Surface sum-frequency vibrational spectroscopy of nonpolar media

Sun, Shumei; Tian, Chuanshan; Shen, Y. Ron

doi:10.1073/pnas.1505438112

Surface sum-frequency vibrational spectroscopy of nonpolar media

Journal Article · Mon Apr 27 00:00:00 EDT 2015 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1505438112· OSTI ID:1348219

Sun, Shumei ^[1]; Tian, Chuanshan ^[2]; Shen, Y. Ron ^[3]

Fudan Univ., Shanghai (China); DOE Office of Scientific and Technical Information (OSTI)
Fudan Univ., Shanghai (China)
Fudan Univ., Shanghai (China); Univ. of California, Berkeley, CA (United States)

Sum-frequency generation spectroscopy is surface specific only if the bulk contribution to the signal is negligible. Negligible bulk contribution is, however, not necessarily true, even for media with inversion symmetry. The inevitable challenge is to find the surface spectrum in the presence of bulk contribution, part of which has been believed to be inseparable from the surface contribution. Here, we show that, for nonpolar media, it is possible to separately deduce surface and bulk spectra from combined phase-sensitive sum-frequency vibrational spectroscopic measurements in reflection and transmission. Finally, the study of benzene interfaces is presented as an example.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC03-76SF00098

OSTI ID:: 1348219

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 19 Vol. 112; ISSN 0027-8424

Publisher:: National Academy of Sciences, Washington, DC (United States)Copyright Statement

Country of Publication:: United States

Language:: English

References (36)

