Predicting oxidation-limited lifetime of thin-walled components of NiCrW alloy 230

Duan, R.; Jalowicka, Aleksandra; Unocic, Kinga A.; Pint, Bruce A.; Huczkowski, P.; Chyrkin, Anton; Gruner, D.; Pillai, R.; Quadakkers, Willem Joseph

doi:10.1007/s11085-016-9653-9

Title: Predicting oxidation-limited lifetime of thin-walled components of NiCrW alloy 230

Journal Article · Tue Oct 18 00:00:00 EDT 2016 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-016-9653-9· OSTI ID:1344986

Duan, R. ^[1]; Jalowicka, Aleksandra ^[1]; Unocic, Kinga A. ^[2]; Pint, Bruce A. ^[2]; Huczkowski, P. ^[1]; Chyrkin, Anton ^[1]; Gruner, D. ^[1]; Pillai, R. ^[1]; Quadakkers, Willem Joseph ^[1]

Forschungszentrum Julich GmbH, Julich (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Using alloy 230 as an example, a generalized oxidation lifetime model for chromia-forming Ni-base wrought alloys is proposed, which captures the most important damaging oxidation effects relevant for component design: wall thickness loss, scale spallation, and the occurrence of breakaway oxidation. For deriving input parameters and for verification of the model approach, alloy 230 specimens with different thicknesses were exposed for different times at temperatures in the range 950–1050 °C in static air. The studies focused on thin specimens (0.2–0.5 mm) to obtain data for critical subscale depletion processes resulting in breakaway oxidation within reasonably achievable test times up to 3000 h. The oxidation kinetics and oxidation-induced subscale microstructural changes were determined by combining gravimetric data with results from scanning electron microscopy with energy dispersive X-ray spectroscopy. The modeling of the scale spallation and re-formation was based on the NASA cyclic oxidation spallation program, while a new model was developed to describe accelerated oxidation occurring after longer exposure times in the thinnest specimens. The calculated oxidation data were combined with the reservoir model equation, by means of which the relation between the consumption and the remaining concentration of Cr in the alloy was established as a function of temperature and specimen thickness. Based on this approach, a generalized lifetime diagram is proposed, in which wall thickness loss is plotted as a function of time, initial specimen thickness, and temperature. As a result, the time to reach a critical Cr level at the scale/alloy interface of 10 wt% is also indicated in the diagrams.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344986

Journal Information:: Oxidation of Metals, Vol. 87, Issue 1-2; ISSN 0030-770X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 30 works

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References (48)

