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Title: [Ni(cod)2][Al(ORF)4], a Source for Naked Nickel(I) Chemistry

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [1];  [2];  [1];  [1];  [1];  [3];  [4];  [4];  [5];  [2];  [1]
  1. Univ. of Freiburg (Germany). Institut fuer Anorganische und Analytische Chemie, Freiburger Materialforschungszentrum (FMF)
  2. Univ. of Freiburg (Germany). Institut fuer Physikalische Chemie
  3. Humboldt Univ. of Berlin (Germany). Inst. fuer Chemie
  4. Univ. of Ausburg (Germany). Inst. fuer Physik
  5. Univ. of Amsterdam (Netherlands). Van‘t Hoff Inst. for Molecular Sciences (HIMS)
+ Show Author Affiliations

The straightforward synthesis of the cationic, purely organometallic NiI salt [Ni(cod)2]+[Al(ORF)4]- was realized through a reaction between [Ni(cod)2] and Ag[Al(ORF)4] (cod=1,5-cyclooctadiene). Crystal-structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic NiI olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic NiI complexes.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0012704
OSTI ID:
1354244
Report Number(s):
BNL-112760-2016-JA
Journal Information:
Angewandte Chemie (International Edition), Vol. 54, Issue 49; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY