Cascade synthesis of a gold nanoparticle–network polymer composite

Grubjesic, Simonida; Ringstrand, Bryan Scott; Jungjohann, Katherine L.; Brombosz, Scott M.; Seifert, Sönke; Firestone, Millicent Anne

doi:10.1039/c5nr06594a

Title: Cascade synthesis of a gold nanoparticle–network polymer composite

Journal Article · Mon Nov 02 00:00:00 EST 2015 · Nanoscale

DOI:https://doi.org/10.1039/c5nr06594a· OSTI ID:1347351

Grubjesic, Simonida ^[1]; Ringstrand, Bryan Scott ^[2]; Jungjohann, Katherine L. ^[3]; Brombosz, Scott M. ^[1]; Seifert, Sönke ^[1]; Firestone, Millicent Anne ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

In this paper, the multi-step, cascade synthesis of a self-supporting, hierarchically-structured gold nanoparticle hydrogel composite is described. The composite is spontaneously prepared from a non-covalent, lamellar lyotropic mesophase composed of amphiphiles that support the reactive constituents, a mixture of hydroxyl- and acrylate-end-derivatized PEO₁₁₇-PPO₄₇-PEO₁₁₇ and [AuCl₄]^-. The reaction sequence begins with the auto-reduction of aqueous [AuCl₄]^- by PEO₁₁₇-PPO₄₇-PEO₁₁₇ which leads to both the production of Au NPs and the free radical initiated polymerization and crosslinking of the acrylate endderivatized PEO₁₁₇-PPO₄₇-PEO₁₁₇ to yield a network polymer. Optical spectroscopy and TEM monitored the reduction of [AuCl₄]^-, formation of large aggregated Au NPs and oxidative etching into a final state of dispersed, spherical Au NPs. ATR/FT-IR spectroscopy and thermal analysis confirms acrylate crosslinking to yield the polymer network. X-ray scattering (SAXS and WAXS) monitored the evolution of the multilamellar structured mesophase and revealed the presence of semi-crystalline PEO confined within the water layers. The hydrogel could be reversibly swollen without loss of the well-entrained Au NPs with full recovery of composite structure. Finally, optical spectroscopy shows a notable red shift (Δλ~ 45 nm) in the surface plasmon resonance between swollen and contracted states, demonstrating solvent-mediated modulation of the internal NP packing arrangement.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC04-94AL85000; AC52-06NA25396; AC02-06CH11357

OSTI ID:: 1347351

Alternate ID(s):: OSTI ID: 1335623; OSTI ID: 1352655

Report Number(s):: SAND2015-2522J; LA-UR-15-28768; 579846

Journal Information:: Nanoscale, Vol. 8, Issue 5; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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References (63)

