLa(SO4)2 · 3 H2O: Ein neues saures Sulfat der Selten-Erd-Elemente journal July 2001
Anion Control over Interpenetration and Framework Topology in Coordination Networks Based on Homoleptic Six-Connected Scandium Nodes journal January 2005
Chemoselective Catalysis with Organosoluble Lewis Acidic Polyoxotungstates journal May 2010
Three Scandium Compounds with Unsaturated Coordinative Metal Sites - Structures and Catalysis: Three Scandium Compounds with Unsaturated Coordinative Metal Sites journal January 2015
Separation and purification of scandium by solvent extraction and related technologies: a review journal May 2011
Synthesis and structures of Sc7Cl12 and Zr6Cl15 journal August 1982
Struktur und thermisches Verhalten von Gadolinium(III)-sulfat-Octahydrat Gd2(SO4)3 � 8 H2O journal April 1993
A Missing Rare-Earth Oxide Halide Structure Now Observed For Scandium Oxide Iodide, ScOI journal October 2008
Crystal Structures and Magnetic Properties of Rare-Earth Ultraphosphates, RP5O14 (R=La, Nd, Sm, Eu, Gd) journal March 2000
Hydrothermal Synthesis and Crystal Structure of a Novel 3-D Porous Lanthanum Sulfate journal October 2006
Coordination Polymers of Scandium Sulfate. Crystal Structures of (H2Bipy)[Sc(H2O)(SO4)2]2 · 2H2O and (H2Bipy)[HSO4]2 journal August 2005
Sc(III), Eu(III), and Gd(III) Complexes with Macrocyclic Cavitand Cucurbit[6]uril: Synthesis and Crystal Structures journal November 2005
Supplemental Literature Review of Binary Phase Diagrams: Al-P, B-Ga, B-Nd, Ba-Ga, Bi-Cs, Ca-Ga, Cd-Gd, Cr-Mo, Gd-Ni, Ni-Pb, Ni-Sc, and Sc-Sn journal July 2015
The structure of Pr2(SO4)3 · 8H2O and La2(SO4)3 · 9H2O journal November 1976
Crystal structure of neodymium and gadolinium dihydroxy-nitrate, Ln(OH)2NO3 journal July 1986
The crystal structure of lanthanum metaphosphate LaP3O9 journal August 1988
Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design journal November 2002
Structural chemistry of Sc(III): an overview journal January 1999
Coordination geometry and structural determinations of SmPO4,EuPO4 and GdPO4 journal March 1985
Ninefold coordination LaPO4: Pentagonal interpenetrating tetrahedral polyhedron journal October 1984
Structural investigations of YPO4, ScPO4, and LuPO4 journal January 1982
A pentagonal bipyramidal scandium(III) complex: Synthesis and characterization of diaqua(2,6-diacetylpyridine bis-semicarbazone)scandium(III) hydroxide dinitrate journal January 1976
Homoleptic octahedral hexakis(trimethylphosphine oxide)lanthanide hexafluorophosphates, [Ln(Me3PO)6][PF6]3: journal January 2003
Preparation and structure of HGdP2O7·3H2O journal January 2001
Scandium, yttrium and lanthanum nitrate complexes of tertiary arsine oxides: synthesis and multinuclear spectroscopic studies. X-ray structures of [M(Me3AsO)6](NO3)3 (M=Sc or Y), [Sc(Ph3AsO)3(NO3)2]NO3, [M″(Ph3AsO)4(NO3)2]NO3 (M″=Y or La) and [La(Ph3AsO)2(EtOH)(NO3)3] journal September 2001
Scandium halide complexes of phosphine- and arsine-oxides: synthesis, structures and 45Sc NMR studies journal July 2002
Geometrical isomers of ScCl3(THF)x(H2O)3 − x: Isolation and crystal structure of the compound where x = 2 journal January 1997
Dehydration of scandium chloride hydrate: synthesis and molecular structures of ScCl3(η2-DME)(MeCN), ScCl3(diglyme) and [Sc2(μ-OH)2(H2O)10]Cl4·2H2O journal May 1999
Accuracy of ab initio methods in predicting the crystal structures of metals: A review of 80 binary alloys journal September 2005
Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands journal October 2008
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2014 journal January 2016
Metallurgical processes for scandium recovery from various resources: A review journal June 2011
Hydrothermal syntheses and crystal structures of two lanthanum compounds La(OH)SO 4 and LaO(NO 3 ) journal July 2004
Synthesis and structure of a dimeric scandium bis(μ-methoxy) complex journal July 2008
Hydrothermal synthesis and structure of organically templated chain, layered and framework scandium phosphates journal June 2005
Hydrothermal synthesis and crystal structure of a new inorganic/organic hybrid of scandium sulfate: (H2en)Sc2(SO4)4·(H2O)0.72 journal May 2006
The phase transition of the incommensurate phases , crystal structures of and journal July 2009
Reinvestigation of the GdP5O14 crystal structure at room temperature and magnetic properties journal April 2007
