Covalent organic frameworks comprising cobalt porphyrins for catalytic CO2 reduction in water

Lin, S.; Diercks, C. S.; Zhang, Y. -B.; Kornienko, N.; Nichols, E. M.; Zhao, Y.; Paris, A. R.; Kim, D.; Yang, P.; Yaghi, O. M.; Chang, C. J.

doi:10.1126/science.aac8343

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO2 reduction in water

Journal Article · Wed Aug 19 20:00:00 EDT 2015 · Science

DOI:https://doi.org/10.1126/science.aac8343· OSTI ID:1355835

Lin, S.; Diercks, C. S.; Zhang, Y. -B.; Kornienko, N.; Nichols, E. M.; Zhao, Y.; Paris, A. R.; Kim, D.; Yang, P.; Yaghi, O. M.; Chang, C. J.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001015

OSTI ID:: 1355835

Alternate ID(s):: OSTI ID: 1370752

Journal Information:: Science, Journal Name: Science Journal Issue: 6253 Vol. 349; ISSN 0036-8075

Publisher:: American Association for the Advancement of Science (AAAS)Copyright Statement

Country of Publication:: United States

Language:: English

References (68)

Elements of Molecular and Biomolecular Electrochemistry Savéant, Jean-Michel https://doi.org/10.1002/0471758078	book	January 2006
A Self-Assembled M8L6 Cubic Cage that Selectively Encapsulates Large Aromatic Guests Meng, Wenjing; Breiner, Boris; Rissanen, Kari Angewandte Chemie International Edition, Vol. 50, Issue 15 https://doi.org/10.1002/anie.201100193	journal	March 2011
[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction Bourrez, Marc; Molton, Florian; Chardon-Noblat, Sylvie Angewandte Chemie International Edition, Vol. 50, Issue 42 https://doi.org/10.1002/anie.201103616	journal	September 2011
Lattice Expansion of Highly Oriented 2D Phthalocyanine Covalent Organic Framework Films Spitler, Eric L.; Colson, John W.; Uribe-Romo, Fernando J. Angewandte Chemie International Edition, Vol. 51, Issue 11 https://doi.org/10.1002/anie.201107070	journal	January 2012
Internal Functionalization of Three-Dimensional Covalent Organic Frameworks Bunck, David N.; Dichtel, William R. Angewandte Chemie International Edition, Vol. 51, Issue 8 https://doi.org/10.1002/anie.201108462	journal	January 2012
A convenient, high-yielding, chromatography-free method for the insertion of transition metal acetates into porphyrins Yao, Shu A.; Hansen, Christopher B.; Berry, John F. Polyhedron, Vol. 58 https://doi.org/10.1016/j.poly.2012.05.038	journal	July 2013
Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films DeBlase, Catherine R.; Hernández-Burgos, Kenneth; Silberstein, Katharine E. ACS Nano, Vol. 9, Issue 3 https://doi.org/10.1021/acsnano.5b00184	journal	February 2015
Covalent Organic Frameworks with High Charge Carrier Mobility Wan, Shun; Gándara, Felipe; Asano, Atsushi Chemistry of Materials, Vol. 23, Issue 18, p. 4094-4097 https://doi.org/10.1021/cm201140r	journal	September 2011
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Electrocatalytic Reduction of Carbon Dioxide by the Binuclear Copper Complex [Cu2(6-(diphenylphosphino-2,2'-bipyridyl)2(MeCN)2][PF6]2 Haines, Raymond J.; Wittrig, Rebecca E.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 33, Issue 21 https://doi.org/10.1021/ic00099a024	journal	October 1994
Re(bipy-tBu)(CO) ₃ Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies Smieja, Jonathan M.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic1008363	journal	October 2010
Noninnocence in Metal Complexes: A Dithiolene Dawn Eisenberg, Richard; Gray, Harry B. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic2011748	journal	October 2011
Homogeneous CO ₂ Reduction by Ni(cyclam) at a Glassy Carbon Electrode Froehlich, Jesse D.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 51, Issue 7 https://doi.org/10.1021/ic3001619	journal	March 2012
Studies of Cobalt-Mediated Electrocatalytic CO ₂ Reduction Using a Redox-Active Ligand Lacy, David C.; McCrory, Charles C. L.; Peters, Jonas C. Inorganic Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/ic403122j	journal	April 2014
Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process Beley, Marc.; Collin, Jean Paul.; Ruppert, Romain. Journal of the American Chemical Society, Vol. 108, Issue 24 https://doi.org/10.1021/ja00284a003	journal	November 1986
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt Fisher, Barbara J.; Eisenberg, Richard Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363 https://doi.org/10.1021/ja00544a035	journal	September 1980
Using a One-Electron Shuttle for the Multielectron Reduction of CO₂ to Methanol: Kinetic, Mechanistic, and Structural Insights Barton Cole, Emily; Lakkaraju, Prasad S.; Rampulla, David M. Journal of the American Chemical Society, Vol. 132, Issue 33, p. 11539-11551 https://doi.org/10.1021/ja1023496	journal	August 2010