Domino Reactions in Organic Synthesis Tietze, Lutz F. Chemical Reviews, Vol. 96, Issue 1 https://doi.org/10.1021/cr950027e	journal	January 1996
Synergy between chemo- and bio-catalysts in multi-step transformations Caiazzo, Aldo; Garcia, Paula M. L.; Wever, Ron Organic & Biomolecular Chemistry, Vol. 7, Issue 14 https://doi.org/10.1039/b901592b	journal	January 2009
Recent Developments in Asymmetric Organocatalytic Domino Reactions Pellissier, Hélène Advanced Synthesis & Catalysis, Vol. 354, Issue 2-3 https://doi.org/10.1002/adsc.201100714	journal	February 2012
Combining the ‘two worlds’ of chemocatalysis and biocatalysis towards multi-step one-pot processes in aqueous media Gröger, Harald; Hummel, Werner Current Opinion in Chemical Biology, Vol. 19 https://doi.org/10.1016/j.cbpa.2014.03.002	journal	April 2014
The art of total synthesis through cascade reactions Nicolaou, K. C.; Chen, Jason S. Chemical Society Reviews, Vol. 38, Issue 11 https://doi.org/10.1039/b903290h	journal	January 2009
Cascade Reactions in Total Synthesis Nicolaou, K. C.; Edmonds, David J.; Bulger, Paul G. Angewandte Chemie International Edition, Vol. 45, Issue 43 https://doi.org/10.1002/anie.200601872	journal	November 2006
Nanostructured Catalysts for Organic Transformations Chng, Leng Leng; Erathodiyil, Nandanan; Ying, Jackie Y. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300197s	journal	January 2013
One-pot cascade reactions catalyzed by acid–base mesoporous MCM-41 materials Shang, Fanpeng; Sun, Jianrui; Liu, Heng Materials Research Bulletin, Vol. 47, Issue 3 https://doi.org/10.1016/j.materresbull.2011.11.055	journal	March 2012
Tailored Synthesis of Various Nanomaterials by Using a Graphene-Oxide-Based Gel as a Nanoreactor and Nanohybrid-Catalyzed CC Bond Formation Biswas, Abhijit; Banerjee, Arindam Chemistry - An Asian Journal, Vol. 9, Issue 12 https://doi.org/10.1002/asia.201402695	journal	September 2014
Cascade Reactions Catalyzed by Bionanostructures Filice, Marco; Palomo, Jose M. ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs401005y	journal	April 2014
A Yolk-Shell Nanoreactor with a Basic Core and an Acidic Shell for Cascade Reactions Yang, Yan; Liu, Xiao; Li, Xiaobo Angewandte Chemie International Edition, Vol. 51, Issue 36 https://doi.org/10.1002/anie.201204829	journal	August 2012
Multi-enzyme co-embedded organic–inorganic hybrid nanoflowers: synthesis and application as a colorimetric sensor Sun, Jiayu; Ge, Jiechao; Liu, Weimin Nanoscale, Vol. 6, Issue 1 https://doi.org/10.1039/C3NR04425D	journal	January 2014
Cascade Reactions in Multicompartmentalized Polymersomes Peters, Ruud J. R. W.; Marguet, Maïté; Marais, Sébastien Angewandte Chemie International Edition, Vol. 53, Issue 1 https://doi.org/10.1002/anie.201308141	journal	November 2013
Greater than the sum: Synergy and emergent properties in nanoparticle–polymer composites Firestone, Millicent A.; Hayden, Steven C.; Huber, Dale L. MRS Bulletin, Vol. 40, Issue 9 https://doi.org/10.1557/mrs.2015.202	journal	September 2015
Structural Fabrication and Functional Modulation of Nanoparticle-Polymer Composites Zhang, Hao; Han, Jishu; Yang, Bai Advanced Functional Materials, Vol. 20, Issue 10 https://doi.org/10.1002/adfm.201000089	journal	May 2010
Dynamic Nanoparticle Assemblies Wang, Libing; Xu, Liguang; Kuang, Hua Accounts of Chemical Research, Vol. 45, Issue 11 https://doi.org/10.1021/ar200305f	journal	March 2012
Controlled Structure and Properties of Thermoresponsive Nanoparticle–Hydrogel Composites Wang, C.; Flynn, N. T.; Langer, R. Advanced Materials, Vol. 16, Issue 13 https://doi.org/10.1002/adma.200306516	journal	July 2004
A study on synthesis and properties of Ag nanoparticles immobilized polyacrylamide hydrogel composites Saravanan, P.; Padmanabha Raju, M.; Alam, Sarfaraz Materials Chemistry and Physics, Vol. 103, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2007.02.025	journal	June 2007
