Synthetic strategy for preparing chiral double-semicrystalline polyether block copolymers

McGrath, Alaina J.; Shi, Weichao; Rodriguez, Christina G.; Kramer, Edward J.; Hawker, Craig J.; Lynd, Nathaniel A.

doi:10.1039/c4py01503g

Title: Synthetic strategy for preparing chiral double-semicrystalline polyether block copolymers

Journal Article · Thu Dec 11 00:00:00 EST 2014 · Polymer Chemistry

DOI:https://doi.org/10.1039/c4py01503g· OSTI ID:1346162

McGrath, Alaina J. ^[1]; Shi, Weichao ^[1]; Rodriguez, Christina G. ^[1]; Kramer, Edward J. ^[1]; Hawker, Craig J. ^[1]; Lynd, Nathaniel A. ^[1]

Univ. of California, Santa Barbara, CA (United States)

Here, we report an effective strategy for the synthesis of semi-crystalline block copolyethers with well-defined architecture and stereochemistry. As an exemplary system, triblock copolymers containing either atactic (racemic) or isotactic (R or S) poly(propylene oxide) end blocks with a central poly(ethylene oxide) mid-block were prepared by anionic ring-opening procedures. Stereochemical control was achieved by an initial hydrolytic kinetic resolution of racemic terminal epoxides followed by anionic ring-opening polymerization of the enantiopure monomer feedstock. The resultant triblock copolymers were highly isotactic (meso triads [mm]% ~ 90%) with optical microscopy, differential scanning calorimetry, wide angle x-ray scattering and small angle x-ray scattering being used to probe the impact of the isotacticity on the resultant polymer and hydrogel properties.

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Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1346162

Journal Information:: Polymer Chemistry, Vol. 6, Issue 9; ISSN 1759-9954

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 17 works

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