Recent trends in binary and ternary rare-earth fluoride nanophosphors: How structural and physical properties influence optical behaviour

Sharma, Rahul Kumar; Mudring, Anja -Verena; Ghosh, Pushpal

doi:10.1016/j.jlumin.2017.03.062

Title: Recent trends in binary and ternary rare-earth fluoride nanophosphors: How structural and physical properties influence optical behaviour

Journal Article · Tue Mar 28 00:00:00 EDT 2017 · Journal of Luminescence

DOI:https://doi.org/10.1016/j.jlumin.2017.03.062· OSTI ID:1349901

Sharma, Rahul Kumar ^[1]; Mudring, Anja -Verena ^[2]; Ghosh, Pushpal ^[1]

Dr. H. S. Gour Univ. (A Central Univ.), Madhya Pradesh (India)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Rare-earth (RE) doped binary and ternary fluoride nanomaterials are currently receiving the highest attention as phosphor materials due to their potential for a wide range of photonic and biophotonic applications. This review article aims providing and introduction to the field and giving a critical overview about the latest developments in this fast evolving field. First, the underlying photoluminescence mechanisms like up- and downconversion (UC and DC), charge transfer (CT) and energy transfer (ET) between optically active trivalent RE ions are explained. Then, the influence of particle size and surface, shape and lattice strain, as well as the crystal phase of the host materials on the optical properties of rare earth based nanomaterias are illustrated. In addition, the effect of surface plasmon resonance (SPR) on the rare earth luminescence is discussed. In the following, different synthesis strategies which have been developed for tuning the crystal phase, shape, size, and morphology of the host nanomaterial are presented. The role of surface modification and functionalization for improving the luminescence intensity, stability, aqueous dispersity/dispersibility and biocompatibility of the materials is discussed. Lastly, photonic applications of RE-doped nanofluorides for energy efficient lighting, improved solar cells and biophotonic applications like photodynamic therapy, and biological detection techniques including in vivo and in vitro bioimaging are presented.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1349901

Report Number(s):: IS-J-9035; PII: S0022231316306603

Journal Information:: Journal of Luminescence, Vol. 189; ISSN 0022-2313

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 71 works

Citation information provided by
Web of Science

References (137)