Synthesis, structure refinement and characterization of tetrahydrated acid gadolinium diphosphate HGdP2O7·4H2O journal December 2005
Growth, structural, IR and magnetic studies of a new gadolinium metaphosphate, Gd(PO3)3 journal November 2006
Synthesis, structure and luminescent properties of Lu(PO3)3 journal May 2008
Structural characterization of methanol substituted lanthanum halides journal May 2010
Hydrothermal Synthesis, Structure Determination, and Solid-State NMR Study of the First Organically Templated Scandium Phosphate journal May 2002
Hydrothermal Synthesis and Structural Characterization of Four Scandium Phosphate Frameworks journal October 2003
Synthesis and Structure Determination of a New Organically Templated Scandium Fluorophosphate Framework and Its Indium Analogue journal November 2004
The layered, metallic scandium iodide Sc0.93I2: synthesis, structure, and properties journal May 1990
Crystal Structures of Incommensurately Modulated Ln(PO 3 ) 3 (Ln = Tb−Yb) and Commensurate Gd(PO 3 ) 3 and Lu(PO 3 ) 3 journal April 2007
Effect of Inclining Strain on the Crystal Lattice along an Extended Series of Lanthanide Hydroxysulfates Ln(OH)SO 4 (Ln = Pr−Yb, except Pm) journal January 2011
[Sc 2 (μ-OH) 2 (H 2 O) 6 (NO 3 ) 2 ](NO 3 ) 2 : Aqueous Synthesis and Characterization journal January 2013
Metal-metal bonding in reduced scandium halides. Synthesis and crystal structure of scandium monochloride journal February 1977
Metal-metal bonding in reduced scandium halides. Synthesis and characterization of heptascandium decachloride (Sc7Cl10). A novel metal-chain structure journal May 1977
Correction. Metal-Metal Bonding in Reduced Scandium Halides. Synthesis and Characterization of Heptascandium Decachloride (Sc 7 Cl 10 ) journal August 1979
Crystal and molecular structure of the undecacoordinate complex pentaaquatris(nitrato)lanthanum(III) monohydrate journal May 1980
Investigation of the Structural Properties of an Extended Series of Lanthanide Bis-hydroxychlorides Ln(OH) 2 Cl (Ln = Nd−Lu, except Pm and Sm) journal May 2010
Cluster condensation reactions. Synthesis and structure of pentascandium octachloride (Sc5Cl8). An infinite chain structure derived by cluster condensation journal August 1978
Catalytic Asymmetric Hydroxymethylation of Silicon Enolates Using an Aqueous Solution of Formaldehyde with a Chiral Scandium Complex journal October 2004
Experimental and Theoretical Studies of 45 Sc NMR Interactions in Solids journal August 2006
Vibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium( iii ) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium( iii ) ion journal January 2004
A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate journal January 2006
Sc 2 (pydc) 2 unit based 1D, 2D and 3D metal–organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation journal January 2015
The complex chemistry of scandium. Part 1. Preparation and properties of some scandium( III ) complexes of polyamines. X-Ray crystal structures of tri(nitrato-OO′)(2,2′ : 6′,2″-terpyridyl-NN′N″)scandium( III ) and [1,2-bis(pyridine-α-carbaldimino)ethane-NN′N″N‴]-di-µ-hydroxo-di(nitrato-OO′)discandium( III ) dinitrate bis(acetonitrile) journal January 1984
Syntheses, structures and multinuclear NMR (45Sc, 89Y, 31P) studies of Ph3PO, Ph2MePO and Me3PO complexes of scandium and yttrium nitrates journal January 2000
A study of lanthanide complexes formed with the terdentate nitrogen ligand 4-amino-bis(2,6-(2-pyridyl))-1,3,5-triazine. Relevance to the separation of actinides and lanthanides by solvent extraction † journal January 2000
Primary and secondary coordination of crown ethers to scandium(iii). Synthesis, properties and structures of the reaction products of ScCl3(thf)3, ScCl3·6H2O and Sc(NO3)3·5H2O with crown ethers journal February 2003
Trivalent scandium, yttrium and lanthanide complexes with thia-oxa and selena-oxa macrocycles and crown ether coordination journal January 2013
Crystal and molecular structure of trichlorotris(tetrahydrofuran)scandium(III) journal January 1974
Hydrolysis of scandium(III): ultracentrifugation and acidity measurements journal January 1966
Structural Systematics of Rare Earth Complexes. XXII. ('Maximally') Hydrated Rare Earth Iodides journal January 2000
Crystal Structures of the ('Maximally') Hydrated Scandium Halides, ScX3.nH2O (X = Cl, Br, I) journal January 2000
