Noble-metal-free bimetallic alloy nanoparticle-catalytic gasification of phenol in supercritical water

Jia, Lijuan; Yu, Jiangdong; Chen, Yuan; Ning, Ping; Guan, Qingqing; Gu, Junjie; Miao, Rongrong; Chen, Qiuling

doi:10.1016/j.supflu.2017.02.017

Title: Noble-metal-free bimetallic alloy nanoparticle-catalytic gasification of phenol in supercritical water

Journal Article · Tue Aug 01 00:00:00 EDT 2017 · Journal of Supercritical Fluids

DOI:https://doi.org/10.1016/j.supflu.2017.02.017· OSTI ID:1347958

Jia, Lijuan; Yu, Jiangdong; Chen, Yuan; Ning, Ping; Guan, Qingqing; Gu, Junjie; Miao, Rongrong; Chen, Qiuling

The exploration of non-noble-metal catalysts for high efficiency gasification of biomass in supercritical water (SCW) is of great significance for the sustainable development. A series of Ni–M (M = Co or Zn) bimetallic nanoparticles supported on graphitized carbon black were synthesized and examined as catalysts for gasification of phenol in SCW. We found that a nearly complete gasification of phenol can be achieved even at a low temperature of 450 °C with the bimetallic nanoparticles catalysts. Kinetic study indicated the activation energy for phenol gasification were 20.4 ± 2.6 and 43.6 ± 2.6 kJ/mol for Ni20Zn15 and Ni20Co15 catalyst, respectively. Furthermore, XRD, XPS and TEM were performed to characterize the catalysts and the results showed the formation of NiCo and NiZn alloy phase. Catalyst recycling experiments were also conducted to evaluate the stability of the catalysts. The characterization of used catalysts suggest that the severe agglomeration of nanoparticles leads to the decrease in catalytic activity.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830; 51568067; 21307049; U1137603; 1319880237

OSTI ID:: 1347958

Journal Information:: Journal of Supercritical Fluids, Vol. 126, Issue C; ISSN 0896-8446

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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References (34)