Tuning upconversion through energy migration in core–shell nanoparticles Wang, Feng; Deng, Renren; Wang, Juan Nature Materials, Vol. 10, Issue 12 https://doi.org/10.1038/nmat3149	journal	October 2011
High-Quality Sodium Rare-Earth Fluoride Nanocrystals: Controlled Synthesis and Optical Properties Mai, Hao-Xin; Zhang, Ya-Wen; Si, Rui Journal of the American Chemical Society, Vol. 128, Issue 19 https://doi.org/10.1021/ja060212h	journal	May 2006
Lanthanide doped upconverting colloidal CaF2 nanoparticles prepared by a single-step hydrothermal method: toward efficient materials with near infrared-to-near infrared upconversion emission Pedroni, Marco; Piccinelli, Fabio; Passuello, Tiziana Nanoscale, Vol. 3, Issue 4 https://doi.org/10.1039/c0nr00860e	journal	January 2011
Impacts of core–shell structures on properties of lanthanide-based nanocrystals: crystal phase, lattice strain, downconversion, upconversion and energy transfer Kar, Arik; Patra, Amitava Nanoscale, Vol. 4, Issue 12 https://doi.org/10.1039/c2nr30389b	journal	January 2012
Progress on lanthanide-based organic–inorganic hybrid phosphors Carlos, Luís D.; Ferreira, Rute A. S.; de Zea Bermudez, Verónica Chem. Soc. Rev., Vol. 40, Issue 2 https://doi.org/10.1039/C0CS00069H	journal	January 2011
Influence of Crystal Phase and Excitation Wavelength on Luminescence Properties of Eu ³⁺ -Doped Sodium Yttrium Fluoride Nanocrystals Ghosh, Pushpal; Patra, Amitava The Journal of Physical Chemistry C, Vol. 112, Issue 49 https://doi.org/10.1021/jp807539r	journal	November 2008
Tuning of Crystal Phase and Luminescence Properties of Eu ³⁺ Doped Sodium Yttrium Fluoride Nanocrystals Ghosh, Pushpal; Patra, Amitava The Journal of Physical Chemistry C, Vol. 112, Issue 9 https://doi.org/10.1021/jp7099114	journal	March 2008
Sensitization of Gd3+ and the dynamics of quantum splitting in GdF3:Pr,Eu Feofilov, S. P.; Zhou, Y.; Jeong, J. Y. Journal of Luminescence, Vol. 122-123 https://doi.org/10.1016/j.jlumin.2006.01.219	journal	January 2007
Energy transfer study between Ce3+ and Tb3+ ions in doped and core-shell sodium yttrium fluoride nanocrystals Ghosh, Pushpal; Kar, Arik; Patra, Amitava Nanoscale, Vol. 2, Issue 7 https://doi.org/10.1039/c0nr00019a	journal	January 2010
Crystal Phase Control of Luminescing α-NaGdF4:Eu3+and β-NaGdF4:Eu3+ Nanocrystals Ptacek, P.; Schäfer, H.; Kömpe, K. Advanced Functional Materials, Vol. 17, Issue 18 https://doi.org/10.1002/adfm.200600974	journal	December 2007
Hexagonal Sodium Yttrium Fluoride Based Green and Blue Emitting Upconversion Phosphors Krämer, Karl W.; Biner, Daniel; Frei, Gabriela Chemistry of Materials, Vol. 16, Issue 7 https://doi.org/10.1021/cm031124o	journal	April 2004
Synthesis of Lanthanide Fluoride Nanoparticles of Varying Shape and Size Lemyre, Jean-Luc; Ritcey, Anna M. Chemistry of Materials, Vol. 17, Issue 11 https://doi.org/10.1021/cm0502065	journal	May 2005
Recent Progress in Rare Earth Micro/Nanocrystals: Soft Chemical Synthesis, Luminescent Properties, and Biomedical Applications Gai, Shili; Li, Chunxia; Yang, Piaoping Chemical Reviews, Vol. 114, Issue 4 https://doi.org/10.1021/cr4001594	journal	December 2013
Semiconductor Nanocrystals as Fluorescent Biological Labels Bruchez Jr., Marcel; Moronne, Mario Moronne; Gin, Peter Gin Science, Vol. 281, Issue 5385, p. 2013-2016 https://doi.org/10.1126/science.281.5385.2013	patent	September 1998
Quantum Dot Bioconjugates for Ultrasensitive Nonisotopic Detection Chan, Warren C. W.; Nie, Shuming Science, Vol. 281, Issue 5385, p. 2016-2018 https://doi.org/10.1126/science.281.5385.2016	journal	September 1998
Stabilization of Inorganic Nanocrystals by Organic Dendrons Wang, Y. Andrew; Li, J. Jack; Chen, Haiyan Journal of the American Chemical Society, Vol. 124, Issue 10 https://doi.org/10.1021/ja016711u	journal	March 2002
Synthesis, Characterization, and Biological Application of Size-Controlled Nanocrystalline NaYF ₄ :Yb,Er Infrared-to-Visible Up-Conversion Phosphors Yi, Guangshun; Lu, Huachang; Zhao, Shuying Nano Letters, Vol. 4, Issue 11 https://doi.org/10.1021/nl048680h	journal	October 2004
Na(Y _1.5 Na _0.5 )F ₆ Single-Crystal Nanorods as Multicolor Luminescent Materials Wang, Leyu; Li, Yadong Nano Letters, Vol. 6, Issue 8 https://doi.org/10.1021/nl060684u	journal	August 2006
Green upconversion nanocrystals for DNA detection Wang, Leyu; Li, Yadong Chemical Communications, Issue 24 https://doi.org/10.1039/b604871d	journal	January 2006
Lanthanide Luminescence for Biomedical Analyses and Imaging Bünzli, Jean-Claude G. Chemical Reviews, Vol. 110, Issue 5 https://doi.org/10.1021/cr900362e	journal	May 2010
Lanthanide luminescence for functional materials and bio-sciences Eliseeva, Svetlana V.; Bünzli, Jean-Claude G. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B905604C	journal	January 2010
Doping Cu in Semiconductor Nanocrystals: Some Old and Some New Physical Insights Srivastava, Bhupendra B.; Jana, Santanu; Pradhan, Narayan Journal of the American Chemical Society, Vol. 133, Issue 4 https://doi.org/10.1021/ja1089809	journal	February 2011
Upconversion and Anti-Stokes Processes with f and d Ions in Solids Auzel, François Chemical Reviews, Vol. 104, Issue 1 https://doi.org/10.1021/cr020357g	journal	January 2004
Absolute quantum yield measurements of colloidal NaYF4: Er3+, Yb3+ upconverting nanoparticles Boyer, John-Christopher; van Veggel, Frank C. J. M. Nanoscale, Vol. 2, Issue 8 https://doi.org/10.1039/c0nr00253d	journal	January 2010
Energy transfer in lanthanide upconversion studies for extended optical applications Dong, Hao; Sun, Ling-Dong; Yan, Chun-Hua Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00188E	journal	January 2015
The photon avalanche: A new phenomenon in Pr ³⁺ ‐based infrared quantum counters Chivian, Jay S.; Case, W. E.; Eden, D. D. Applied Physics Letters, Vol. 35, Issue 2 https://doi.org/10.1063/1.91044	journal	July 1979
Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection Zheng, Wei; Huang, Ping; Tu, Datao Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00178H	journal	January 2015
Relative and absolute determination of fluorescence quantum yields of transparent samples Würth, Christian; Grabolle, Markus; Pauli, Jutta Nature Protocols, Vol. 8, Issue 8 https://doi.org/10.1038/nprot.2013.087	journal	July 2013
Photon upconversion in core–shell nanoparticles Chen, Xian; Peng, Denfeng; Ju, Qiang Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00151F	journal	January 2015
Visible Quantum Cutting in LiGdF ₄ :Eu ³⁺ Through Downconversion Wegh, René T.; Donker, Harry; Oskam, Koenraad D. Science, Vol. 283, Issue 5402 https://doi.org/10.1126/science.283.5402.663	journal	January 1999
