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Dispersion of Nanocrystalline Fe 3 O 4 within Composite Electrodes: Insights on Battery-Related Electrochemistry

Journal Article · · ACS Applied Materials and Interfaces

Aggregation of nanosized materials in composite lithium-ion-battery electrodes can be a significant factor influencing electrochemical behavior. In this study, aggregation was controlled in magnetite, Fe3O4, composite electrodes via oleic acid capping and subsequent dispersion in a carbon black matrix. A heat treatment process was effective in the removal of the oleic acid capping agent while preserving a high degree of Fe3O4 dispersion. Electrochemical testing showed that Fe3O4 dispersion is initially beneficial in delivering a higher functional capacity, in agreement with continuum model simulations. However, increased capacity fade upon extended cycling was observed for the dispersed Fe3O4 composites relative to the aggregated Fe3O4 composites. X-ray absorption spectroscopy measurements of electrodes post cycling indicated that the dispersed Fe3O4 electrodes are more oxidized in the discharged state, consistent with reduced reversibility compared with the aggregated sample. Higher charge-transfer resistance for the dispersed sample after cycling suggests increased surface-film formation on the dispersed, high-surface-area nanocrystalline Fe3O4 compared to the aggregated materials. This study provides insight into the specific effects of aggregation on electrochemistry through a multiscale view of mechanisms for magnetite composite electrodes.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1354336
Report Number(s):
BNL--112852-2016-JA
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 18 Vol. 8; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

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Cited By (7)

One-dimensional hybrid nanocomposite of high-density monodispersed Fe 3 O 4 nanoparticles and carbon nanotubes for high-capacity storage of lithium and sodium journal January 2016
A Tunable 3D Nanostructured Conductive Gel Framework Electrode for High-Performance Lithium Ion Batteries journal March 2017
High-energy flexible quasi-solid-state lithium-ion capacitors enabled by a freestanding rGO-encapsulated Fe 3 O 4 nanocube anode and a holey rGO film cathode journal January 2018
Multi-electron transfer enabled by topotactic reaction in magnetite journal April 2019
Scalable Synthesis of an Artificial Polydopamine Solid‐Electrolyte‐Interface‐Assisted 3D rGO/Fe 3 O 4 @PDA Hydrogel for a Highly Stable Anode with Enhanced Lithium‐Ion‐Storage Properties journal January 2019
Size dependent behavior of Fe 3 O 4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation journal January 2017
FeO x -Based Materials for Electrochemical Energy Storage journal April 2018

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