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E. Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454 https://doi.org/10.1021/ja203564w	journal	August 2011
Tin Oxide Dependence of the CO ₂ Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts Chen, Yihong; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja2108799	journal	January 2012
CO₂ Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu₂O Films Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234 https://doi.org/10.1021/ja3010978	journal	April 2012
Nitrogen-Based Catalysts for the Electrochemical Reduction of CO ₂ to CO Tornow, Claire E.; Thorson, Michael R.; Ma, Sichao Journal of the American Chemical Society, Vol. 134, Issue 48 https://doi.org/10.1021/ja308217w	journal	November 2012
Aqueous CO ₂ Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles Chen, Yihong; Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 49 https://doi.org/10.1021/ja309317u	journal	November 2012
On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid–Vapor Interface Reactions Liu, Xuan-He; Guan, Cui-Zhong; Ding, San-Yuan Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja403464h	journal	May 2013
Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework Pullen, Sonja; Fei, Honghan; Orthaber, Andreas Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407176p	journal	October 2013
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G. Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja4074003	journal	September 2013
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO Zhu, Wenlei; Michalsky, Ronald; Metin, Önder Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409445p	journal	October 2013
Solvothermal Preparation of an Electrocatalytic Metalloporphyrin MOF Thin Film and its Redox Hopping Charge-Transfer Mechanism Ahrenholtz, Spencer R.; Epley, Charity C.; Morris, Amanda J. Journal of the American Chemical Society, Vol. 136, Issue 6 https://doi.org/10.1021/ja410684q	journal	January 2014
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate Zhang, Sheng; Kang, Peng; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja4113885	journal	January 2014
Particle Size Effects in the Catalytic Electroreduction of CO ₂ on Cu Nanoparticles Reske, Rulle; Mistry, Hemma; Behafarid, Farzad Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja500328k	journal	May 2014
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A. Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja501252f	journal	February 2014
Efficient Reduction of CO ₂ to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials Medina-Ramos, Jonnathan; DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja501923g	journal	May 2014
Polyethylenimine-Enhanced Electrocatalytic Reduction of CO ₂ to Formate at Nitrogen-Doped Carbon Nanomaterials Zhang, Sheng; Kang, Peng; Ubnoske, Stephen Journal of the American Chemical Society, Vol. 136, Issue 22 https://doi.org/10.1021/ja5031529	journal	May 2014
Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction Calik, Mona; Auras, Florian; Salonen, Laura M. Journal of the American Chemical Society, Vol. 136, Issue 51 https://doi.org/10.1021/ja509551m	journal	December 2014
Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores Park, Jihye; Feng, Dawei; Zhou, Hong-Cai Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja5123528	journal	January 2015
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 118, Issue 7 https://doi.org/10.1021/ja9534462	journal	January 1996
Operando Spectroscopic Analysis of an Amorphous Cobalt Sulfide Hydrogen Evolution Electrocatalyst Kornienko, Nikolay; Resasco, Joaquin; Becknell, Nigel Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03545	journal	June 2015
Cobalt Porphyrin Catalyzed Reduction of CO ₂ . Radiation Chemical, Photochemical, and Electrochemical Studies Behar, D.; Dhanasekaran, T.; Neta, P. The Journal of Physical Chemistry A, Vol. 102, Issue 17 https://doi.org/10.1021/jp9807017	journal	April 1998
Activity Descriptors for CO ₂ Electroreduction to Methane on Transition-Metal Catalysts Peterson, Andrew A.; Nørskov, Jens K. The Journal of Physical Chemistry Letters, Vol. 3, Issue 2 https://doi.org/10.1021/jz201461p	journal	January 2012
Size-Controlled Model Co Nanoparticle Catalysts for CO ₂ Hydrogenation: Synthesis, Characterization, and Catalytic Reactions Iablokov, Viacheslav; Beaumont, Simon K.; Alayoglu, Selim Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl300973b	journal	May 2012
Oriented Thin Films of a Benzodithiophene Covalent Organic Framework Medina, Dana D.; Werner, Veronika; Auras, Florian ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn5000223	journal	March 2014