Facile preparation of quantum cutting GdF ₃ : Eu3+nanoparticles from ionic liquids Lorbeer, Chantal; Cybinska, Joanna; Mudring, Anja-Verena Chem. Commun., Vol. 46, Issue 4 https://doi.org/10.1039/B919732J	journal	January 2010
Reaching quantum yields ≫100% in nanomaterials Lorbeer, Chantal; Cybinska, Joanna; Mudring, Anja-Verena Journal of Materials Chemistry C, Vol. 2, Issue 10 https://doi.org/10.1039/c3tc31662a	journal	January 2014
Efficient quantum cutting in hexagonal NaGdF4:Eu3+ nanorods Ghosh, Pushpal; Tang, Sifu; Mudring, Anja-Verena Journal of Materials Chemistry, Vol. 21, Issue 24 https://doi.org/10.1039/c1jm10728c	journal	January 2011
Charge compensation in RE ³⁺ (RE = Eu, Gd) and M ⁺ (M = Li, Na, K) co-doped alkaline earth nanofluorides obtained by microwave reaction with reactive ionic liquids leading to improved optical properties Lorbeer, C.; Behrends, F.; Cybinska, J. J. Mater. Chem. C, Vol. 2, Issue 44 https://doi.org/10.1039/C4TC01214C	journal	January 2014
Quantum cutting in nanoparticles producing two green photons Lorbeer, C.; Mudring, A. -V. Chem. Commun., Vol. 50, Issue 87 https://doi.org/10.1039/C4CC04400B	journal	January 2014
Structural and Spectroscopic Characterization of Active Sites in a Family of Light-Emitting Sodium Lanthanide Tetrafluorides Aebischer, Annina; Hostettler, Marc; Hauser, Jürg Angewandte Chemie International Edition, Vol. 45, Issue 17 https://doi.org/10.1002/anie.200503966	journal	April 2006
Optical spectroscopy of the dimer system Cs ₃ Yb ₂ Br ₉ Hehlen, Markus P.; Güdel, Hans U. The Journal of Chemical Physics, Vol. 98, Issue 3 https://doi.org/10.1063/1.464265	journal	February 1993
Remarkable differences in photoluminescent properties between LaPO4:Eu one-dimensional nanowires and zero-dimensional nanoparticles Song, Hongwei; Yu, Lixin; Lu, Shaozhe Applied Physics Letters, Vol. 85, Issue 3 https://doi.org/10.1063/1.1773616	journal	July 2004
Enhancement of Upconversion Emission of LaPO ₄ :Er@Yb Core−Shell Nanoparticles/Nanorods Ghosh, Pushpal; Oliva, Jorge; Rosa, Elder De la The Journal of Physical Chemistry C, Vol. 112, Issue 26 https://doi.org/10.1021/jp801978b	journal	June 2008
Green-Emitting CePO4:Tb/LaPO4 Core–Shell Nanoparticles with 70 % Photoluminescence Quantum Yield Kömpe, Karsten; Borchert, Holger; Storz, Jörg Angewandte Chemie International Edition, Vol. 42, Issue 44 https://doi.org/10.1002/anie.200351943	journal	November 2003
Structural Changes and Spectroscopic Properties of Ce ³⁺ -Ion-Doped Sodium Yttrium Fluoride Nanocrystals: Influences of Sonication and Temperature Ghosh, Pushpal; Kar, Arik; Patra, Amitava The Journal of Physical Chemistry C, Vol. 114, Issue 2 https://doi.org/10.1021/jp910912c	journal	December 2009
The Fluoride Host: Nucleation, Growth, and Upconversion of Lanthanide-Doped Nanoparticles Naccache, Rafik; Yu, Qing; Capobianco, John A. Advanced Optical Materials, Vol. 3, Issue 4 https://doi.org/10.1002/adom.201400628	journal	March 2015
Uniform Nanostructured Arrays of Sodium Rare-Earth Fluorides for Highly Efficient Multicolor Upconversion Luminescence Zhang, Fan; Wan, Ying; Yu, Ting Angewandte Chemie International Edition, Vol. 46, Issue 42 https://doi.org/10.1002/anie.200702519	journal	October 2007
Single-Crystalline and Monodisperse LaF ₃ Triangular Nanoplates from a Single-Source Precursor Zhang, Ya-Wen; Sun, Xiao; Si, Rui Journal of the American Chemical Society, Vol. 127, Issue 10 https://doi.org/10.1021/ja042801y	journal	March 2005
Facile Sonochemical Synthesis of Single-Crystalline Europium Fluorine with Novel Nanostructure Zhu, Ling; Liu, Xiaoming; Meng, Jian Crystal Growth & Design, Vol. 7, Issue 12 https://doi.org/10.1021/cg070224u	journal	December 2007
Controlled Synthesis and Luminescence of Lanthanide Doped NaYF₄ Nanocrystals Wang, Leyu; Li, Yadong Chemistry of Materials, Vol. 19, Issue 4, p. 727-734 https://doi.org/10.1021/cm061887m	journal	February 2007
Doping alkaline-earth: a strategy of stabilizing hexagonal GdF3 at room temperature Zhao, Qi; Shao, Baiqi; Lü, Wei Dalton Transactions, Vol. 42, Issue 43 https://doi.org/10.1039/c3dt51967h	journal	January 2013
Ba ₂ GdF ₇ Nanocrystals: Solution-Based Synthesis, Growth Mechanism, and Luminescence Properties Zhao, Qi; Shao, Baiqi; Lü, Wei Crystal Growth & Design, Vol. 14, Issue 4 https://doi.org/10.1021/cg401933m	journal	March 2014
Controlled synthesis of ultrasmall hexagonal NaTm0.02Lu0.98−xYbxF4 nanocrystals with enhanced upconversion luminescence Zhai, Xuesong; Liu, Shusen; Zhang, Yongling Journal of Materials Chemistry C, Vol. 2, Issue 11 https://doi.org/10.1039/c3tc31760a	journal	January 2014
Hydrothermal synthesis of ordered β-NaYF4 nanorod self-assemblies with multicolor up- and down-conversions Ding, Mingye; Lu, Chunhua; Song, Yan CrystEngComm, Vol. 16, Issue 6 https://doi.org/10.1039/c3ce41860j	journal	January 2014
One-pot hydrothermal synthesis of lanthanide ions doped one-dimensional upconversion submicrocrystals and their potential application in vivo CT imaging Gao, Guo; Zhang, Chunlei; Zhou, Zhijun Nanoscale, Vol. 5, Issue 1 https://doi.org/10.1039/C2NR32850J	journal	January 2013
Monodisperse lanthanide oxyfluorides LnOF (Ln = Y, La, Pr–Tm): morphology controlled synthesis, up-conversion luminescence and in vitro cell imaging Zhang, Yang; Li, Xuejiao; Hou, Zhiyao Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/c4nr00384e	journal	January 2014
Formation of YF ₃ Nanocrystals and Their Self-Assembly into Hollow Peanut-Like Structures Wang, Miao; Huang, Qing-Li; Zhong, Hao-Xiang Crystal Growth & Design, Vol. 7, Issue 10 https://doi.org/10.1021/cg070397j	journal	September 2007
Synthesis and Photoluminescence Properties of Truncated Octahedral Eu-Doped YF ₃ Submicrocrystals or Nanocrystals Tao, Feng; Wang, Zhijun; Yao, Lianzeng The Journal of Physical Chemistry C, Vol. 111, Issue 8 https://doi.org/10.1021/jp065905z	journal	February 2007
Synthesis, Growth Mechanism, and Tunable Upconversion Luminescence of Yb ³⁺ /Tm ³⁺ -Codoped YF ₃ Nanobundles Wang, Guofeng; Qin, Weiping; Zhang, Jisen The Journal of Physical Chemistry C, Vol. 112, Issue 32 https://doi.org/10.1021/jp8004713	journal	July 2008
Monodisperse Upconverting Nanocrystals by Microwave-Assisted Synthesis Wang, Hai-Qiao; Nann, Thomas ACS Nano, Vol. 3, Issue 11 https://doi.org/10.1021/nn9012093	journal	October 2009
Water-Soluble NaYF ₄ :Yb,Er(Tm)/NaYF ₄ /Polymer Core/Shell/Shell Nanoparticles with Significant Enhancement of Upconversion Fluorescence Yi, Guang-Shun; Chow, Gan-Moog Chemistry of Materials, Vol. 19, Issue 3 https://doi.org/10.1021/cm062447y	journal	February 2007
