Oxygen Reduction Kinetics on Pt Monolayer Shell Highly Affected by the Structure of Bimetallic AuNi Cores

Chen, Guangyu; Kuttiyiel, Kurian A.; Su, Dong; Li, Meng; Wang, Chiu-Hui; Buceta, David; Du, Chunyu; Gao, Yunzhi; Yin, Geping; Sasaki, Kotaro; Vukmirovic, Miomir B.; Adzic, Radoslav R.

doi:10.1021/acs.chemmater.6b00500

Title: Oxygen Reduction Kinetics on Pt Monolayer Shell Highly Affected by the Structure of Bimetallic AuNi Cores

Journal Article · Tue Aug 09 00:00:00 EDT 2016 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.6b00500· OSTI ID:1354474

Chen, Guangyu; Kuttiyiel, Kurian A.; Su, Dong; Li, Meng; Wang, Chiu-Hui; Buceta, David; Du, Chunyu; Gao, Yunzhi; Yin, Geping; Sasaki, Kotaro; Vukmirovic, Miomir B.; Adzic, Radoslav R.

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC00112704

OSTI ID:: 1354474

Report Number(s):: BNL-112991-2016-JA

Journal Information:: Chemistry of Materials, Vol. 28, Issue 15; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (55)

Catalysts by Platonic design Strasser, P. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aac7861	journal	July 2015
Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets Zhang, L.; Roling, L. T.; Wang, X. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aab0801	journal	July 2015
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces Chen, C.; Kang, Y.; Huo, Z. Science, Vol. 343, Issue 6177 https://doi.org/10.1126/science.1249061	journal	February 2014
Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction Sasaki, Kotaro; Naohara, Hideo; Choi, YongMan Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2124	journal	January 2012
Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters Zhang, J.; Sasaki, K.; Sutter, E. Science, Vol. 315, Issue 5809, p. 220-222 https://doi.org/10.1126/science.1134569	journal	January 2007
Tuning the thermodynamic onset potential of electrocatalytic O ₂ reduction reaction by synthetic iron–porphyrin complexes Amanullah, Sk; Das, Pradip Kumar; Samanta, Subhra Chemical Communications, Vol. 51, Issue 49 https://doi.org/10.1039/C5CC01938A	journal	January 2015
Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis Koper, Marc T. M. Journal of Electroanalytical Chemistry, Vol. 660, Issue 2 https://doi.org/10.1016/j.jelechem.2010.10.004	journal	September 2011
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja405149m	journal	October 2013
Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction Yang, Lijun; Jiang, Shujuan; Zhao, Yu Angewandte Chemie International Edition, Vol. 50, Issue 31 https://doi.org/10.1002/anie.201101287	journal	June 2011
The Role of Catalysts and Peroxide Oxidation in Lithium-Oxygen Batteries Black, Robert; Lee, Jin-Hyon; Adams, Brian Angewandte Chemie International Edition, Vol. 52, Issue 1, p. 392-396 https://doi.org/10.1002/anie.201205354	journal	November 2012
Gold-promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong Nature Communications, Vol. 5, Article No. 5185 https://doi.org/10.1038/ncomms6185	journal	November 2014
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt Wu, G.; More, K. L.; Johnston, C. M. Science, Vol. 332, Issue 6028, p. 443-447 https://doi.org/10.1126/science.1200832	journal	April 2011
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric Science, Vol. 324, Issue 5923, p. 71-74 https://doi.org/10.1126/science.1170051	journal	April 2009
Electrocatalytic Oxygen Activation by Carbanion Intermediates of Nitrogen-Doped Graphitic Carbon Li, Qiqi; Noffke, Benjamin W.; Wang, Yilun Journal of the American Chemical Society, Vol. 136, Issue 9 https://doi.org/10.1021/ja413179n	journal	February 2014
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction Gong, K.; Du, F.; Xia, Z. Science, Vol. 323, Issue 5915, p. 760-764 https://doi.org/10.1126/science.1168049	journal	February 2009
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias Nature Materials, Vol. 6, Issue 3, p. 241-247 https://doi.org/10.1038/nmat1840	journal	February 2007
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Platinum-Based Electrocatalysts with Core-Shell Nanostructures Yang, Hong Angewandte Chemie International Edition, Vol. 50, Issue 12 https://doi.org/10.1002/anie.201005868	journal	February 2011