The oxidation of finite samples of heat-resistant alloys Whittle, D. P. Corrosion Science, Vol. 12, Issue 11 https://doi.org/10.1016/S0010-938X(72)80016-7	journal	January 1972
Compositional changes in the underlying alloy during the protective oxidation of alloys Whittle, D. P.; Evans, D. J.; Scully, D. B. Acta Metallurgica, Vol. 15, Issue 9 https://doi.org/10.1016/0001-6160(67)90173-3	journal	September 1967
Effect of Specimen Thickness on Microstructural Changes During Oxidation of the NiCrW Alloy 230 at 950–1050°C Jalowicka, A.; Duan, R.; Huczkowski, P. JOM, Vol. 67, Issue 11 https://doi.org/10.1007/s11837-015-1645-8	journal	September 2015
Kinetics, Microstructures and Mechanism of Internal Oxidation - Its Effect and Prevention in High Temperature Alloy Oxidation Rapp, Robert A. CORROSION, Vol. 21, Issue 12 https://doi.org/10.5006/0010-9312-21.12.382	journal	December 1965
Mechanisms of Oxide Scale Formation on Ferritic Interconnect Steel in Simulated Low and High pO2 Service Environments of Solid Oxide Fuel Cells Niewolak, L.; Young, D. J.; Hattendorf, H. Oxidation of Metals, Vol. 82, Issue 1-2 https://doi.org/10.1007/s11085-014-9481-8	journal	June 2014
Effect of Element Diffusion Through Metallic Networks During Oxidation of Type 321 Stainless Steel Zeng, Z.; Natesan, K.; Cai, Z. Journal of Materials Engineering and Performance, Vol. 23, Issue 4 https://doi.org/10.1007/s11665-014-0909-8	journal	February 2014
Oxidation Limited Lifetime of Ni-Base Metal Foams in the Temperature Range 700-900 °C Chyrkin, Anton; Schulze, Sebastian Leif; Pirón-Abellán, Javier Advanced Engineering Materials, Vol. 12, Issue 9 https://doi.org/10.1002/adem.201000139	journal	September 2010
COSP: A computer model of cyclic oxidation Lowell, Carl E.; Barrett, Charles A.; Palmer, Raymond W. Oxidation of Metals, Vol. 36, Issue 1-2 https://doi.org/10.1007/BF00938457	journal	August 1991
Alloy depletion profiles resulting from the preferential removal of the less noble metal during alloy oxidation Bastow, B. D.; Whittle, D. P.; Wood, G. C. Oxidation of Metals, Vol. 12, Issue 5 https://doi.org/10.1007/BF00612088	journal	October 1978
Advanced alloys for compact, high-efficiency, high-temperature heat-exchangers Maziasz, P.; Pint, B.; Shingledecker, J. International Journal of Hydrogen Energy, Vol. 32, Issue 16 https://doi.org/10.1016/j.ijhydene.2006.08.018	journal	November 2007
Cyclic Oxidation of Chromia-Scale Forming Alloys: Lifetime Prediction and Accounting for the Effects of Major and Minor Alloying Additions Gleeson, Brian; Li, Bing Tao Materials Science Forum, Vol. 461-464 https://doi.org/10.4028/www.scientific.net/MSF.461-464.427	journal	August 2004
Practical Aspects of the Reactive Element Effect Quadakkers, Joe; Singheiser, Lorenz Materials Science Forum, Vol. 369-372 https://doi.org/10.4028/www.scientific.net/MSF.369-372.77	journal	October 2001
The prediction of breakaway oxidation for alumina forming ODS alloys using oxidation diagrams Quadakkers, W. J.; Bongartz, K. Materials and Corrosion/Werkstoffe und Korrosion, Vol. 45, Issue 4 https://doi.org/10.1002/maco.19940450404	journal	April 1994
Predicting Internal Oxidation: Building on the Wagner Model Young, David J. Materials Science Forum, Vol. 696 https://doi.org/10.4028/www.scientific.net/MSF.696.1	journal	September 2011
Factors governing breakaway oxidation of FeCrAl-based alloys Gurrappa, I.; Weinbruch, S.; Naumenko, D. Materials and Corrosion, Vol. 51, Issue 4 https://doi.org/10.1002/(SICI)1521-4176(200004)51:4<224::AID-MACO224>3.0.CO;2-B	journal	April 2000
Oxidation-related life-time assessment using the new ISO standards ISO 21608:2012 and ISO 26146:2012: Life-time assessment using new ISO standards Schütze, M.; Schmidt, G. T.; Naji, A. Materials and Corrosion, Vol. 67, Issue 1 https://doi.org/10.1002/maco.201508599	journal	October 2015