Photoluminescent properties of LaF3:Eu3+ and GdF3:Eu3+ nanoparticles prepared by co-precipitation method Grzyb, T.; Lis, S. Journal of Rare Earths, Vol. 27, Issue 4 https://doi.org/10.1016/S1002-0721(08)60294-X	journal	August 2009
Phase selective synthesis of quantum cutting nanophosphors and the observation of a spontaneous room temperature phase transition Ghosh, Pushpal; Mudring, Anja-Verena Nanoscale, Vol. 8, Issue 15 https://doi.org/10.1039/C6NR00172F	journal	January 2016
Luminescent LaF ₃ :Yb ³⁺ /Er ³⁺ crystals with self-assembling microstructures by a facile ionothermal process Wu, Yuan; Yang, Dongmei; Kang, Xiaojiao CrystEngComm, Vol. 16, Issue 6 https://doi.org/10.1039/C3CE41854E	journal	January 2014
Stokes emission in GdF ₃ :Nd ³⁺ nanoparticles for bioimaging probes Pokhrel, M.; Mimun, L. C.; Yust, B. Nanoscale, Vol. 6, Issue 3 https://doi.org/10.1039/C3NR03317A	journal	January 2014
Europium(III) Fluoride Nanoparticles from Ionic Liquids: Structural, Morphological, and Luminescent Properties Lorbeer, Chantal; Cybińska, Joanna; Mudring, Anja-Verena Crystal Growth & Design, Vol. 11, Issue 4 https://doi.org/10.1021/cg101140r	journal	April 2011
Up-conversion luminescence properties of lanthanide-doped LuF ₃ with different morphologies synthesized via a facile ionothermal process Yu, Xue; Bian, Wenjuan; Wang, Ting CrystEngComm, Vol. 17, Issue 10 https://doi.org/10.1039/C4CE02521K	journal	January 2015
Ionic Liquid-Based “All-in-One” Synthesis and Photoluminescence Properties of Lanthanide Fluorides Zhang, Chao; Chen, Ji; Zhou, Yunchun The Journal of Physical Chemistry C, Vol. 112, Issue 27 https://doi.org/10.1021/jp802083q	journal	June 2008
Solvothermal growth and characterization of one-dimensional-nanostructured materials NH4LnF4 and LnF3 (Ln=Nd, Sm, Eu, Gd and Tb) Huang, Bin; Liu, Zheng; Hong, Jian-Ming Journal of Crystal Growth, Vol. 276, Issue 3-4 https://doi.org/10.1016/j.jcrysgro.2004.11.395	journal	April 2005
Metastable NaYF4 fluorite at high pressures and high temperatures Grzechnik, Andrzej; Bouvier, Pierre; Crichton, Wilson A. Solid State Sciences, Vol. 4, Issue 7 https://doi.org/10.1016/S1293-2558(02)01353-5	journal	June 2002
Synthesis of porous upconverting luminescence α-NaYF ₄ :Ln ³⁺ microspheres and their potential applications as carriers Lv, Changjian; Di, Weihua; Liu, Zhihe Dalton Trans., Vol. 43, Issue 9 https://doi.org/10.1039/C3DT53213E	journal	January 2014
Up-Conversion in Yb ³⁺ −Tm ³⁺ Co-Doped Lutetium Fluoride Particles Prepared by a Combustion−Fluorization Method Xiao, Siguo; Yang, Xiaoliang; Ding, J. W. The Journal of Physical Chemistry C, Vol. 111, Issue 23 https://doi.org/10.1021/jp067323n	journal	June 2007
Synthesis of Li1−xNaxYF4:Yb3+/Ln3+ (0 ≤ x ≤ 0.3, Ln = Er, Tm, Ho) nanocrystals with multicolor up-conversion luminescence properties for in vitro cell imaging Yang, Dongmei; Dai, Yunlu; Ma, Ping'an Journal of Materials Chemistry, Vol. 22, Issue 38 https://doi.org/10.1039/c2jm33910b	journal	January 2012
Morphology control and multicolor up-conversion luminescence of GdOF:Yb3+/Er3+, Tm3+, Ho3+ nano/submicrocrystals Zhang, Yang; Li, Xuejiao; Kang, Xiaojiao Physical Chemistry Chemical Physics, Vol. 16, Issue 22 https://doi.org/10.1039/c4cp00817k	journal	January 2014
Monodisperse Silica-Coated Polyvinylpyrrolidone/NaYF4 Nanocrystals with Multicolor Upconversion Fluorescence Emission Li, Zhengquan; Zhang, Yong Angewandte Chemie, Vol. 118, Issue 46 https://doi.org/10.1002/ange.200602975	journal	November 2006
Dispersible Tm3+-Doped Nanoparticles that Exhibit Strong 1.47 μm Photoluminescence Diamente, P. R.; Raudsepp, M.; van Veggel, F. C. J. M. Advanced Functional Materials, Vol. 17, Issue 3 https://doi.org/10.1002/adfm.200600142	journal	February 2007
Hard Proof of the NaYF ₄ /NaGdF ₄ Nanocrystal Core/Shell Structure Abel, Keith A.; Boyer, John-Christopher; Veggel, Frank C. J. M. van Journal of the American Chemical Society, Vol. 131, Issue 41 https://doi.org/10.1021/ja906971y	journal	September 2009
NIR-Responsive Silica-Coated NaYbF ₄ :Er/Tm/Ho Upconversion Fluorescent Nanoparticles with Tunable Emission Colors and Their Applications in Immunolabeling and Fluorescent Imaging of Cancer Cells Wang, Meng; Mi, Congcong; Zhang, Yixin The Journal of Physical Chemistry C, Vol. 113, Issue 44 https://doi.org/10.1021/jp906394z	journal	October 2009
Fluorescence Resonant Energy Transfer Biosensor Based on Upconversion-Luminescent Nanoparticles Wang, Leyu; Yan, Ruoxue; Huo, Ziyang Angewandte Chemie International Edition, Vol. 44, Issue 37 https://doi.org/10.1002/anie.200501907	journal	September 2005
Bifunctional Nanoparticles with Magnetization and Luminescence Wang, Leyu; Yang, Zhihua; Zhang, Yi The Journal of Physical Chemistry C, Vol. 113, Issue 10 https://doi.org/10.1021/jp808425k	journal	February 2009
Multifunctional Hydroxyapatite/Na(Y/Gd)F ₄ :Yb ³⁺ ,Er ³⁺ Composite Fibers for Drug Delivery and Dual Modal Imaging Liu, Min; Liu, Hui; Sun, Shufen Langmuir, Vol. 30, Issue 4 https://doi.org/10.1021/la500131d	journal	September 2013
Multifunctional NaYF4:Yb/Er/Gd nanocrystal decorated SiO2 nanotubes for anti-cancer drug delivery and dual modal imaging Li, Xuejiao; Hou, Zhiyao; Ma, Ping'an RSC Advances, Vol. 3, Issue 22 https://doi.org/10.1039/c3ra40992a	journal	January 2013
Au Nanorod Decoration on NaYF ₄ :Yb/Tm Nanoparticles for Enhanced Emission and Wavelength-Dependent Biomolecular Sensing Kannan, Palanisamy; Abdul Rahim, Ferhan; Chen, Rui ACS Applied Materials & Interfaces, Vol. 5, Issue 9 https://doi.org/10.1021/am4007758	journal	March 2013
Sub-20 nm sandwich-structured NaGdF4:Yb/Tm@NaLuF4:Yb/Tm@NaYF4 nanocrystals for in vivo upconversion luminescence/computed tomography imaging Shen, Ji-Wei; Wang, Jianing; Kong, Deling RSC Advances, Vol. 4, Issue 10 https://doi.org/10.1039/c3ra46885b	journal	January 2014
Controlled synthesis of lanthanide-doped NaYF4 upconversion nanocrystals via ligand induced crystal phase transition and silica coating Shan, Jingning; Ju, Yiguang Applied Physics Letters, Vol. 91, Issue 12 https://doi.org/10.1063/1.2783476	journal	September 2007
Transition to cubic phase and enhancement of green upconversion emission by adding La3+ ions in hexagonal NaLuF4:Yb3+/Er3+ nanocrystals Xiang, Guotao; Zhang, Jiahua; Hao, Zhendong CrystEngComm, Vol. 16, Issue 12 https://doi.org/10.1039/c3ce42490a	journal	January 2014
A lanthanide-doping route to aspect-ratio-controlled KSc ₂ F ₇ nanocrystals for upconversion, downconversion and magnetism Ding, Yujie; Zhang, Xiaoxia; Zhu, Hao J. Mater. Chem. C, Vol. 2, Issue 5 https://doi.org/10.1039/C3TC31608D	journal	January 2014
