Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells

Li, Dongguo; Lv, Haifeng; Kang, Yijin; Markovic, Nenad M.; Stamenkovic, Vojislav R.

doi:10.1146/annurev-chembioeng-080615-034526

Title: Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells

Journal Article · Wed Apr 06 00:00:00 EDT 2016 · Annual Review of Chemical and Biomolecular Engineering

DOI:https://doi.org/10.1146/annurev-chembioeng-080615-034526· OSTI ID:1352589

Li, Dongguo ^[1]; Lv, Haifeng ^[1]; Kang, Yijin ^[1]; Markovic, Nenad M. ^[1]; Stamenkovic, Vojislav R. ^[1]

Argonne National Laboratory, Lemont, IL (United States). Materials Science Division

In this paper, we present a brief summary on the most recent progress in the design of catalysts for electrochemical reduction of oxygen. The main challenge in the wide spread of fuel cell technology is to lower the content of, or even eliminate, Pt and other precious metals in catalysts without sacrificing their performance. Pt-based nanosized catalysts with novel and refined architectures continue to dominate in catalytic performance, and formation of Pt-skin-like surfaces is key to achieving the highest values in activity. Moreover, durability has also been improved in Pt-based systems with addition of Au, which plays an important role in stabilizing the Pt topmost layers against dissolution. However, various carbon-based materials without precious metal have shown improvement in activity and durability and have been explored to serve as catalyst supports. Finally, understanding how the doped elements interact with each other and/or carbon is challenging and necessary in the design of robust fuel cell catalysts.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1352589

Journal Information:: Annual Review of Chemical and Biomolecular Engineering, Vol. 7, Issue 1; ISSN 1947-5438

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 34 works

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Remarkable support effect of SWNTs in Pt catalyst for methanol electrooxidation Wu, Gang; Chen, Yong-Sheng; Xu, Bo-Qing Electrochemistry Communications, Vol. 7, Issue 12 https://doi.org/10.1016/j.elecom.2005.07.015	journal	December 2005
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Titanium nitride–carbon nanotube core–shell composites as effective electrocatalyst supports for low temperature fuel cells Higgins, Drew C.; Choi, Ja-Yeon; Wu, Jason Journal of Materials Chemistry, Vol. 22, Issue 9 https://doi.org/10.1039/c2jm15014j	journal	January 2012
Metal-Organic Framework-Derived Bamboo-like Nitrogen-Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen-Reduction Electrocatalysts Li, Qing; Pan, Hengyu; Higgins, Drew Small, Vol. 11, Issue 12 https://doi.org/10.1002/smll.201402069	journal	November 2014
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Metal-Free Catalysts for Oxygen Reduction Reaction Dai, Liming; Xue, Yuhua; Qu, Liangti Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/cr5003563	journal	May 2015
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Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1427	journal	August 2011
FePt Nanoparticles Assembled on Graphene as Enhanced Catalyst for Oxygen Reduction Reaction Guo, Shaojun; Sun, Shouheng Journal of the American Chemical Society, Vol. 134, Issue 5 https://doi.org/10.1021/ja2104334	journal	January 2012
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Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction Yang, Lijun; Jiang, Shujuan; Zhao, Yu Angewandte Chemie International Edition, Vol. 50, Issue 31 https://doi.org/10.1002/anie.201101287	journal	June 2011
Sulfur-Doped Graphene as an Efficient Metal-free Cathode Catalyst for Oxygen Reduction Yang, Zhi; Yao, Zhen; Li, Guifa ACS Nano, Vol. 6, Issue 1, p. 205-211 https://doi.org/10.1021/nn203393d	journal	December 2011
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A Highly Active and Support-Free Oxygen Reduction Catalyst Prepared from Ultrahigh-Surface-Area Porous Polyporphyrin Yuan, Shengwen; Shui, Jiang-Lan; Grabstanowicz, Lauren Angewandte Chemie, Vol. 125, Issue 32 https://doi.org/10.1002/ange.201302924	journal	June 2013
Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks Zhao, Dan; Shui, Jiang-Lan; Grabstanowicz, Lauren R. Advanced Materials, Vol. 26, Issue 7 https://doi.org/10.1002/adma.201304238	journal	December 2013
Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren Proceedings of the National Academy of Sciences, Vol. 112, Issue 34 https://doi.org/10.1073/pnas.1507159112	journal	August 2015

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Ferrocene-based porous organic polymer derived high-performance electrocatalysts for oxygen reduction Zhou, Baolong; Liu, Liangzhen; Cai, Pingwei J. Mater. Chem. A, Vol. 5, Issue 42 https://doi.org/10.1039/c7ta06515a	journal	January 2017
Iron-/Nitrogen-Doped Electrocatalytically Active Carbons for the Oxygen Reduction Reaction with Low Amounts of Cobalt Pimonova, Yulia A.; Budnyk, Andriy P.; Yohannes, Weldegebriel ACS Omega, Vol. 4, Issue 22 https://doi.org/10.1021/acsomega.9b01534	journal	November 2019
Magnetic Field-Enhanced 4-Electron Pathway for Well-Aligned Co ₃ O ₄ /Electrospun Carbon Nanofibers in the Oxygen Reduction Reaction Zeng, Zheng; Zhang, Tian; Liu, Yiyang ChemSusChem, Vol. 11, Issue 3 https://doi.org/10.1002/cssc.201701947	journal	January 2018
Palladium single atoms supported by interwoven carbon nanotube and manganese oxide nanowire networks for enhanced electrocatalysis Xiang, Weikai; Zhao, Yonghui; Jiang, Zheng Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/c8ta09034c	journal	January 2018
Carbon nanotube@ZIF–derived Fe-N-doped carbon electrocatalysts for oxygen reduction and evolution reactions Xiong, Juan; Zhao, Jing; Xiang, Zhen Journal of Solid State Electrochemistry, Vol. 23, Issue 7 https://doi.org/10.1007/s10008-019-04317-2	journal	June 2019

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