Gold Nanoparticle/Hydrogel Composites with Solvent-Switchable Electronic Properties Pardo-Yissar, V.; Gabai, R.; Shipway, A. N. Advanced Materials, Vol. 13, Issue 17 https://doi.org/10.1002/1521-4095(200109)13:17<1320::AID-ADMA1320>3.0.CO;2-8	journal	September 2001
Thermoswitchable Electronic Properties of a Gold Nanoparticle/Hydrogel Composite Zhao, Xiuli; Ding, Xiaobin; Deng, Zhenghua Macromolecular Rapid Communications, Vol. 26, Issue 22 https://doi.org/10.1002/marc.200500534	journal	November 2005
A kind of smart gold nanoparticle–hydrogel composite with tunable thermo-switchable electrical properties Zhao, Xiuli; Ding, Xiaobin; Deng, Zhenghua New J. Chem., Vol. 30, Issue 6 https://doi.org/10.1039/B601069E	journal	January 2006
Nanoparticle-Hydrogel Composites: Concept, Design, and Applications of These Promising, Multi-Functional Materials Thoniyot, Praveen; Tan, Mein Jin; Karim, Anis Abdul Advanced Science, Vol. 2, Issue 1-2 https://doi.org/10.1002/advs.201400010	journal	January 2015
Formation of a Biomimetic, Liquid-Crystalline Hydrogel by Self-Assembly and Polymerization of an Ionic Liquid Batra, Dolly; Firestone, Millicent A. Chemistry of Materials, Vol. 19, Issue 18 https://doi.org/10.1021/cm062992z	journal	September 2007
Preparation of a self-supporting cell architecture mimic by water channel confined photocrosslinking within a lamellar structured hydrogel Grubjesic, Simonida; Lee, Byeongdu; Seifert, Sönke Soft Matter, Vol. 7, Issue 20 https://doi.org/10.1039/c1sm06364b	journal	January 2011
Multi-length scale evaluation of the temperature-tunable mechanical properties of a lyotropic mesophase Lee, Sungwon; Seifert, Sönke; Firestone, Millicent A. Polymer Journal, Vol. 45, Issue 2 https://doi.org/10.1038/pj.2012.99	journal	July 2012
Immobilization of hexa-arginine tagged esterase onto carboxylated gold nanoparticles Ha, Tai Hwan; Jeong, Jin Young; Chung, Bong Hyun Chemical Communications, Issue 31 https://doi.org/10.1039/b504184h	journal	January 2005
Infrared Spectroscopic Study of the Phases and Phase Transitions in Poly(ethylene oxide) and Poly(ethylene oxide)-Lithium Trifluoromethanesulfonate Complexes Dissanayake, M. A. K. L.; Frech, Roger Macromolecules, Vol. 28, Issue 15 https://doi.org/10.1021/ma00119a022	journal	July 1995
Shape auxiliary approach for carboxylate-functionalized gold nanocrystals Seo, Daeha; Yoo, Choong Il; Chung, Bong Hyun Chemical Communications, Issue 10 https://doi.org/10.1039/b820220f	journal	January 2009
FTIR Spectroscopic Study on Effects of Temperature and Polymer Composition on the Structural Properties of PEO−PPO−PEO Block Copolymer Micelles Su, Yan-lei; Wang, Jing; Liu, Hui-zhou Langmuir, Vol. 18, Issue 14 https://doi.org/10.1021/la020007p	journal	July 2002
Structure and Conformational Dynamics of DMPC/Dicationic Surfactant and DMPC/Dicationic Surfactant/DNA Systems Pietralik, Zuzanna; Krzysztoń, Rafał; Kida, Wojciech International Journal of Molecular Sciences, Vol. 14, Issue 4 https://doi.org/10.3390/ijms14047642	journal	April 2013
Film Architecture in Biomolecular Assemblies. Effect of Linker on the Orientation of Genetically Engineered Surface-Bound Proteins Firestone, Millicent A.; Shank, Mary L.; Sligar, Stephen G. Journal of the American Chemical Society, Vol. 118, Issue 38 https://doi.org/10.1021/ja961046o	journal	January 1996
How PEO-PPO-PEO Triblock Polymer Micelles Control the Synthesis of Gold Nanoparticles: Temperature and Hydrophobic Effects Khullar, Poonam; Mahal, Aabroo; Singh, Vijender Langmuir, Vol. 26, Issue 13 https://doi.org/10.1021/la100734p	journal	July 2010