Synthesis and Upconversion Luminescence of Hexagonal-Phase NaYF4:Yb, Er3+ Phosphors of Controlled Size and Morphology Zeng, J. -H.; Su, J.; Li, Z. -H. Advanced Materials, Vol. 17, Issue 17 https://doi.org/10.1002/adma.200402046	journal	September 2005
Color tunable YF ₃ : Ce ³⁺ /Ln ³⁺ (Ln ³⁺ : Eu ³⁺ , Tb ³⁺ , Dy ³⁺ , Sm ³⁺ ) luminescent system: role of sensitizer and energy transfer study Sayed, Farheen N.; Grover, V.; Godbole, S. V. RSC Adv., Vol. 2, Issue 3 https://doi.org/10.1039/C1RA00651G	journal	January 2012
Synthesis and Characterization of Ternary NH4Ln2F7 (Ln = Y, Ho, Er, Tm, Yb, Lu) Nanocages Liang, Xin; Wang, Xun; Wang, Leyu European Journal of Inorganic Chemistry, Vol. 2006, Issue 11 https://doi.org/10.1002/ejic.200600076	journal	June 2006
Synthesis of Oil-Dispersible Hexagonal-Phase and Hexagonal-Shaped NaYF ₄ :Yb,Er Nanoplates Wei, Yang; Lu, Fengqi; Zhang, Xinrong Chemistry of Materials, Vol. 18, Issue 24 https://doi.org/10.1021/cm0606171	journal	November 2006
Microwave-assisted synthesis and up–down conversion luminescent properties of multicolor hydrophilic LaF ₃ :Ln ³⁺ nanocrystals Li, Feifei; Li, Chunguang; Liu, Xiaomin Dalton Trans., Vol. 42, Issue 6 https://doi.org/10.1039/C2DT32295A	journal	January 2013
Orthorhombic KSc2F7:Yb/Er nanorods: controlled synthesis and strong red upconversion emission Ding, Yujie; Teng, Xue; Zhu, Hao Nanoscale, Vol. 5, Issue 23 https://doi.org/10.1039/c3nr01840g	journal	January 2013
Rare-Earth-Compound Nanowires, Nanotubes, and Fullerene-Like Nanoparticles: Synthesis, Characterization, and Properties Wang, Xun; Li, Yadong Chemistry - A European Journal, Vol. 9, Issue 22 https://doi.org/10.1002/chem.200304785	journal	November 2003
Fullerene-Like Rare-Earth Nanoparticles Wang, Xun; Li, Yadong Angewandte Chemie International Edition, Vol. 42, Issue 30 https://doi.org/10.1002/anie.200351006	journal	August 2003
A facile synthesis and photoluminescence properties of water-dispersible Re3+ doped CeF3 nanocrystals and solid nanocomposites with polymers Li, Chunguang; Li, Feifei; Li, Tao Dalton Transactions, Vol. 41, Issue 16 https://doi.org/10.1039/c2dt30064h	journal	January 2012
Modifying crystal phase, shape, size, optical and magnetic properties of monodispersed multifunctional NaYbF4 nanocrystals through lanthanide doping Zeng, Songjun; Ren, Guozhong; Xu, Changfu CrystEngComm, Vol. 13, Issue 12 https://doi.org/10.1039/c0ce00833h	journal	January 2011
Morphological Control and Luminescent Properties of CeF ₃ Nanocrystals Zhu, Ling; Li, Qin; Liu, Xiangdong The Journal of Physical Chemistry C, Vol. 111, Issue 16 https://doi.org/10.1021/jp068974m	journal	April 2007
Synthesis of Hexagonal-Phase NaYF₄:Yb,Er and NaYF₄:Yb,Tm Nanocrystals with Efficient Up-Conversion Fluorescence Yi, G. S.; Chow, G. M. Advanced Functional Materials, Vol. 16, Issue 18, p. 2324-2329 https://doi.org/10.1002/adfm.200600053	journal	December 2006
Tunable Thickness and Photoluminescence of Bipyramidal Hexagonal β-NaYF ₄ Microdisks Zhuang, Jianle; Wang, Jing; Yang, Xianfeng Chemistry of Materials, Vol. 21, Issue 1 https://doi.org/10.1021/cm802543k	journal	December 2008
Selective Synthesis and Characterization of Nanocrystalline EuF ₃ with Orthorhombic and Hexagonal Structures Wang, Miao; Huang, Qing-Li; Hong, Jian-Ming Crystal Growth & Design, Vol. 6, Issue 8 https://doi.org/10.1021/cg060116s	journal	August 2006
Controlled Synthesis and Characterization of Nanostructured EuF ₃ with Different Crystalline Phases and Morphologies Wang, Miao; Huang, Qing-Li; Hong, Jian-Ming Crystal Growth & Design, Vol. 6, Issue 9 https://doi.org/10.1021/cg0601709	journal	September 2006
Upconversion Multicolor Fine-Tuning: Visible to Near-Infrared Emission from Lanthanide-Doped NaYF ₄ Nanoparticles Wang, Feng; Liu, Xiaogang Journal of the American Chemical Society, Vol. 130, Issue 17 https://doi.org/10.1021/ja800868a	journal	April 2008
Multi-photon upconversion luminescence from a CaxYF3+2x host by doping with Yb3+/Er3+ or Yb3+/Tm3+ An, Bao-Li; Ma, Li-Hua; Fang, Jian-Hui RSC Advances, Vol. 3, Issue 43 https://doi.org/10.1039/c3ra43702g	journal	January 2013
Synthesis and Photoluminescent Properties of Titanate Layered Oxides Intercalated with Lanthanide Cations by Electrostatic Self-Assembly Methods Matsumoto, Yasumichi; Unal, Ugur; Kimura, Yoshitaka The Journal of Physical Chemistry B, Vol. 109, Issue 26 https://doi.org/10.1021/jp0517089	journal	June 2005
UV Luminescence Property of YPO ₄ :RE (RE = Ce ³⁺ , Tb ³⁺ ) Lai, Hua; Bao, Amurisana; Yang, Yuming The Journal of Physical Chemistry C, Vol. 112, Issue 1 https://doi.org/10.1021/jp074103g	journal	December 2007
Temperature-dependent upconversion luminescence and dynamics of NaYF ₄ :Yb ³⁺ /Er ³⁺ nanocrystals: influence of particle size and crystalline phase Yu, Wei; Xu, Wen; Song, Hongwei Dalton Trans., Vol. 43, Issue 16 https://doi.org/10.1039/C3DT53562B	journal	January 2014
Near-Infrared (NIR) to Red and Green Up-Conversion Emission from Silica Sol−Gel Thin Films Made with La _0.45 Yb _0.50 Er _0.05 F ₃ Nanoparticles, Hetero-Looping-Enhanced Energy Transfer (Hetero-LEET): A New Up-Conversion Process Sivakumar, Sri; van Veggel, Frank C. J. M.; May, P. Stanley Journal of the American Chemical Society, Vol. 129, Issue 3 https://doi.org/10.1021/ja065378x	journal	January 2007
Upconversion Luminescence of β-NaYF ₄ : Yb ³⁺ , Er ³⁺ @β-NaYF ₄ Core/Shell Nanoparticles: Excitation Power Density and Surface Dependence Wang, Yu; Tu, Langping; Zhao, Junwei The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp9003399	journal	April 2009
Upconverting Phosphor Reporters in Immunochromatographic Assays Hampl, Johannes; Hall, Michael; Mufti, Naheed A. Analytical Biochemistry, Vol. 288, Issue 2 https://doi.org/10.1006/abio.2000.4902	journal	January 2001
Enhanced near-infrared quantum cutting luminescence in 1,2,4,5-benzenetetracarboxylic acid/NaYF4:Tb3+, Yb3+ hybrid nanoparticles Li, Suwen; Hou, Zhiyao; Cheng, Ziyong RSC Advances, Vol. 3, Issue 16 https://doi.org/10.1039/c3ra23439h	journal	January 2013
Au@NaYF4:Tb3+ core@shell nanostructures: Synthesis and construction of luminescence resonance energy transfer Song, Yan; Liu, Guixia; Dong, Xiangting Journal of Luminescence, Vol. 171 https://doi.org/10.1016/j.jlumin.2015.10.041	journal	March 2016
Up-Conversion Nanoparticle Assembled Mesoporous Silica Composites: Synthesis, Plasmon-Enhanced Luminescence, and Near-Infrared Light Triggered Drug Release Niu, Na; He, Fei; Ma, Ping’an ACS Applied Materials & Interfaces, Vol. 6, Issue 5 https://doi.org/10.1021/am500325w	journal	February 2014
