Magnetic ordering in TCNQ-based metal–organic frameworks with host–guest interactions

Zhang, Xuan; Saber, Mohamed R.; Prosvirin, Andrey P.; Reibenspies, Joseph H.; Sun, Lei; Ballesteros-Rivas, Maria; Zhao, Hanhua; Dunbar, Kim R.

doi:10.1039/c5qi00128e

Magnetic ordering in TCNQ-based metal–organic frameworks with host–guest interactions

Journal Article · Thu Sep 03 00:00:00 EDT 2015 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/c5qi00128e· OSTI ID:1352247

^[1]; Saber, Mohamed R. ^[1]; Prosvirin, Andrey P. ^[1]; Reibenspies, Joseph H. ^[1]; Sun, Lei ^[2]; Ballesteros-Rivas, Maria ^[1]; Zhao, Hanhua ^[1]; Dunbar, Kim R. ^[1]

Texas A & M Univ., College Station, TX (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Host–guest interactions between the aromatic molecules benzene, toluene, aniline and nitrobenzene and the redox-active TCNQ-based metal–organic framework (MOF), Fe(TCNQ)(4,4'-bpy) (1) (TCNQ = 7,7,8,8-tetracyanoquinodimethane), have been found to modulate spontaneous magnetization behaviours at low temperatures. An analogous MOF, Mn(TCNQ)(4,4'-bpy) (2) with isotropic Mn(II) ions as well as the two-dimensional compound Fe(TCNQ)(DMF)2·2DMF (3·2DMF), were also prepared as models for studying the effects of single-ion magnetic anisotropy and structural distortion on spin canting. In this work, the results indicate guest-dependent long range magnetic ordering occurs at low temperatures, which correlates with the electrostatic and steric effects of the incorporated aromatic guests.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357; SC0012582

OSTI ID:: 1352247

Journal Information:: Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Journal Issue: 10 Vol. 2; ISSN 2052-1553

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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