Structural Systematics of Rare Earth Complexes. XIII (‘Maximally’) Hydrated (Heavy) Rare Earth Nitrates journal January 1999
Structural Systematics of Rare Earth Complexes. XVI (‘Maximally’) Hydrated Rare Earth(III) Bromides journal January 1999
Structural Systematics of Rare Earth Complexes. XX (Maximally) Hydrated Rare Earth Sulfates and the Double Sulfates (NH4)Ln(SO4)2.4H2O (Ln = La, Tb) journal January 1999
The Inorganic Crystal Structure Database (ICSD)—Present and Future journal January 2004
The scandium effect in multicomponent alloys journal April 2016
Physiological and Biochemical Effects of Rare Earth Elements on Plants and Their Agricultural Significance: A Review journal December 2004
Recent Advances in Chelation Therapy journal January 1965
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
Struktur der hexagonalen Modifikation von Lanthan(III) trichlorid trihydrat journal June 1994
X-ray diffraction study of cerous phosphate and related crystals. I. Hexagonal modification journal September 1950
The structure of lanthanum sulphate enneahydrate journal January 1954
The structure of anhydrous scandium phosphate journal August 1956
The crystal structure of gadolinium trichloride hexahydrate journal March 1961
Die Kristallstrukturen von Yttrium-Vanadat, Lutetium-Phosphat und Lutetium-Arsenat journal January 1973
The crystal structure of La 7 (OH) 18 I 3 journal March 1978
Affinement de la structure cristalline du tétramétaphosphate de scandium: Sc 4 (P 4 O 12 ) 3 journal May 1978
Pentaaquahydroxoscandium(III) dibromide, [Sc(H 2 O) 5 (OH)]Br 2 journal April 2006
Redetermination of [Gd(NO 3 ) 3 (H 2 O) 4 ]·2H 2 O journal June 2012
The Cambridge Structural Database
  • Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P.
  • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179 https://doi.org/10.1107/S2052520616003954
journal April 2016
Synthesis and molecular and crystal structure of the coordination metallopolymer of scandium(III) nitrate with 4,4,10,10-tetramethyl-1,3,7,9,-tetraazospiro[5.5]undecane-2,8-dione journal April 2014
The structure of the scandium iodide complex with antipyrine (AP) and its comparison with the structure of nonisostructural analogues (Compounds [Ln(AP)6]I3 (Ln = La, Y, or Eu)) journal September 2009
Deca(hydroxo)-23-aqua-hexa(lanthanum(III)) iodide octahydrate and deca(hydroxo)-23-aqua-hexa(neodymium(III)) iodide octahydrate: Syntheses and structures journal January 2009
Halide polyhydrates of some rare-earth elements: Synthesis and structures journal September 2011
Scandium in aluminium alloys journal February 2005
Die Kristallstruktur von Gadolinium (III)-sulfit Trihydrat Gd 2 (S0 3 ) 3 ∙ 3H 2 O / Crystal Structure of Gadolinium(III)-sulfite Trihydrate Gd 2 (SO 3 ) 3 ∙3H 2 O journal January 1994
Die Kristallstruktur von Gadolinium-(III)-hydrogensulfat Gd(H SO 4 ) 3 / Crystal Structure of Gadolinium-(III)-hydrogensulfate Gd(HSO 4 ) 3 journal March 1994
La(OH) 2 I(H 2 O): Closing a Gap in Rare Earth Hydroxide Halide Structural Chemistry journal February 2006
Crystal structure of caesium scandium bis(monohydrogenmonophosphate), CsSc(HPO4)2 journal December 2008
Crystal chemistry of the monazite and xenotime structures journal February 1995
Studies on the Hydrolysis of Metal Ions. Part 35. The Hydrolysis of the Lanthanum Ion, La3+. journal January 1961
Crystal Structure of ScCl3 Refined from Powder Neutron Diffraction Data. journal January 1994
Hydrothermal Syntheses, Structures, and Characterizations of Two Lanthanide Sulfate Hydrates Materials, La 2 (SO 4 ) 3 ·H 2 O and Eu 2 (SO 4 ) 3 ·4H 2 O journal April 2010
Sixty Years of the Chemistry of Rare-earth Organometallic Complexes journal January 2014

Cited By (3)

Group 3 metal trihalide complexes with neutral N-donor ligands – exploring their affinity towards fluoride journal January 2018
Separation and purification of scandium: From industry to medicine journal January 2018
Crystal structure of hydroxy scandium nitrate chloride journal April 2019

Similar Records

Isomers of scandium(III) complexes
Journal Article · Tue Nov 30 23:00:00 EST 1982 · Dokl. Phys. Chem. (Engl. Transl.); (United States) · OSTI ID:6131120

The Synthesis and Structure of a Scandium Nitrate Hydroxy-Bridged Dimeric Complex Supported by Bipyridyl Ligands
Journal Article · Mon Mar 21 00:00:00 EDT 2022 · Molecules · OSTI ID:1896474