Au Nanorods@NaGdF ₄ /Yb ³⁺ ,Er ³⁺ Multifunctional Hybrid Nanocomposites with Upconversion Luminescence, Magnetism, and Photothermal Property Song, Yan; Liu, Guixia; Dong, Xiangting The Journal of Physical Chemistry C, Vol. 119, Issue 32 https://doi.org/10.1021/acs.jpcc.5b06099	journal	July 2015
Two-Color Surface Plasmon Polariton Enhanced Upconversion in NaYF ₄ :Yb:Tm Nanoparticles on Au Nanopillar Arrays Luu, QuocAnh; Hor, Amy; Fisher, Jon The Journal of Physical Chemistry C, Vol. 118, Issue 6 https://doi.org/10.1021/jp4115173	journal	January 2014
Properties of transparent Ce:YAG ceramic phosphors for white LED Nishiura, S.; Tanabe, S.; Fujioka, K. Optical Materials, Vol. 33, Issue 5 https://doi.org/10.1016/j.optmat.2010.06.005	journal	March 2011
White-Light-Emitting Single Phosphors via Triply Doped LaF ₃ Nanoparticles Lorbeer, Chantal; Mudring, Anja-Verena The Journal of Physical Chemistry C, Vol. 117, Issue 23 https://doi.org/10.1021/jp312411f	journal	May 2013
Minimum ion-ion distance, cross relaxation and excitonic behaviour in Ln3+ stoichiometric materials Auzel, F.; Dexpert-Ghys, J.; Gautier, C. Journal of Luminescence, Vol. 27, Issue 1 https://doi.org/10.1016/0022-2313(82)90026-6	journal	June 1982
Luminescence of inorganic solids: From isolated centres to concentrated systems Blasse, George Progress in Solid State Chemistry, Vol. 18, Issue 2 https://doi.org/10.1016/0079-6786(88)90004-0	journal	January 1988
Ionic Liquid-Assisted Route to Nanocrystalline Single-Phase Phosphors for White Light-Emitting Diodes Lorbeer , Chantal; Mudring , Anja-Verena ChemSusChem, Vol. 6, Issue 12 https://doi.org/10.1002/cssc.201200915	journal	November 2013
White Emission by Frequency Up-Conversion in Yb ³⁺ -Ho ³⁺ -Tm ³⁺ Triply Doped Hexagonal NaYF ₄ Nanorods Yang, L. W.; Han, H. L.; Zhang, Y. Y. The Journal of Physical Chemistry C, Vol. 113, Issue 44 https://doi.org/10.1021/jp9021689	journal	October 2009
Quantum cutting abilities of sol–gel derived LiGdF4:Eu3+ powders Lepoutre, S.; Boyer, D.; Mahiou, R. Journal of Luminescence, Vol. 128, Issue 4 https://doi.org/10.1016/j.jlumin.2007.10.033	journal	April 2008
Near-Infrared Quantum Cutting for Photovoltaics van der Ende, Bryan M.; Aarts, Linda; Meijerink, Andries Advanced Materials, Vol. 21, Issue 30 https://doi.org/10.1002/adma.200802220	journal	August 2009
Application of NaYF4:Er3+ up-converting phosphors for enhanced near-infrared silicon solar cell response Shalav, A.; Richards, B. S.; Trupke, T. Applied Physics Letters, Vol. 86, Issue 1 https://doi.org/10.1063/1.1844592	journal	January 2005
Upconversion for Photovoltaics - a Review of Materials, Devices and Concepts for Performance Enhancement Goldschmidt, Jan Christoph; Fischer, Stefan Advanced Optical Materials, Vol. 3, Issue 4 https://doi.org/10.1002/adom.201500024	journal	April 2015
Below Band-Gap IR Response of Substrate-Free GaAs Solar Cells Using Two-Photon Up-Conversion Gibart, Pierre; Auzel, François; Guillaume, Jean-Claude Japanese Journal of Applied Physics, Vol. 35, Issue Part 1, No. 8 https://doi.org/10.1143/JJAP.35.4401	journal	August 1996
Upconversion Luminescent Materials: Advances and Applications Zhou, Jing; Liu, Qian; Feng, Wei Chemical Reviews, Vol. 115, Issue 1 https://doi.org/10.1021/cr400478f	journal	November 2014
Light upconverting core–shell nanostructures: nanophotonic control for emerging applications Chen, Guanying; Ågren, Hans; Ohulchanskyy, Tymish Y. Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00170B	journal	January 2015
Efficiency enhancement of solar cells by luminescent up-conversion of sunlight Trupke, T.; Shalav, A.; Richards, B. S. Solar Energy Materials and Solar Cells, Vol. 90, Issue 18-19 https://doi.org/10.1016/j.solmat.2005.09.021	journal	November 2006
Narrow-bandwidth solar upconversion: Case studies of existing systems and generalized fundamental limits Briggs, Justin A.; Atre, Ashwin C.; Dionne, Jennifer A. Journal of Applied Physics, Vol. 113, Issue 12 https://doi.org/10.1063/1.4796092	journal	March 2013
Core/shell structured NaYF ₄ :Yb ³⁺ /Er ³⁺ /Gd ⁺³ nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells Li, Z. Q.; Li, X. D.; Liu, Q. Q. Nanotechnology, Vol. 23, Issue 2 https://doi.org/10.1088/0957-4484/23/2/025402	journal	December 2011
Lab on upconversion nanoparticles: optical properties and applications engineering via designed nanostructure Li, Xiaomin; Zhang, Fan; Zhao, Dongyuan Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00163J	journal	January 2015
Upconversion nanoparticles as versatile light nanotransducers for photoactivation applications Idris, Niagara Muhammad; Jayakumar, Muthu Kumara Gnanasammandhan; Bansal, Akshaya Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00158C	journal	January 2015
Immunolabeling and NIR-Excited Fluorescent Imaging of HeLa Cells by Using NaYF ₄ :Yb,Er Upconversion Nanoparticles Wang, Meng; Mi, Cong-Cong; Wang, Wen-Xing ACS Nano, Vol. 3, Issue 6 https://doi.org/10.1021/nn900491j	journal	May 2009
Up-converting phosphor reporters for nucleic acid microarrays van de Rijke, Frans; Zijlmans, Henry; Li, Shang Nature Biotechnology, Vol. 19, Issue 3 https://doi.org/10.1038/85734	journal	March 2001
Upconverting nanoparticles as nanotransducers for photodynamic therapy in cancer cells Chatterjee, Dev K.; Yong, Zhang Nanomedicine, Vol. 3, Issue 1 https://doi.org/10.2217/17435889.3.1.73	journal	February 2008
Rare earth nanoprobes for functional biomolecular imaging and theranostics Naczynski, Dominik J.; Tan, Mei Chee; Riman, Richard E. J. Mater. Chem. B, Vol. 2, Issue 20 https://doi.org/10.1039/C4TB00094C	journal	January 2014
Luminescent lanthanide nanomaterials: an emerging tool for theranostic applications Ranjan, Shashi; Jayakumar, Muthu Kumara Gnanasammandhan; Zhang, Yong Nanomedicine, Vol. 10, Issue 9 https://doi.org/10.2217/nnm.14.229	journal	May 2015
Design of a Highly Sensitive and Specific Nucleotide Sensor Based on Photon Upconverting Particles Zhang, Peng; Rogelj, Snezna; Nguyen, Khoi Journal of the American Chemical Society, Vol. 128, Issue 38 https://doi.org/10.1021/ja0644024	journal	September 2006
Rattle-type hollow CaWO4:Tb3+@SiO2 nanocapsules as carriers for drug delivery Zhai, Xuefeng; Yu, Min; Cheng, Ziyong Dalton Transactions, Vol. 40, Issue 48 https://doi.org/10.1039/c1dt10996k	journal	January 2011
In Vivo and Scanning Electron Microscopy Imaging of Upconverting Nanophosphors in Caenorhabditis elegans Lim, Shuang Fang; Riehn, Robert; Ryu, William S. Nano Letters, Vol. 6, Issue 2 https://doi.org/10.1021/nl0519175	journal	February 2006

Cited By (8)

Impact of Lanthanide Nanomaterials on Photonic Devices and Smart Applications Zhou, Jiajia; Leaño, Julius L.; Liu, Zhenyu Small, Vol. 14, Issue 40 https://doi.org/10.1002/smll.201801882	journal	July 2018
Influence of ionic liquids and concentration of red phosphorous on luminescent Cu3P nanocrystals Chouryal, Yogendra Nath; Sharma, Rahul Kumar; Acharjee, Debopam Journal of Chemical Sciences, Vol. 131, Issue 9 https://doi.org/10.1007/s12039-019-1665-y	journal	September 2019
Tuning of photoluminescence intensity of europium doped sodium yttrium fluorides synthesized via hydrothermal route Tashi, Lobzang; Kumar, Manesh; Singh, Rajinder Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 15 https://doi.org/10.1007/s10854-019-01795-y	journal	July 2019
BaCaLu ₂ F ₁₀ :Ln ³⁺ (Ln = Eu, Dy, Tb, Sm, Yb/Er, Yb/Ho) spheres: ionic liquid-based synthesis and luminescence properties Liu, Wei; Sun, Qi; Yan, Ming CrystEngComm, Vol. 20, Issue 40 https://doi.org/10.1039/c8ce01080c	journal	January 2018
Novel salicyloylhydrazone derivatives and corresponding terbium(III) complexes: Synthesis and properties research Xiao, Rong; Huang, Wei; Xiao, Xiaoming Luminescence, Vol. 34, Issue 1 https://doi.org/10.1002/bio.3583	journal	December 2018
Tuning the Crystal Phase and Morphology of the Photoluminescent Indium Sulphide Nanocrystals and Their Adsorption-Based Catalytic and Photocatalytic Applications Sharma, Rahul Kumar; Chouryal, Yogendra Nath; Nigam, Sandeep ChemistrySelect, Vol. 3, Issue 28 https://doi.org/10.1002/slct.201801006	journal	July 2018
Structural and luminescence properties of silica powders and transparent glass‐ceramics containing LaF ₃ :Eu ³⁺ nanocrystals Pawlik, Natalia; Szpikowska‐Sroka, Barbara; Pietrasik, Ewa Journal of the American Ceramic Society, Vol. 101, Issue 10 https://doi.org/10.1111/jace.15728	journal	May 2018
A closer look at the defects and luminescence of nanocrystalline fluorides synthesized via ionic liquids: the case of Ce ³⁺ -doped BaF ₂ Sharma, Rahul Kumar; Chouryal, Yogendra Nath; Slesarev, Anatoly I. New Journal of Chemistry, Vol. 44, Issue 1 https://doi.org/10.1039/c9nj04526k	journal	January 2020