Gasification of alga Nannochloropsis sp. in supercritical water Guan, Qingqing; Savage, Phillip E.; Wei, Chaohai The Journal of Supercritical Fluids, Vol. 61 https://doi.org/10.1016/j.supflu.2011.09.007	journal	January 2012
Hydrothermal Gasification of Nannochloropsis sp. with Ru/C Guan, Qingqing; Wei, Chaohai; Savage, Phillip E. Energy & Fuels, Vol. 26, Issue 7 https://doi.org/10.1021/ef3007992	journal	June 2012
Supercritical water gasification of sewage sludge: Gas production and phosphorus recovery Acelas, Nancy Y.; López, Diana P.; Brilman, D. W. F. (Wim) Bioresource Technology, Vol. 174 https://doi.org/10.1016/j.biortech.2014.10.003	journal	December 2014
Treatment of sewage sludge in supercritical water and evaluation of the combined process of supercritical water gasification and oxidation Qian, Lili; Wang, Shuzhong; Xu, Donghai Bioresource Technology, Vol. 176 https://doi.org/10.1016/j.biortech.2014.10.125	journal	January 2015
Characterization of the liquid intermediates from gasification of lignite in supercritical water: Insights into the gasification process for hydrogen production Yu, Jiangdong; Chen, Qiuling; Guan, Qingqing International Journal of Hydrogen Energy, Vol. 41, Issue 39 https://doi.org/10.1016/j.ijhydene.2016.08.034	journal	October 2016
Hydrogen production by catalytic gasification of coal in supercritical water with alkaline catalysts: Explore the way to complete gasification of coal Ge, Zhiwei; Jin, Hui; Guo, Liejin International Journal of Hydrogen Energy, Vol. 39, Issue 34 https://doi.org/10.1016/j.ijhydene.2014.09.119	journal	November 2014
Catalytic gasification of lignite in supercritical water with Ru/CeO2–ZrO2 Yu, Jiangdong; Lu, Xiuyun; Shi, Yunjie International Journal of Hydrogen Energy, Vol. 41, Issue 8 https://doi.org/10.1016/j.ijhydene.2015.12.152	journal	March 2016
Catalytic hydrothermal gasification of algae for hydrogen production: Composition of reaction products and potential for nutrient recycling Onwudili, Jude A.; Lea-Langton, Amanda R.; Ross, Andrew B. Bioresource Technology, Vol. 127 https://doi.org/10.1016/j.biortech.2012.10.020	journal	January 2013
Effect of metal addition to Ni/activated charcoal catalyst on gasification of glucose in supercritical water Lee, In-Gu International Journal of Hydrogen Energy, Vol. 36, Issue 15 https://doi.org/10.1016/j.ijhydene.2011.05.008	journal	July 2011
Hydrogen production from the gasification of lignin with nickel catalysts in supercritical water Furusawa, T.; Sato, T.; Sugito, H. International Journal of Hydrogen Energy, Vol. 32, Issue 6 https://doi.org/10.1016/j.ijhydene.2006.08.001	journal	May 2007
Supercritical water gasification with Ni/ZrO2 catalyst for hydrogen production from model wastewater of polyethylene glycol Yan, Bo; Wu, Junzhang; Xie, Cheng The Journal of Supercritical Fluids, Vol. 50, Issue 2 https://doi.org/10.1016/j.supflu.2009.04.015	journal	September 2009
Supercritical water gasification of phenol using a Ru/CeO2 catalyst Guan, Qingqing; Huang, Xiaodian; Liu, Jing Chemical Engineering Journal, Vol. 283 https://doi.org/10.1016/j.cej.2015.05.033	journal	January 2016
Catalytic gasification of phenol in supercritical water with Ru/graphitized carbon black Yu, Jiangdong; Guan, Qingqing; Chen, Qiuling RSC Advances, Vol. 6, Issue 79 https://doi.org/10.1039/C6RA15601K	journal	January 2016
Gasification of Organosolv-lignin Over Charcoal Supported Noble Metal Salt Catalysts in Supercritical Water Yamaguchi, Aritomo; Hiyoshi, Norihito; Sato, Osamu Topics in Catalysis, Vol. 55, Issue 11-13 https://doi.org/10.1007/s11244-012-9857-4	journal	July 2012
Hydrogen from ethylene glycol by supercritical water reforming using noble and base metal catalysts de Vlieger, D. J. M.; Chakinala, A. G.; Lefferts, L. Applied Catalysis B: Environmental, Vol. 111-112 https://doi.org/10.1016/j.apcatb.2011.11.005	journal	January 2012
Supercritical water gasification of an aqueous by-product from biomass hydrothermal liquefaction with novel Ru modified Ni catalysts Zhang, Linghong; Champagne, Pascale; (Charles) Xu, Chunbao Bioresource Technology, Vol. 102, Issue 17, p. 8279-8287 https://doi.org/10.1016/j.biortech.2011.06.051	journal	September 2011
Catalytic supercritical gasification of biocrude from hydrothermal liquefaction of cattle manure Tushar, Mohammad S. H. K.; Dutta, Animesh; Xu, Chunbao (Charles) Applied Catalysis B: Environmental, Vol. 189 https://doi.org/10.1016/j.apcatb.2016.02.032	journal	July 2016
Sorption enhanced aqueous phase reforming of glycerol for hydrogen production over Pt-Ni supported on multi-walled carbon nanotubes He, Chao; Zheng, Jianwei; Wang, Ke Applied Catalysis B: Environmental, Vol. 162 https://doi.org/10.1016/j.apcatb.2014.07.012	journal	January 2015
Lignin Gasification over Charcoal-supported Palladium and Nickel Bimetal Catalysts in Supercritical Water Yamaguchi, Aritomo; Hiyoshi, Norihito; Sato, Osamu Chemistry Letters, Vol. 39, Issue 12 https://doi.org/10.1246/cl.2010.1251	journal	December 2010
Noble-Metal-Free Bimetallic Nanoparticle-Catalyzed Selective Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage Singh, Sanjay Kumar; Singh, Ashish Kumar; Aranishi, Kengo Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja208475y	journal	December 2011
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene Studt, F.; Abild-Pedersen, F.; Bligaard, T. Science, Vol. 320, Issue 5881 https://doi.org/10.1126/science.1156660	journal	June 2008
ZnO-Carbon-Nanotube Composite Supported Nickel Catalysts for Selective Conversion of Cellulose into Vicinal Diols van der Wijst, Cornelis; Duan, Xuezhi; Skeie Liland, Ingvild ChemCatChem, Vol. 7, Issue 18 https://doi.org/10.1002/cctc.201500486	journal	August 2015
Hydrogen production by biomass gasification in supercritical water with bimetallic Ni–M/γAl2O3 catalysts (M = Cu, Co and Sn) Li, Sha; Lu, Youjun; Guo, Liejin International Journal of Hydrogen Energy, Vol. 36, Issue 22 https://doi.org/10.1016/j.ijhydene.2011.07.144	journal	November 2011
Supercritical water gasification of phenol as a model for plant biomass Selvi Gökkaya, Dilek; Saglam, Mehmet; Yüksel, Mithat International Journal of Hydrogen Energy, Vol. 40, Issue 34 https://doi.org/10.1016/j.ijhydene.2015.04.078	journal	September 2015
Supercritical Water Gasification of Phenol and Glycine as Models for Plant and Protein Biomass DiLeo, Gregory J.; Neff, Matthew E.; Kim, Soo Energy & Fuels, Vol. 22, Issue 2 https://doi.org/10.1021/ef700497d	journal	January 2008
Hydrothermal gasification of biomass: consecutive reactions to long-living intermediates Kruse, Andrea; Bernolle, Philipp; Dahmen, Nicolaus Energy Environ. Sci., Vol. 3, Issue 1 https://doi.org/10.1039/B915034J	journal	January 2010
Polyol synthesis of nickel–copper based catalysts for hydrogen production by methane decomposition Shen, Yi; Lua, Aik Chong International Journal of Hydrogen Energy, Vol. 40, Issue 1 https://doi.org/10.1016/j.ijhydene.2014.10.071	journal	January 2015
Synthesis of Ni and Ni–Cu supported on carbon nanotubes for hydrogen and carbon production by catalytic decomposition of methane Shen, Yi; Lua, Aik Chong Applied Catalysis B: Environmental, Vol. 164 https://doi.org/10.1016/j.apcatb.2014.08.038	journal	March 2015
Ru decorated carbon nanotubes – a promising catalyst for reforming bio-based acetic acid in the aqueous phase de Vlieger, D. J. M.; Lefferts, L.; Seshan, K. Green Chemistry, Vol. 16, Issue 2 https://doi.org/10.1039/c3gc41922c	journal	January 2014
A NiCo/NiO–CoO _x ultrathin layered catalyst with strong basic sites for high-performance H ₂ generation from hydrous hydrazine Wu, Dandan; Wen, Ming; Lin, Xijian Journal of Materials Chemistry A, Vol. 4, Issue 17 https://doi.org/10.1039/C6TA01092J	journal	January 2016
Coprecipitation of nickel zinc malonate: A facile and reproducible synthesis route for Ni1−Zn O nanoparticles and Ni1−Zn O/ZnO nanocomposites via pyrolysis Lontio Fomekong, Roussin; Kenfack Tsobnang, Patrice; Magnin, Delphine Journal of Solid State Chemistry, Vol. 230 https://doi.org/10.1016/j.jssc.2015.07.040	journal	October 2015
Hydrogen production from glycerol by reforming in supercritical water over Ru/Al2O3 catalyst Byrd, A.; Pant, K.; Gupta, R. Fuel, Vol. 87, Issue 13-14 https://doi.org/10.1016/j.fuel.2008.04.024	journal	October 2008
Stability of Supported Ruthenium Catalysts for Lignin Gasification in Supercritical Water Osada, Mitsumasa; Sato, Osamu; Arai, Kunio Energy & Fuels, Vol. 20, Issue 6 https://doi.org/10.1021/ef060356h	journal	November 2006
Hydrogen rich gas production via supercritical water gasification of sugarcane bagasse using unpromoted and copper promoted Ni/CNT nanocatalysts Rashidi, Masih; Tavasoli, Ahmad The Journal of Supercritical Fluids, Vol. 98 https://doi.org/10.1016/j.supflu.2015.01.008	journal	March 2015

