Quaternary borocarbides: New class of intermetallic superconductors

Conference · Sat Apr 01 04:00:00 EST 1995

OSTI ID:135363

Nagarajan, R; Gupta, L C; Dhar, S K; Mazumdar, C; Hossain, Z; Godart, C; Levy-Clement, C; Padalia, B D; Vijayaraghavan, R ^[1]

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1. Indian Inst. of Tech., Bombay (India)

The authors recent discovery of superconductivity (SC) in the four-element multiphase Y-Ni-B-C system at an elevated temperature (TC approximately 12 K) has opened up great possibilities of identifying new superconducting materials and generating new physics. Superconductivity with Tc (greater than 20 K) higher than that known so far in bulk intermetallics has been observed in multiphase Y-Pd-B-C and Th-Pd-B-C systems and a family of single phase materials RENi2B2C (RE= Y, rare earth) have been found. The authors investigations show YNi2B2C to be a strong coupling hard type-II SC. HC2(T) exhibits an unconventional temperature dependence. Specific heat and magnetization studies reveal coexistence of SC and magnetism in RNi2B2C (R = Ho, Er, Tm) with magnetic ordering temperatures (Tc approximately 8 K, 10.5 K, 11 K and Tm approximately 5 K, approximately 7K, approximately 4 K respectively) that are remarkably higher than those in known magnetic superconductors . Mu-SR studies suggest the possibility of Ni atoms carrying a moment in TmNi2B2C. Resistivity results suggests a double re-entrant transition (SC-normal-SC) in HoNi2B2C. RENi2B2C (RE = Ce, Nd, Gd) do not show SC down to 4.2 K. The Nd- and Gd-compounds order magnetically at approximately 4.5 K and approximately 19.5 K, respectively. Two SC transitions are observed in Y-Pd-B-C (Tc approximately 22 K, approximately 10 K) and in Th-Pd-B-C (Tc approximately 20 K, approximately 14 K) systems, which indicate that there are at least two structures which support SC in these borocarbides. In the multiphase ThNi2B2C the authors observe SC at approximately 6 K. No SC was seen in multiphase UNi2B2C, UPd2B2C, UOs2Ge2C and UPd5B3C(0.35) down to 4.2 K. Tc in YNi2B2C is depressed by substitutions (Gd, Th and U at Y-sites and Fe, Co at Ni-sites).

• Research Organization: National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center
• OSTI ID: 135363
• Report Number(s): N--96-10230; NASA-CP--3290-VOL-1; S--792-VOL-1; NAS--1.55:3290-VOL-1; CONF-940627--
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
BORON CARBIDES
INTERMETALLIC COMPOUNDS
MAGNETIZATION
NICKEL CARBIDES
SPECIFIC HEAT
SUPERCONDUCTIVITY
TRANSITION TEMPERATURE
YTTRIUM CARBIDES