Similar Records

Infrared Photon Pair-Production in Ligand-Sensitized Lanthanide Nanocrystals

Journal Article · Wed Nov 04 00:00:00 EST 2020 · Frontiers in Chemistry · OSTI ID:1349901

Agbo, Peter; Kanady, Jacob S.; Abergel, Rebecca J.

MO-G-BRF-07: Optical Characterization of Novel Terbium-Doped Nanophosphors Excited by Clinical Electron and Photon Beams for Potential Use in Molecular Imaging Or Photodynamic Therapy

Journal Article · Sun Jun 15 00:00:00 EDT 2014 · Medical Physics · OSTI ID:1349901

Darafsheh, A; Paik, T; Tenuto, M; +4 more

Structural, morphological and spectroscopic properties of Eu{sup 3+}-doped rare earth fluorides synthesized by the hydrothermalmethod

Journal Article · Mon Apr 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:1349901

Grzyb, Tomasz; Runowski, Marcin; Szczeszak, Agata; +1 more

Related Subjects

36 MATERIALS SCIENCE
rare-earths
rare-earth fluoride
luminescence
nanomaterials
photonics

Title: Recent trends in binary and ternary rare-earth fluoride nanophosphors: How structural and physical properties influence optical behaviour

Citation Formats

References (137)

Cited By (8)

Similar Records

Related Subjects