Enhancement of the oxygen reduction on nitride stabilized pt-M (M=Fe, Co, and Ni) core–shell nanoparticle electrocatalysts Kuttiyiel, Kurian A.; Choi, YongMan; Hwang, Sun-Mi Nano Energy, Vol. 13 https://doi.org/10.1016/j.nanoen.2015.03.007	journal	April 2015
Platinum Monolayer Electrocatalysts: Tunable Activity, Stability, and Self-Healing Properties Adzic, Radoslav R. Electrocatalysis, Vol. 3, Issue 3-4 https://doi.org/10.1007/s12678-012-0112-3	journal	September 2012
Mixed-Metal Pt Monolayer Electrocatalysts for Enhanced Oxygen Reduction Kinetics Zhang, Junliang; Vukmirovic, Miomir B.; Sasaki, Kotaro Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja053695i	journal	September 2005
Enhanced Oxygen Reduction Activity of IrCu Core Platinum Monolayer Shell Nano-electrocatalysts Choi, YongMan; Kuttiyiel, Kurian A.; Labis, Joselito P. Topics in Catalysis, Vol. 56, Issue 12 https://doi.org/10.1007/s11244-013-0070-x	journal	June 2013
Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes Sasaki, Kotaro; Naohara, Hideo; Cai, Yun Angewandte Chemie International Edition, Vol. 49, Issue 46, p. 8602-8607 https://doi.org/10.1002/anie.201004287	journal	October 2010
Rationalization of Au Concentration and Distribution in AuNi@Pt Core–Shell Nanoparticles for Oxygen Reduction Reaction An, Wei; Liu, Ping ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01656	journal	September 2015
Pt monolayer on Au-stabilized PdNi core–shell nanoparticles for oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong Electrochimica Acta, Vol. 110 https://doi.org/10.1016/j.electacta.2013.04.037	journal	November 2013
Platinum-Monolayer Shell on AuNi _0.5 Fe Nanoparticle Core Electrocatalyst with High Activity and Stability for the Oxygen Reduction Reaction Gong, Kuanping; Su, Dong; Adzic, Radoslav R. Journal of the American Chemical Society, Vol. 132, Issue 41 https://doi.org/10.1021/ja1063873	journal	October 2010
Platinum Monolayer on Nonnoble Metal−Noble Metal Core−Shell Nanoparticle Electrocatalysts for O₂ Reduction Zhang, J.; Lima, F. H. B.; Shao, M. H. The Journal of Physical Chemistry B, Vol. 109, Issue 48, p. 22701-22704 https://doi.org/10.1021/jp055634c	journal	December 2005
AuPt Alloy Nanoparticles for CO-Tolerant Hydrogen Activation: Architectural Effects in Au-Pt Bimetallic Nanocatalysts Zhou, S.; Jackson, G. S.; Eichhorn, B. Advanced Functional Materials, Vol. 17, Issue 16 https://doi.org/10.1002/adfm.200700216	journal	September 2007
In Situ Phase Separation of NiAu Alloy Nanoparticles for Preparing Highly Active Au/NiO CO Oxidation Catalysts Zhou, Shenghu; Yin, Hongfeng; Schwartz, Viviane ChemPhysChem, Vol. 9, Issue 17 https://doi.org/10.1002/cphc.200800587	journal	December 2008
Truncated Octahedral Pt ₃ Ni Oxygen Reduction Reaction Electrocatalysts Wu, Jianbo; Zhang, Junliang; Peng, Zhenmeng Journal of the American Chemical Society, Vol. 132, Issue 14 https://doi.org/10.1021/ja100571h	journal	April 2010
Metal monolayer deposition by replacement of metal adlayers on electrode surfaces Brankovic, S. R.; Wang, J. X.; Adžić, R. R. Surface Science, Vol. 474, Issue 1-3, p. L173-L179 https://doi.org/10.1016/S0039-6028(00)01103-1	journal	March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Structural Characterization of Carbon-Supported Platinum−Ruthenium Nanoparticles from the Molecular Cluster Precursor PtRu ₅ C(CO) ₁₆ Nashner, Michael S.; Frenkel, Anatoly I.; Adler, David L. Journal of the American Chemical Society, Vol. 119, Issue 33 https://doi.org/10.1021/ja971039f	journal	August 1997
Carbon-Supported IrNi Core–Shell Nanoparticles: Synthesis, Characterization, and Catalytic Activity Sasaki, Kotaro; Kuttiyiel, Kurian A.; Barrio, Laura The Journal of Physical Chemistry C, Vol. 115, Issue 20 https://doi.org/10.1021/jp200746j	journal	May 2011
Structural Models and Atomic Distribution of Bimetallic Nanoparticles as Investigated by X-ray Absorption Spectroscopy Hwang, Bing-Joe; Sarma, Loka Subramanyam; Chen, Jiun-Ming Journal of the American Chemical Society, Vol. 127, Issue 31 https://doi.org/10.1021/ja0526618	journal	August 2005
Tables of Standard Electrode Potentials Milazzo, G.; Caroli, S.; Braun, Robert D. Journal of The Electrochemical Society, Vol. 125, Issue 6 https://doi.org/10.1149/1.2131790	journal	June 1978
Enhanced Catalytic Hydrogenation Activity and Selectivity of Pt-M _x O _y /Al ₂ O ₃ (M = Ni, Fe, Co) Heteroaggregate Catalysts by in Situ Transformation of PtM Alloy Nanoparticles Wang, Xiangdong; Yu, Hongbo; Hua, Dayin The Journal of Physical Chemistry C, Vol. 117, Issue 14 https://doi.org/10.1021/jp309548v	journal	March 2013
Surface segregation energies in transition-metal alloys Ruban, A. V.; Skriver, H. L.; Nørskov, J. K. Physical Review B, Vol. 59, Issue 24 https://doi.org/10.1103/PhysRevB.59.15990	journal	June 1999
Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts Hsieh, Yu-Chi; Zhang, Yu; Su, Dong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3466	journal	September 2013
Ag L -edge x-ray-absorption near-edge-structure study of charge redistribution at the Ag site in Au-Ag alloys Bzowski, A.; Sham, T. K.; Yiu, Y. M. Physical Review B, Vol. 49, Issue 19 https://doi.org/10.1103/PhysRevB.49.13776	journal	May 1994
Charge redistribution and electronic behavior in a series of Au-Cu alloys Kuhn, M.; Sham, T. K. Physical Review B, Vol. 49, Issue 3 https://doi.org/10.1103/PhysRevB.49.1647	journal	January 1994
Structure and reactivity investigations on supported bimetallic AuNi catalysts used for hydrocarbon steam reforming Chin, Y.; King, D.; Roh, H. Journal of Catalysis, Vol. 244, Issue 2 https://doi.org/10.1016/j.jcat.2006.08.016	journal	December 2006
Structural and Architectural Evaluation of Bimetallic Nanoparticles: A Case Study of Pt−Ru Core−Shell and Alloy Nanoparticles Alayoglu, Selim; Zavalij, Peter; Eichhorn, Bryan ACS Nano, Vol. 3, Issue 10, p. 3127-3137 https://doi.org/10.1021/nn900242v	journal	October 2009
Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts Frenkel, Anatoly I. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35174a	journal	January 2012
Solving the 3D structure of metal nanoparticles Frenkel, Anatoly Zeitschrift für Kristallographie - Crystalline Materials, Vol. 222, Issue 11/2007 https://doi.org/10.1524/zkri.2007.222.11.605	journal	January 2007
Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: Scale-up synthesis, structure and activity of Pt shells on Pd cores Sasaki, K.; Wang, J. X.; Naohara, H. Electrochimica Acta, Vol. 55, Issue 8 https://doi.org/10.1016/j.electacta.2009.11.106	journal	March 2010
Surface electronic structure and reactivity of transition and noble metals1Communication presented at the First Francqui Colloquium, Brussels, 19–20 February 1996.1 Ruban, A.; Hammer, B.; Stoltze, P. Journal of Molecular Catalysis A: Chemical, Vol. 115, Issue 3 https://doi.org/10.1016/S1381-1169(96)00348-2	journal	February 1997
Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A. Physical Review Letters, Vol. 93, Issue 15 https://doi.org/10.1103/PhysRevLett.93.156801	journal	October 2004
A general scheme for the estimation of oxygen binding energies on binary transition metal surface alloys Greeley, Jeff; Nørskov, Jens K. Surface Science, Vol. 592, Issue 1-3 https://doi.org/10.1016/j.susc.2005.07.018	journal	November 2005
Density functional theory in surface chemistry and catalysis Norskov, J. K.; Abild-Pedersen, F.; Studt, F. Proceedings of the National Academy of Sciences, Vol. 108, Issue 3 https://doi.org/10.1073/pnas.1006652108	journal	January 2011
Enhanced Oxygen Reduction Activity of Platinum Monolayer on Gold Nanoparticles Shao, Minhua; Peles, Amra; Shoemaker, Krista The Journal of Physical Chemistry Letters, Vol. 2, Issue 2 https://doi.org/10.1021/jz1015789	journal	December 2010
Electrocatalytic Activity for Oxygen Reduction Reaction of Au Core/Pt Shell Nanoparticle-Loaded Carbon Black Catalyst with Different Core Sizes Higuchi, Eiji; Okada, Kohei; Chiku, Masanobu Electrochimica Acta, Vol. 179 https://doi.org/10.1016/j.electacta.2015.03.079	journal	October 2015
Size dependence of the lattice parameters of carbon supported platinum nanoparticles: X-ray diffraction analysis and theoretical considerations Leontyev, I. N.; Kuriganova, A. B.; Leontyev, N. G. RSC Adv., Vol. 4, Issue 68 https://doi.org/10.1039/C4RA04809A	journal	January 2014

