Photochemically assisted fast abiotic oxidation of manganese and formation of δ-MnO 2 nanosheets in nitrate solution

Jung, Haesung; Chadha, Tandeep S.; Kim, Doyoon; Biswas, Pratim; Jun, Young-Shin

doi:10.1039/C7CC00754J

Photochemically assisted fast abiotic oxidation of manganese and formation of δ-MnO ₂ nanosheets in nitrate solution

Journal Article · Sun Jan 01 04:00:00 EST 2017 · ChemComm

DOI:https://doi.org/10.1039/C7CC00754J· OSTI ID:1355032

Jung, Haesung; ; Kim, Doyoon; Biswas, Pratim;

This study introduces a new and previously unconsidered fast abiotic formation of Mn(IV) oxides. We report photochemically assisted fast abiotic oxidation of Mn²⁺ (aq) to Mn(IV) (s) by superoxide radicals generated from nitrate photolysis. This photochemical pathway generates randomly stacked layered birnessite (δ-MnO₂) nanosheets.

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1355032

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 32 Vol. 53; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: ENGLISH

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Photochemically assisted fast abiotic oxidation of manganese and formation of δ-MnO 2 nanosheets in nitrate solution

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Photochemically assisted fast abiotic oxidation of manganese and formation of δ-MnO ₂ nanosheets in nitrate solution