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Title: High performance, durable polymers including poly(phenylene)

Patent ·
OSTI ID:1345386

The present invention relates to functionalized polymers including a poly(phenylene) structure. In some embodiments, the polymers and copolymers of the invention include a highly localized concentration of acidic moieties, which facilitate proton transport and conduction through networks formed from these polymers. In addition, the polymers can include functional moieties, such as electron-withdrawing moieties, to protect the polymeric backbone, thereby extending its durability. Such enhanced proton transport and durability can be beneficial for any high performance platform that employs proton exchange polymeric membranes, such as in fuel cells or flow batteries.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation
Patent Number(s):
9,580,541
Application Number:
14/933,981
OSTI ID:
1345386
Resource Relation:
Patent File Date: 2015 Nov 05
Country of Publication:
United States
Language:
English

References (32)

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Poly(phenylene)-based anion exchange membrane patent February 2011
Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes patent February 2012
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Anion exchange polymer electrolytes patent September 2013
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Anion exchange polymer electrolytes patent June 2015
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Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells journal November 2009
Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations
  • Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742 https://doi.org/10.1002/polb.23149
journal August 2012
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Evaluation of hydrogen and methanol fuel cell performance of sulfonated diels alder poly(phenylene) membranes journal January 2010
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