Bulk versus surface contributions in nonlinear optics of isotropic centrosymmetric media Cattaneo, Stefano; Kauranen, Martti physica status solidi (b), Vol. 242, Issue 15 https://doi.org/10.1002/pssb.200562207	journal	December 2005
Surface contribution versus bulk contribution in surface nonlinear optical spectroscopy Shen, Y. R. Applied Physics B, Vol. 68, Issue 3 https://doi.org/10.1007/s003400050622	journal	March 1999
Ambiguities in surface nonlinear spectroscopy calculations Byrnes, Steven J.; Geissler, Phillip L.; Shen, Y. R. Chemical Physics Letters, Vol. 516, Issue 4-6 https://doi.org/10.1016/j.cplett.2011.08.027	journal	November 2011
Molecular Bonding and Interactions at Aqueous Surfaces as Probed by Vibrational Sum Frequency Spectroscopy Richmond, G. L. Chemical Reviews, Vol. 102, Issue 8 https://doi.org/10.1021/cr0006876	journal	August 2002
Liquid Interfaces Probed by Second-Harmonic and Sum-Frequency Spectroscopy Eisenthal, K. B. Chemical Reviews, Vol. 96, Issue 4 https://doi.org/10.1021/cr9502211	journal	January 1996
Phase-Sensitive Sum-Frequency Vibrational Spectroscopy and Its Application to Studies of Interfacial Alkyl Chains Ji, Na; Ostroverkhov, Victor; Chen, Chao-Yuan Journal of the American Chemical Society, Vol. 129, Issue 33 https://doi.org/10.1021/ja071989t	journal	August 2007
Mechanisms of Sum Frequency Generation from Liquid Benzene: Symmetry Breaking at Interface and Bulk Contribution Kawaguchi, Tatsuya; Shiratori, Kazuya; Henmi, Yuki The Journal of Physical Chemistry C, Vol. 116, Issue 24 https://doi.org/10.1021/jp302684q	journal	June 2012
Evaluation of Surface vs Bulk Contributions in Sum-Frequency Vibrational Spectroscopy Using Reflection and Transmission Geometries ^† Wei, Xing; Hong, Seok-Cheol; Lvovsky, A. I. The Journal of Physical Chemistry B, Vol. 104, Issue 14 https://doi.org/10.1021/jp9933929	journal	April 2000
Vibrational Sum Frequency Generation by the Quadrupolar Mechanism at the Nonpolar Benzene/Air Interface Matsuzaki, Korenobu; Nihonyanagi, Satoshi; Yamaguchi, Shoichi The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz400829k	journal	May 2013
Surface properties probed by second-harmonic and sum-frequency generation Shen, Y. R. Nature, Vol. 337, Issue 6207 https://doi.org/10.1038/337519a0	journal	February 1989
The air–liquid interface of benzene, toluene, m-xylene, and mesitylene: a sum frequency, Raman, and infrared spectroscopic study Hommel, Elizabeth L.; Allen, Heather C. The Analyst, Vol. 128, Issue 6 https://doi.org/10.1039/b301032p	journal	January 2003
Electric quadrupole contribution to the nonresonant background of sum frequency generation at air/liquid interfaces Yamaguchi, Shoichi; Shiratori, Kazuya; Morita, Akihiro The Journal of Chemical Physics, Vol. 134, Issue 18 https://doi.org/10.1063/1.3586811	journal	May 2011
Sum-frequency generation spectroscopy of interfaces Vidal, Franck; Tadjeddine, Abderrahmane Reports on Progress in Physics, Vol. 68, Issue 5 https://doi.org/10.1088/0034-4885/68/5/R03	journal	March 2005
Sum-frequency generation spectroscopy of interfaces Vidal, Franck; Tadjeddine, Abderrahmane Reports on Progress in Physics, Vol. 68, Issue 5 https://doi.org/10.1088/0034-4885/68/5/r03	journal	March 2005
Nonlinear Optical Properties of Solids: Energy Considerations Pershan, P. S. Physical Review, Vol. 130, Issue 3 https://doi.org/10.1103/PhysRev.130.919	journal	May 1963
Optical Second-Harmonic Generation in Reflection from Media with Inversion Symmetry Bloembergen, N.; Chang, R. K.; Jha, S. S. Physical Review, Vol. 174, Issue 3 https://doi.org/10.1103/PhysRev.174.813	journal	October 1968
Fundamental difficulty in the use of second-harmonic generation as a strictly surface probe Sipe, J. E.; Mizrahi, Victor; Stegeman, George I. Physical Review B, Vol. 35, Issue 17 https://doi.org/10.1103/PhysRevB.35.9091	journal	June 1987
Bulk contribution in surface second-harmonic generation Guyot-Sionnest, P.; Shen, Y. R. Physical Review B, Vol. 38, Issue 12 https://doi.org/10.1103/PhysRevB.38.7985	journal	October 1988
Bulk contribution from isotropic media in surface sum-frequency generation Held, H.; Lvovsky, A. I.; Wei, X. Physical Review B, Vol. 66, Issue 20 https://doi.org/10.1103/PhysRevB.66.205110	journal	November 2002
Nonlinear optical studies of the pure liquid/vapor interface: Vibrational spectra and polar ordering Superfine, R.; Huang, J. Y.; Shen, Y. R. Physical Review Letters, Vol. 66, Issue 8 https://doi.org/10.1103/PhysRevLett.66.1066	journal	February 1991
Strong bulk magnetic dipole induced second-harmonic generation from C 60 Koopmans, Bert; Janner, Anna-Maria; Jonkman, Harry T. Physical Review Letters, Vol. 71, Issue 21 https://doi.org/10.1103/PhysRevLett.71.3569	journal	November 1993
Nonlinear Optical Properties of Solids: Energy Considerations Pershan, P. S. Physical Review, Vol. 130, Issue 3 https://doi.org/10.1103/physrev.130.919	journal	May 1963
Optical Second-Harmonic Generation in Reflection from Media with Inversion Symmetry Bloembergen, N.; Chang, R. K.; Jha, S. S. Physical Review, Vol. 178, Issue 3 https://doi.org/10.1103/physrev.178.1528.3	journal	February 1969
Fundamental difficulty in the use of second-harmonic generation as a strictly surface probe Sipe, J. E.; Mizrahi, Victor; Stegeman, George I. Physical Review B, Vol. 35, Issue 17 https://doi.org/10.1103/physrevb.35.9091	journal	June 1987
Bulk contribution in surface second-harmonic generation Guyot-Sionnest, P.; Shen, Y. R. Physical Review B, Vol. 38, Issue 12 https://doi.org/10.1103/physrevb.38.7985	journal	October 1988
Bulk contribution from isotropic media in surface sum-frequency generation Held, H.; Lvovsky, A. I.; Wei, X. Physical Review B, Vol. 66, Issue 20 https://doi.org/10.1103/physrevb.66.205110	journal	November 2002
Nonlinear optical studies of the pure liquid/vapor interface: Vibrational spectra and polar ordering Superfine, R.; Huang, J. Y.; Shen, Y. R. Physical Review Letters, Vol. 66, Issue 8 https://doi.org/10.1103/physrevlett.66.1066	journal	February 1991
Strong bulk magnetic dipole induced second-harmonic generation from C 60 Koopmans, Bert; Janner, Anna-Maria; Jonkman, Harry T. Physical Review Letters, Vol. 71, Issue 21 https://doi.org/10.1103/physrevlett.71.3569	journal	November 1993
Phase-Sensitive Sum-Frequency Spectroscopy Shen, Y. R. Annual Review of Physical Chemistry, Vol. 64, Issue 1 https://doi.org/10.1146/annurev-physchem-040412-110110	journal	April 2013
Optical Second Harmonic Generation at Interfaces Shen, Y. R. Annual Review of Physical Chemistry, Vol. 40, Issue 1 https://doi.org/10.1146/annurev.pc.40.100189.001551	journal	October 1989
Optical Second Harmonic Generation At Interfaces Shen, Y. Annual Review of Physical Chemistry, Vol. 40, Issue 1 https://doi.org/10.1146/annurev.physchem.40.1.327	journal	January 1989
Separation Problems in Optical Spectroscopies Koopmans, B. Physica Scripta, Vol. T109 https://doi.org/10.1238/Physica.Topical.109a00080	journal	January 2004
Separation Problems in Optical Spectroscopies Koopmans, B. Physica Scripta, Vol. T109 https://doi.org/10.1238/physica.topical.109a00080	journal	January 2004
Theory of Quadrupole Contributions from Interface and Bulk in Second-Order Optical Processes Shiratori, Kazuya; Morita, Akihiro Bulletin of the Chemical Society of Japan, Vol. 85, Issue 10 https://doi.org/10.1246/bcsj.20120167	journal	October 2012
Surface nonlinear optics [Invited] Shen, Y. R. Journal of the Optical Society of America B, Vol. 28, Issue 12 https://doi.org/10.1364/JOSAB.28.000A56	journal	January 2011
Surface nonlinear optics [Invited] Shen, Y. R. Journal of the Optical Society of America B, Vol. 28, Issue 12 https://doi.org/10.1364/josab.28.000a56	journal	January 2011

