Materials Data on Sn4SF6 by Materials Project
Sn4SF6 crystallizes in the trigonal R3 space group. The structure is three-dimensional. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a 2-coordinate geometry to one S2- and three F1- atoms. The Sn–S bond length is 2.68 Å. There are a spread of Sn–F bond distances ranging from 2.14–2.70 Å. In the second Sn2+ site, Sn2+ is bonded in a 6-coordinate geometry to six F1- atoms. There are three shorter (2.21 Å) and three longer (2.64 Å) Sn–F bond lengths. S2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sn2+ atoms. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to three Sn2+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two Sn2+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1351417
- Report Number(s):
- mp-1021490
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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