Ca(BH4)2 as a simple tool for the preparation of thorium and uranium metallocene borohydride complexes: First synthesis and crystal structure of (C5Me5)2Th(η3-H3BH)2
Journal Article
·
· Inorganic Chemistry Communications
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Here, calcium borohydride allows for the high-yielding synthesis of (C5Me5)2An(η3-H3BH)2 (An = Th, U) by reaction with (C5Me5)2AnCl2 (An = Th, U). While a preparative synthesis of (C5Me5)2U(η3-H3BH)2 has been previously reported in the literature using K(C5Me5) and U(BH4)4, the use of Ca(BH4)2 is higher yielding and mild. Full characterization of the novel compound (C5Me5)2Th(η3-H3BH)2 is presented.
- Research Organization:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE Laboratory Directed Research and Development (LDRD) Program
- Grant/Contract Number:
- AC52-06NA25396
- OSTI ID:
- 1351990
- Alternate ID(s):
- OSTI ID: 1396374
- Report Number(s):
- LA-UR-17-20498
- Journal Information:
- Inorganic Chemistry Communications, Vol. 77, Issue C; ISSN 1387-7003
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 6 works
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