Why the Growth Rates of Alumina and Chromia Scales on Thin Specimens Differ from those on Thick Specimens Quadakkers, W. Joe; Huczkowski, P.; Naumenko, D. Materials Science Forum, Vol. 595-598 https://doi.org/10.4028/www.scientific.net/MSF.595-598.1111	journal	September 2008
High-temperature oxidation behavior of a wrought Ni-Cr-W-Mn-Si-La alloy Tawancy, H. M. Oxidation of Metals, Vol. 45, Issue 3-4 https://doi.org/10.1007/BF01046988	journal	April 1996
Comparison of isothermal and cyclic oxidation behavior of twenty-five commercial sheet alloys at 1150�C Barrett, Charles A.; Lowell, Carl E. Oxidation of Metals, Vol. 9, Issue 4 https://doi.org/10.1007/BF00613534	journal	August 1975
Stress effects in high temperature oxidation of metals Evans, H. E. International Materials Reviews, Vol. 40, Issue 1 https://doi.org/10.1179/imr.1995.40.1.1	journal	January 1995
Effect of specimen thickness on the growth rate of chromia scales on Ni-base alloys in high- and low-pO2 gases Zurek, J.; Meier, G. H.; Essuman, E. Journal of Alloys and Compounds, Vol. 467, Issue 1-2 https://doi.org/10.1016/j.jallcom.2007.12.015	journal	January 2009
Oxidation Behavior of Fe–25Cr–20Ni–2.8Si During Isothermal Oxidation at 1,286 K; Life-time Prediction Bauer, R.; Baccalaro, M.; Jeurgens, L. P. H. Oxidation of Metals, Vol. 69, Issue 3-4 https://doi.org/10.1007/s11085-008-9097-y	journal	February 2008
Thickness influence on creep properties for Ni-based superalloy M247LC SX Brunner, Martin; Bensch, Matthias; Völkl, Rainer Materials Science and Engineering: A, Vol. 550 https://doi.org/10.1016/j.msea.2012.04.067	journal	July 2012
Growth mechanism of Cr2O3 scales: oxygen and chromium diffusion, oxidation kinetics and effect of yttrium Tsai, S. C.; Huntz, A. M.; Dolin, C. Materials Science and Engineering: A, Vol. 212, Issue 1 https://doi.org/10.1016/0921-5093(96)10173-8	journal	July 1996
Cyclic Oxidation Kinetics Modeling of NiAl Single Crystal Poquillon, Dominique; Oquab, Djar; Monceau, Daniel Materials Science Forum, Vol. 461-464 https://doi.org/10.4028/www.scientific.net/MSF.461-464.737	journal	August 2004
Predicting the depletion of chromium in two high temperature Ni alloys Pillai, R.; Ackermann, H.; Lucka, K. Corrosion Science, Vol. 69 https://doi.org/10.1016/j.corsci.2012.11.040	journal	April 2013
Effect of Specimen Thickness on the Oxidation Rate of High Chromium Ferritic Steels: The Significance of Intrinsic Alloy Creep Strength Asensio-Jimenez, Cristina; Niewolak, Leszek; Hattendorf, Heike Oxidation of Metals, Vol. 79, Issue 1-2 https://doi.org/10.1007/s11085-012-9323-5	journal	December 2012
Failure mechanisms of thermal barrier coatings on MCrAlY-type bondcoats associated with the formation of the thermally grown oxide Naumenko, Dmitry; Shemet, Vladimir; Singheiser, Lorenz Journal of Materials Science, Vol. 44, Issue 7 https://doi.org/10.1007/s10853-009-3284-3	journal	April 2009
Chromia layer growth on a Ni-based superalloy: Sub-parabolic kinetics and the role of titanium Cruchley, S.; Evans, H. E.; Taylor, M. P. Corrosion Science, Vol. 75 https://doi.org/10.1016/j.corsci.2013.05.016	journal	October 2013
A finite-difference model to predict 2D depletion profiles arising from high temperature oxidation of alloys Pragnell, W. M.; Evans, H. E. Modelling and Simulation in Materials Science and Engineering, Vol. 14, Issue 4 https://doi.org/10.1088/0965-0393/14/4/014	journal	May 2006
The Influence of Specimen Thickness on the High Temperature Corrosion Behavior of CMSX-4 during Thermal-Cycling Exposure Orosz, R.; Krupp, U.; Christ, H. -J. Oxidation of Metals, Vol. 68, Issue 3-4 https://doi.org/10.1007/s11085-007-9067-9	journal	August 2007
Mechanisms of Breakaway Oxidation and Application to a Chromia-Forming Steel Evans, H. E.; Donaldson, A. T.; Gilmour, T. C. Oxidation of Metals, Vol. 52, Issue 5/6, p. 379-402 https://doi.org/10.1023/A:1018855914737	journal	January 1999
