Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23

Sanjeewa, Liurukara D.; McMillen, Colin D.; McGuire, Michael A.; Kolis, Joseph W.

doi:10.1021/acs.inorgchem.6b02355

Manganese Vanadate Chemistry in Hydrothermal BaF ₂ Brines: Ba ₃ Mn ₂ (V ₂ O ₇ ) ₂ F ₂ and Ba ₇ Mn ₈ O ₂ (VO ₄ ) ₂ F ₂₃

Journal Article · Mon Dec 05 00:00:00 EST 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b02355· OSTI ID:1352776

Sanjeewa, Liurukara D. ^[1]; ^[1]; McGuire, Michael A. ^[2]; Kolis, Joseph W. ^[1]

Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

We synthesized manganese vanadate fluorides using high-temperature hydrothermal techniques with BaF₂ as a mineralizer. Ba₃Mn₂(V₂O₇)₂F₂ crystallizes in space group C2/c and consists of dimers built from edge-sharing MnO₄F₂ trigonal prisms with linking V₂O₇ groups. Ba₇Mn₈O₂(VO₄)₂F₂₃ crystallizes in space group Cmmm, with a manganese oxyfluoride network built from edge- and corner-sharing Mn^2+/3+(O,F)₆ octahedra. The resulting octahedra form alternating Mn²⁺ and Mn^2+/3+ layers separated by VO₄ tetrahedra. This latter compound exhibits a canted antiferromagnetic order below TN = 25 K.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1352776

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 24 Vol. 55; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (2)

Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8 Pellizzeri, Tiffany M. Smith; McMillen, Colin D.; Ivey, Kimberly Journal of Chemical Crystallography, Vol. 49, Issue 3 https://doi.org/10.1007/s10870-019-00787-4	journal	May 2019
Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties Smith Pellizzeri, Tiffany M.; McGuire, Michael A.; McMillen, Colin D. Dalton Transactions, Vol. 47, Issue 8 https://doi.org/10.1039/c7dt04642a	journal	January 2018

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