Mechanism of Gold Metal Ion Reduction, Nanoparticle Growth and Size Control in Aqueous Amphiphilic Block Copolymer Solutions at Ambient Conditions Sakai, Toshio; Alexandridis, Paschalis The Journal of Physical Chemistry B, Vol. 109, Issue 16 https://doi.org/10.1021/jp046221z	journal	April 2005
Real-Time Monitoring of Copolymer Stabilized Growing Gold Nanoparticles Polte, Jörg; Emmerling, Franziska; Radtke, Martin Langmuir, Vol. 26, Issue 8 https://doi.org/10.1021/la903829q	journal	April 2010
Reducing Properties of Polymers in the Synthesis of Noble Metal Nanoparticles Zhang, An-Qi; Cai, Ling-Jian; Sui, Li Polymer Reviews, Vol. 53, Issue 2 https://doi.org/10.1080/15583724.2013.776587	journal	May 2013
Preparation of near-infrared light absorbing gold nanoparticles using polyethylene glycol-attached dendrimers Kojima, Chie; Umeda, Yasuhito; Harada, Atsushi Colloids and Surfaces B: Biointerfaces, Vol. 81, Issue 2 https://doi.org/10.1016/j.colsurfb.2010.07.060	journal	December 2010
Effect of pH on the single-step synthesis of gold nanoparticles using PEO–PPO–PEO triblock copolymers in aqueous media Shou, Qinghui; Guo, Chen; Yang, Liangrong Journal of Colloid and Interface Science, Vol. 363, Issue 2 https://doi.org/10.1016/j.jcis.2011.07.021	journal	November 2011
Charged Gold Nanoparticles in Non-Polar Solvents: 10-min Synthesis and 2D Self-Assembly Martin, Matthew N.; Basham, James I.; Chando, Paul Langmuir, Vol. 26, Issue 10, p. 7410-7417 https://doi.org/10.1021/la100591h	journal	May 2010
A Facile Polyol Route to Uniform Gold Octahedra with Tailorable Size and Their Optical Properties Li, Cuncheng; Shuford, Kevin L.; Chen, Minghai ACS Nano, Vol. 2, Issue 9 https://doi.org/10.1021/nn800264q	journal	August 2008
Understanding the Role of Oxidative Etching in the Polyol Synthesis of Pd Nanoparticles with Uniform Shape and Size Xiong, Yujie; Chen, Jingyi; Wiley, Benjamin Journal of the American Chemical Society, Vol. 127, Issue 20 https://doi.org/10.1021/ja0513741	journal	May 2005
Spatially-Directed Oxidation of Gold Nanoparticles by Au(III)−CTAB Complexes Rodríguez-Fernández, Jessica; Pérez-Juste, Jorge; Mulvaney, Paul The Journal of Physical Chemistry B, Vol. 109, Issue 30 https://doi.org/10.1021/jp052516g	journal	August 2005
5-fold Twinned Nanowires and Single Twinned Right Bipyramids of Pd: Utilizing Small Organic Molecules To Tune the Etching Degree of O ₂ /Halides Lu, Na; Chen, Wei; Fang, Guoyong Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm4042204	journal	March 2014
Green synthesis of polysaccharide/gold nanoparticle nanocomposite: An efficient ammonia sensor Pandey, Sadanand; Goswami, Gopal K.; Nanda, Karuna K. Carbohydrate Polymers, Vol. 94, Issue 1 https://doi.org/10.1016/j.carbpol.2013.01.009	journal	April 2013
Effect of digestive ripening agent on nanoparticle size in the digestive ripening process Sahu, Puspanjali; Prasad, B. L. V. Chemical Physics Letters, Vol. 525-526 https://doi.org/10.1016/j.cplett.2011.12.078	journal	February 2012
Thermal degradation of electrical conductivity of polyacrylic acid doped polyaniline: effect of molecular weight of the dopants Lu, Xuehong; Tan, Chiang Yang; Xu, Jianwei Synthetic Metals, Vol. 138, Issue 3 https://doi.org/10.1016/S0379-6779(02)00471-X	journal	July 2003
Photooxidative degradation of acrylic and methacrylic polymers Chiantore, O.; Trossarelli, L.; Lazzari, M. Polymer, Vol. 41, Issue 5, p. 1657-1668 https://doi.org/10.1016/S0032-3861(99)00349-3	journal	March 2000
Degradation of PEO in the Solid State: A Theoretical Kinetic Model de Sainte Claire, Pascal Macromolecules, Vol. 42, Issue 10 https://doi.org/10.1021/ma802469u	journal	May 2009
Synthesis and Size Control of Gold Nanoparticles Stabilized by Poly(methylphenylphosphazene) Walker, Caroline H.; St. John, John V.; Wisian-Neilson, Patty Journal of the American Chemical Society, Vol. 123, Issue 16 https://doi.org/10.1021/ja005812+	journal	April 2001