Electrochemical Reduction of CO₂ to CO Catalyzed by a Bimetallic Palladium Complex Raebiger, James W.; Turner, Jeffrey W.; Noll, Bruce C. Organometallics, Vol. 25, Issue 14, p. 3345-3351 https://doi.org/10.1021/om060228g	journal	July 2006
Powering the planet with solar fuel Gray, Harry B. Nature Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/nchem.141	journal	April 2009
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A. Nature Chemistry, Vol. 6, Issue 7 https://doi.org/10.1038/nchem.1956	journal	May 2014
Lewis acid-catalysed formation of two-dimensional phthalocyanine covalent organic frameworks Spitler, Eric L.; Dichtel, William R. Nature Chemistry, Vol. 2, Issue 8, p. 672-677 https://doi.org/10.1038/nchem.695	journal	June 2010
A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis Ma, Liqing; Falkowski, Joseph M.; Abney, Carter Nature Chemistry, Vol. 2, Issue 10 https://doi.org/10.1038/nchem.738	journal	July 2010
Conjugated organic framework with three-dimensionally ordered stable structure and delocalized π clouds Guo, Jia; Xu, Yanhong; Jin, Shangbin Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3736	journal	November 2013
Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles Kim, Dohyung; Resasco, Joaquin; Yu, Yi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5948	journal	September 2014
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Tuning the structure and function of metal–organic frameworks via linker design Lu, Weigang; Wei, Zhangwen; Gu, Zhi-Yuan Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00003J	journal	January 2014
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22528j	journal	January 2012
Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO) ₃ Cl (bipy = 2,2′-bipyridine) Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond J. Chem. Soc., Chem. Commun., Issue 6 https://doi.org/10.1039/c39840000328	journal	January 1984
Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst Kang, Peng; Meyer, Thomas J.; Brookhart, Maurice Chemical Science, Vol. 4, Issue 9 https://doi.org/10.1039/c3sc51339d	journal	January 2013
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Thiophene-based covalent organic frameworks Bertrand, G. H. V.; Michaelis, V. K.; Ong, T. -C. Proceedings of the National Academy of Sciences, Vol. 110, Issue 13 https://doi.org/10.1073/pnas.1221824110	journal	March 2013
Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation Vannucci, A. K.; Alibabaei, L.; Losego, M. D. Proceedings of the National Academy of Sciences, Vol. 110, Issue 52 https://doi.org/10.1073/pnas.1319832110	journal	November 2013
Ultraefficient homogeneous catalyst for the CO ₂ -to-CO electrochemical conversion Costentin, Cyrille; Passard, Guillaume; Robert, Marc Proceedings of the National Academy of Sciences, Vol. 111, Issue 42 https://doi.org/10.1073/pnas.1416697111	journal	October 2014
The 1s x-ray absorption pre-edge structures in transition metal oxides de Groot, Frank; Vankó, György; Glatzel, Pieter Journal of Physics: Condensed Matter, Vol. 21, Issue 10 https://doi.org/10.1088/0953-8984/21/10/104207	journal	February 2009
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Porous, Crystalline, Covalent Organic Frameworks Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W. Science, Vol. 310, Issue 5751, p. 1166-1170 https://doi.org/10.1126/science.1120411	journal	November 2005
Where Water Is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster Yano, J.; Kern, J.; Sauer, K. Science, Vol. 314, Issue 5800 https://doi.org/10.1126/science.1128186	journal	November 2006
Designed Synthesis of 3D Covalent Organic Frameworks El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L. Science, Vol. 316, Issue 5822, p. 268-272 https://doi.org/10.1126/science.1139915	journal	April 2007
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks Deng, H.; Doonan, C. J.; Furukawa, H. Science, Vol. 327, Issue 5967, p. 846-850 https://doi.org/10.1126/science.1181761	journal	February 2010
Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene Colson, J. W.; Woll, A. R.; Mukherjee, A. Science, Vol. 332, Issue 6026 https://doi.org/10.1126/science.1202747	journal	April 2011
Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R. Science, Vol. 334, Issue 6056, p. 643-644 https://doi.org/10.1126/science.1209786	journal	September 2011
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Photochemical and Photoelectrochemical Reduction of CO ₂ Kumar, Bhupendra; Llorente, Mark; Froehlich, Jesse Annual Review of Physical Chemistry, Vol. 63, Issue 1 https://doi.org/10.1146/annurev-physchem-032511-143759	journal	May 2012

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