Atomic Layer Deposition of Metastable β-Fe 2 O 3 via Isomorphic Epitaxy for Photoassisted Water Oxidation

Emery, Jonathan D.; Schlepütz, Christian M.; Guo, Peijun; Riha, Shannon C.; Chang, Robert P.  H.; Martinson, Alex B. F.

doi:10.1021/am507065y

Atomic Layer Deposition of Metastable β-Fe ₂ O ₃ via Isomorphic Epitaxy for Photoassisted Water Oxidation

Journal Article · Tue Dec 09 00:00:00 EST 2014 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/am507065y· OSTI ID:1355777

Emery, Jonathan D. ^[1]; Schlepütz, Christian M. ^[2]; Guo, Peijun ^[3]; Riha, Shannon C. ^[1]; Chang, Robert P. H. ^[3]; Martinson, Alex B. F. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering

Here, we report the growth and photoelectrochemical (PEC) characterization of the uncommon bibyite phase of iron(III) oxide (β-Fe₂O₃) epitaxially stabilized via atomic layer deposition on an conductive, transparent, and isomorphic template (Sn-doped In₂O₃). Furthermore, as a photoanode, unoptimized β-Fe₂O₃ ultrathin films perform similarly to their ubiquitous α-phase (hematite) counterpart, but reveal a more ideal bandgap (1.8 eV), a ~0.1 V improved photocurrent onset potential, and longer wavelength (>600 nm) spectral response. Finally, stable operation under basic water oxidation justifies further exploration of this atypical phase and motivates the investigation of other unexplored metastable phases as new PEC materials.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; FG02-94ER14466; SC0001059

OSTI ID:: 1355777

Alternate ID(s):: OSTI ID: 1210441
OSTI ID: 1386535

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 24 Vol. 6; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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The potential versus current state of water splitting with hematite Zandi, Omid; Hamann, Thomas W. Physical Chemistry Chemical Physics, Vol. 17, Issue 35 https://doi.org/10.1039/c5cp04267d	journal	January 2015
Electronic and nuclear contributions to time-resolved optical and X-ray absorption spectra of hematite and insights into photoelectrochemical performance Hayes, Dugan; Hadt, Ryan G.; Emery, Jonathan D. Energy & Environmental Science, Vol. 9, Issue 12 https://doi.org/10.1039/c6ee02266a	journal	January 2016
Metastable iron( iii ) oxide polymorphs derived from Fe/Mn bimetallic coordination polymer particles in confined space: SiO ₂ shell effect on crystal phase transition Lee, Junhyung CrystEngComm, Vol. 21, Issue 18 https://doi.org/10.1039/c9ce00191c	journal	January 2019

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36 MATERIALS SCIENCE
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