Cited By (6)

Redox-active and semi-conducting donor–acceptor conjugated microporous polymers as metal-free ORR catalysts Roy, Syamantak; Bandyopadhyay, Arkamita; Das, Mrinmay Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/c8ta00099a	journal	January 2018
Highly stable one-dimensional Pt nanowires with modulated structural disorder towards the oxygen reduction reaction Kong, Fanpeng; Norouzi Banis, Mohammad; Du, Lei Journal of Materials Chemistry A, Vol. 7, Issue 43 https://doi.org/10.1039/c9ta08120h	journal	January 2019
Highly Dispersed Carbon Supported PdNiMo Core with Pt Monolayer Shell Electrocatalysts for Oxygen Reduction Reaction Okoli, Celest; Kuttiyiel, Kurian A.; Sasaki, Kotaro Journal of The Electrochemical Society, Vol. 165, Issue 15 https://doi.org/10.1149/2.0381815jes	journal	January 2018
Strain engineering of metal-based nanomaterials for energy electrocatalysis Xia, Zhonghong; Guo, Shaojun Chemical Society Reviews, Vol. 48, Issue 12 https://doi.org/10.1039/c8cs00846a	journal	January 2019
Electrocatalysts Prepared by Galvanic Replacement Papaderakis, Athanasios; Mintsouli, Ioanna; Georgieva, Jenia Catalysts, Vol. 7, Issue 12 https://doi.org/10.3390/catal7030080	journal	March 2017
Highly Dispersed Carbon Supported PdNiMo Core with Pt Monolayer Shell Electrocatalysts for Oxygen Reduction Reaction Okoli, Celest; Kuttiyiel, Kurian A.; Sasaki, Kotaro ECS Transactions, Vol. 85, Issue 12 https://doi.org/10.1149/08512.0067ecst	journal	March 2018

Similar Records

Oxygen reduction kinetics on Pt monolayer shell highly affected by the structure of bimetallic AuNi cores

Journal Article · Tue Jul 12 00:00:00 EDT 2016 · Chemistry of Materials · OSTI ID:1354474

Chen, Guangyu; Kuttiyiel, Kurian A.; Su, Dong; +9 more

Tuning electrocatalytic activity of Pt monolayer shell by bimetallic Ir-M (M=Fe, Co, Ni or Cu) cores for the oxygen reduction reaction

Journal Article · Wed May 18 00:00:00 EDT 2016 · Nano Energy · OSTI ID:1354474

Kuttiyiel, Kurian A.; Choi, YongMan; Sasaki, Kotaro; +6 more

Pt monolayer shell on nitrided alloy core — A path to highly stable oxygen reduction catalyst

Journal Article · Wed Jul 22 00:00:00 EDT 2015 · Catalysts · OSTI ID:1354474

Hu, Jue; Kuttiyiel, Kurian A.; Sasaki, Kotaro; +6 more

Title: Oxygen Reduction Kinetics on Pt Monolayer Shell Highly Affected by the Structure of Bimetallic AuNi Cores

Citation Formats

References (55)

Cited By (6)

Similar Records

Related Subjects