Oxidation limited life times of chromia forming ferritic steels Huczkowski, P.; Shemet, V.; Piron-Abellan, J. Materials and Corrosion, Vol. 55, Issue 11 https://doi.org/10.1002/maco.200303798	journal	November 2004
Predicting Minimum Aluminum Concentrations for Protective Scale Formation on Ni-Base Alloys Nesbitt, J. A. Journal of The Electrochemical Society, Vol. 136, Issue 5 https://doi.org/10.1149/1.2096954	journal	January 1989
Tensile cracking of a chromia layer on a stainless steel during thermal cycling with hold periods Osgerby, S.; Berriche-Bouhanek, K.; Evans, H. E. Materials Science and Engineering: A, Vol. 412, Issue 1-2 https://doi.org/10.1016/j.msea.2005.08.193	journal	December 2005
The Creep Rupture Properties of 9% Chromium Steels and the Influence of Oxidation on Strength Nickel, H.; Ennis, P. J.; Quadakkers, W. J. Mineral Processing and Extractive Metallurgy Review, Vol. 22, Issue 1 https://doi.org/10.1080/08827509808962495	journal	January 2001
Test methods and data on the mechanical properties of protective oxide scales Schütze, M.; Ito, S.; Przybilla, W. Materials at High Temperatures, Vol. 18, Issue 1 https://doi.org/10.3184/096034001783640685	journal	February 2001
High temperature creep behaviour of an Ni-Cr-W-B alloy Tawancy, H. M. Journal of Materials Science, Vol. 27, Issue 23 https://doi.org/10.1007/BF00576301	journal	February 1992
A deterministic interfacial cyclic oxidation spalling model Smialek, James L. Acta Materialia, Vol. 51, Issue 2 https://doi.org/10.1016/S1359-6454(02)00430-5	journal	January 2003
Conditions for the initiation of oxide-scale cracking and spallation Evans, H. E.; Lobb, R. C. Corrosion Science, Vol. 24, Issue 3 https://doi.org/10.1016/0010-938X(84)90051-9	journal	January 1984
Growth mechanisms of oxide scales on ODS alloys in the temperature range 1000-1100°C Quadakkers, W. J. Materials and Corrosion/Werkstoffe und Korrosion, Vol. 41, Issue 12 https://doi.org/10.1002/maco.19900411204	journal	December 1990
Oxidation behaviour of Fe-Cr-Al alloys during resistance and furnace heating Echsler, H.; Hattendorf, H.; Singheiser, L. Materials and Corrosion, Vol. 57, Issue 2 https://doi.org/10.1002/maco.200503897	journal	February 2006
Effect of selective oxidation of chromium on creep strength of Alloy 617 Ennis, P. J.; Quadakkers, W. J.; Schuster, H. Materials Science and Technology, Vol. 8, Issue 1 https://doi.org/10.1179/026708392790169812	journal	January 1992
Creep relaxation and the spallation of oxide layers Evans, H. E.; Taylor, M. P. Surface and Coatings Technology, Vol. 94-95 https://doi.org/10.1016/S0257-8972(97)00471-4	journal	October 1997
A Simple Expression for Predicting the Oxidation Limited Life of Thin Components Manufactured from FCC High Temperature Alloys Young, D. J.; Chyrkin, A.; Quadakkers, W. J. Oxidation of Metals, Vol. 77, Issue 5-6 https://doi.org/10.1007/s11085-012-9283-9	journal	January 2012
Effect of thermal cycling on protective properties of alumina scale grown on thin Haynes 214 foil Chyrkin, A.; Mortazavi, N.; Halvarsson, M. Corrosion Science, Vol. 98 https://doi.org/10.1016/j.corsci.2015.06.020	journal	September 2015
The Development of High-Strength Alloys Resistant to Corrosion in Impure Helium Dean, A. V.; Ennis, Philip J. Nuclear Technology, Vol. 66, Issue 1 https://doi.org/10.13182/NT84-A33460	journal	July 1984
Creep Properties of lnconel-617 in Air and Helium at 800 to 1000°C Cook, Roger H. Nuclear Technology, Vol. 66, Issue 2 https://doi.org/10.13182/NT84-A33431	journal	August 1984

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Title: Predicting oxidation-limited lifetime of thin-walled components of NiCrW alloy 230

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