Controlled Poly(ethylene glycol) Network Structures through Silsesquioxane Cross-Links Formed by Sol−Gel Reactions Radi, Babak; Wellard, R. Mark; George, Graeme A. Macromolecules, Vol. 43, Issue 23 https://doi.org/10.1021/ma101511p	journal	December 2010
Effects of nanoparticle treatment on the crystallization behavior and mechanical properties of polypropylene/calcium carbonate nanocomposites Wan, Weitao; Yu, Demei; Xie, Yunchuan Journal of Applied Polymer Science, Vol. 102, Issue 4 https://doi.org/10.1002/app.24561	journal	January 2006
Structure development and crystallization behaviour of PP/nanoparticulate composite Saujanya, C.; Radhakrishnan, S. Polymer, Vol. 42, Issue 16 https://doi.org/10.1016/S0032-3861(01)00140-9	journal	July 2001
Two Phase Transitions of Poly( N -isopropylacrylamide) Brushes Bound to Gold Nanoparticles Shan, Jun; Chen, Jie; Nuopponen, Markus Langmuir, Vol. 20, Issue 11 https://doi.org/10.1021/la0363938	journal	May 2004
Enhanced radical scavenging activity by antioxidant-functionalized gold nanoparticles: A novel inspiration for development of new artificial antioxidants Nie, Zhou; Liu, Ke Jian; Zhong, Chuan-Jian Free Radical Biology and Medicine, Vol. 43, Issue 9 https://doi.org/10.1016/j.freeradbiomed.2007.06.011	journal	November 2007
Preparation of high purity, anionic polymerization grade alkyl methacrylate monomers Allen, R. D.; Long, T. E.; McGrath, J. E. Polymer Bulletin, Vol. 15, Issue 2 https://doi.org/10.1007/BF00263389	journal	January 1986
Small-Angle X-ray Scattering Study of the Interaction of Poly(ethylene oxide)- b -Poly(propylene oxide)- b -Poly(ethylene oxide) Triblock Copolymers with Lipid Bilayers Firestone, Millicent A.; Wolf, Amanda C.; Seifert, Sönke Biomacromolecules, Vol. 4, Issue 6 https://doi.org/10.1021/bm034134r	journal	November 2003
Crystallization and melting behavior of low molar weight PEO–PPO–PEO triblock copolymers Zhang, Fajun; Stühn, Bernd Colloid and Polymer Science, Vol. 285, Issue 4 https://doi.org/10.1007/s00396-006-1571-y	journal	November 2006
Hierarchical Structure and Crystal Orientation in Poly(ethylene oxide)/Clay Nanocomposite Films Chu, Che-Yi; Chen, Meng-Hsin; Wu, Mei-Lin Langmuir, Vol. 30, Issue 10 https://doi.org/10.1021/la4042748	journal	March 2014
Morphological Transformation of PS- b -PEO Diblock Copolymer by Selectively Dispersed Colloidal CdS Quantum Dots Yeh, Siao-Wei; Wei, Kung-Hwa; Sun, Ya-Sen Macromolecules, Vol. 36, Issue 21 https://doi.org/10.1021/ma034800g	journal	October 2003
Thermally Reversible Self-Assembly of Nanoparticles via Polymer Crystallization Kinnear, Calum; Balog, Sandor; Rothen-Rutishauser, Barbara Macromolecular Rapid Communications, Vol. 35, Issue 23 https://doi.org/10.1002/marc.201400457	journal	October 2014
Effect of the Lipid Chain Melting Transition on the Stability of DSPE-PEG(2000) Micelles Kastantin, Mark; Ananthanarayanan, Badriprasad; Karmali, Priya Langmuir, Vol. 25, Issue 13 https://doi.org/10.1021/la900310k	journal	July 2009
Thermotropic structural changes of saturated-cationic-lipid–DNA complexes Zantl, R.; Artzner, F.; Rapp, G. Europhysics Letters (EPL), Vol. 45, Issue 1 https://doi.org/10.1209/epl/i1999-00136-9	journal	January 1999
Solvent-Mediated Plasmon Tuning in a Gold-Nanoparticle-Poly(Ionic Liquid) Composite Batra, D.; Seifert, S.; Varela, L. M. Advanced Functional Materials, Vol. 17, Issue 8 https://doi.org/10.1002/adfm.200600797	journal	April 2007
Electron Density Mapping of Triblock Copolymers Associated with Model Biomembranes: Insights into Conformational States and Effect on Bilayer Structure Lee, Byeongdu; Firestone, Millicent A. Biomacromolecules, Vol. 9, Issue 6 https://doi.org/10.1021/bm701348r	journal	June 2008

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