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Title: [Ni(cod) 2][Al(OR F) 4], a Source for Naked Nickel(I) Chemistry

Abstract

The straightforward synthesis of the cationic, purely organometallic Ni I salt [Ni(cod) 2] +[Al(OR F) 4] - was realized through a reaction between [Ni(cod) 2] and Ag[Al(OR F) 4] (cod=1,5-cyclooctadiene). Crystal-structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic NiI olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic NiI complexes.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [3];  [4];  [4];  [5];  [2];  [1]
  1. Univ. of Freiburg (Germany). Institut fuer Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF)
  2. Univ. of Freiburg (Germany). Institut fuer Physikalische Chemie
  3. Humboldt Univ. of Berlin (Germany). Inst. fuer Chemie
  4. Univ. of Ausburg (Germany). Inst. fuer Physik
  5. Univ. of Amsterdam (Netherlands). Van‘t Hoff Inst. for Molecular Sciences (HIMS)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1354244
Report Number(s):
BNL-112760-2016-JA
Journal ID: ISSN 1433-7851
DOE Contract Number:  
SC0012704
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 54; Journal Issue: 49; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Schwab, Miriam M., Himmel, Daniel, Kacprzak, Sylwia, Kratzert, Daniel, Radtke, Valentin, Weis, Philippe, Ray, Kallol, Scheidt, Ernst-Wilhelm, Scherer, Wolfgang, de Bruin, Bas, Weber, Stefan, and Krossing, Ingo. [Ni(cod)2][Al(ORF)4], a Source for Naked Nickel(I) Chemistry. United States: N. p., 2015. Web. doi:10.1002/anie.201506475.
Schwab, Miriam M., Himmel, Daniel, Kacprzak, Sylwia, Kratzert, Daniel, Radtke, Valentin, Weis, Philippe, Ray, Kallol, Scheidt, Ernst-Wilhelm, Scherer, Wolfgang, de Bruin, Bas, Weber, Stefan, & Krossing, Ingo. [Ni(cod)2][Al(ORF)4], a Source for Naked Nickel(I) Chemistry. United States. doi:10.1002/anie.201506475.
Schwab, Miriam M., Himmel, Daniel, Kacprzak, Sylwia, Kratzert, Daniel, Radtke, Valentin, Weis, Philippe, Ray, Kallol, Scheidt, Ernst-Wilhelm, Scherer, Wolfgang, de Bruin, Bas, Weber, Stefan, and Krossing, Ingo. Tue . "[Ni(cod)2][Al(ORF)4], a Source for Naked Nickel(I) Chemistry". United States. doi:10.1002/anie.201506475.
@article{osti_1354244,
title = {[Ni(cod)2][Al(ORF)4], a Source for Naked Nickel(I) Chemistry},
author = {Schwab, Miriam M. and Himmel, Daniel and Kacprzak, Sylwia and Kratzert, Daniel and Radtke, Valentin and Weis, Philippe and Ray, Kallol and Scheidt, Ernst-Wilhelm and Scherer, Wolfgang and de Bruin, Bas and Weber, Stefan and Krossing, Ingo},
abstractNote = {The straightforward synthesis of the cationic, purely organometallic NiI salt [Ni(cod)2]+[Al(ORF)4]- was realized through a reaction between [Ni(cod)2] and Ag[Al(ORF)4] (cod=1,5-cyclooctadiene). Crystal-structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic NiI olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic NiI complexes.},
doi = {10.1002/anie.201506475},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 49,
volume = 54,
place = {United States},
year = {2015},
month = {10}
}

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