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Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in a polymeric matrix

Patent ·
OSTI ID:1351078

A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-BATTELLE, LLC
Patent Number(s):
9,617,398
Application Number:
14/107,416
OSTI ID:
1351078
Country of Publication:
United States
Language:
English

References (8)

Fatigue performance of carbon fibre/vinyl ester composites: the effect of two dissimilar polymeric sizing agents journal July 1998
Plasma-graft polymerization of a monomer with double bonds onto the surface of carbon fiber and its adhesion to a vinyl ester resin journal September 2003
Theoretical study on reaction mechanism of isocyanate radical NCO with ethene journal March 2009
Enhanced interfacial adhesion of carbon fibers to vinyl ester resin using poly(arylene ether phosphine oxide) coatings as adhesion promoters journal January 2000
Plasma etching and plasma polymerization coating of carbon fibers. Part 1. Interfacial adhesion study journal January 2002
Mechanical and Thermal Properties of Chemically Modified Epoxy Resin journal January 2012
Effect of solubility and miscibility on the adhesion behavior of polymer-coated carbon fibers with vinyl ester resins journal January 2000
Designed Interphase Regions in Carbon Fiber Reinforced Vinyl Ester Matrix Composites journal December 1999