Cited By (5)

Symmetry-breaking-induced nonlinear optics at a microcavity surface Zhang, Xueyue; Cao, Qi-Tao; Wang, Zhuo Nature Photonics, Vol. 13, Issue 1 https://doi.org/10.1038/s41566-018-0297-y	journal	November 2018
Phase reference in phase-sensitive sum-frequency vibrational spectroscopy Sun, Shumei; Liang, Rongda; Xu, Xiaofan The Journal of Chemical Physics, Vol. 144, Issue 24 https://doi.org/10.1063/1.4954824	journal	June 2016
Quadrupolar mechanism for vibrational sum frequency generation at air/liquid interfaces: Theory and experiment Matsuzaki, Korenobu; Nihonyanagi, Satoshi; Yamaguchi, Shoichi The Journal of Chemical Physics, Vol. 151, Issue 6 https://doi.org/10.1063/1.5088192	journal	August 2019
How surface-specific is 2nd-order non-linear spectroscopy? Sun, Shumei; Schaefer, Jan; Backus, Ellen H. G. The Journal of Chemical Physics, Vol. 151, Issue 23 https://doi.org/10.1063/1.5129108	journal	December 2019
Water at surfaces with tunable surface chemistries Sanders, Stephanie E.; Vanselous, Heather; Petersen, Poul B. Journal of Physics: Condensed Matter, Vol. 30, Issue 11 https://doi.org/10.1088/1361-648x/aaacb5	journal	February 2018

Similar Records

Sum-frequency generation for surface vibrational spectroscopy

Conference · Fri Jul 01 00:00:00 EDT 1988 · OSTI ID:7189087

Sum-Frequency Generation from Chiral Media and Interfaces

Thesis/Dissertation · Sun Feb 12 23:00:00 EST 2006 · OSTI ID:877641

Vibrational Sum Frequency Generation Spectroscopy Microscope

Technical Report · Fri Aug 19 00:00:00 EDT 2016 · OSTI ID:1562215

Related Subjects

36 MATERIALS SCIENCE
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
bulk contribution
electric-quadrupole contribution
nonpolar media
sum-frequency spectroscopy
surface structure

Surface sum-frequency vibrational spectroscopy of nonpolar media

Citation Formats

References (36)

Cited By (5)

Similar Records

Related Subjects