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Catalytic gasification of phenol in supercritical water over bimetallic Co–Ni/AC catalyst Guan, Qingqing; Kong, Zhaoni; Xie, Zhengzhe Environmental Technology, Vol. 40, Issue 16 https://doi.org/10.1080/09593330.2018.1439111	journal	February 2018
Bimetallic Nanoparticles in Alternative Solvents for Catalytic Purposes Dang-Bao, Trung; Pla, Daniel; Favier, Isabelle Catalysts, Vol. 7, Issue 7 https://doi.org/10.3390/catal7070207	journal	July 2017
Selective Conversion of Phenol in a Subcritical Water Medium Using γ-Al2O3 Supported Ni–Co Bimetallic Catalyst Shi, Yuzhen; Chen, Shanshuai; He, Liang Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030212	journal	February 2019
Catalytic gasification of phenol in supercritical water over bimetallic Co–Ni/AC catalyst Guan, Qingqing; Kong, Zhaoni; Xie, Zhengzhe Figshare https://doi.org/10.6084/m9.figshare.5943193	text	January 2018
Catalytic gasification of phenol in supercritical water over bimetallic Co–Ni/AC catalyst Guan, Qingqing; Kong, Zhaoni; Xie, Zhengzhe Taylor & Francis https://doi.org/10.6084/m9.figshare.5943193.v1	text	January 2018

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36 MATERIALS SCIENCE
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supercritical water
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Title: Noble-metal-free bimetallic alloy nanoparticle-catalytic gasification of phenol in supercritical water

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