Mechanism-based design of labile precursors for chromium(I) chemistry

Akturk, Eser S.; Yap, Glenn P. A.; Theopold, Klaus H.

doi:10.1039/c5cc05993c

Mechanism-based design of labile precursors for chromium(I) chemistry

Journal Article · Thu Aug 27 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/c5cc05993c· OSTI ID:1346159

Akturk, Eser S. ^[1]; Yap, Glenn P. A. ^[2]; Theopold, Klaus H. ^[2]

Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry; DOE Office of Scientific and Technical Information (OSTI)
Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry

Here, we report that dinitrogen complexes of the type Tp^R,RCr–N₂–CrTp^R,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – Tp^tBu,MeCr(η²-C₂(SiMe₃)₂) – proved to be much more reactive.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-92ER14273

OSTI ID:: 1346159

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 84 Vol. 51; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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CCDC 1058335: Experimental Crystal Structure Determination: ZUWJEI : (μ2-Dinitrogen-N,N')-bis(hydrogen tris(3-t-butyl-5-isopropylpyrazolyl)borate-N,N',N'')-di-chromium diethyl ether solvate Akturk, Eser; Yap, Glenn; Theopold, Klaus https://doi.org/10.5517/cc14j8vs The current record is supplemented by this dataset	dataset	April 2015
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Mechanism-based design of labile precursors for chromium(I) chemistry

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