Experimental determination of solubilities of di-calcium ethylenediaminetetraacetic acid hydrate [Ca2C10H12N2O8·7H2O(s)] in NaCl and MgCl2 solutions to high ionic strengths and its Pitzer model: Applications to geological disposal of nuclear waste and other low temperature environments

Xiong, Yongliang; Kirkes, Leslie; Westfall, Terry

doi:10.1016/j.chemgeo.2017.01.025

Experimental determination of solubilities of di-calcium ethylenediaminetetraacetic acid hydrate [Ca2C10H12N2O8·7H2O(s)] in NaCl and MgCl2 solutions to high ionic strengths and its Pitzer model: Applications to geological disposal of nuclear waste and other low temperature environments

Journal Article · Sat Apr 01 00:00:00 EDT 2017 · Chemical Geology

DOI:https://doi.org/10.1016/j.chemgeo.2017.01.025· OSTI ID:1344455

Xiong, Yongliang; Kirkes, Leslie; Westfall, Terry

In this study, solubility measurements on di-calcium ethylenediaminetetraacetic acid [Ca₂C₁₀H₁₂N₂O₈(s), abbreviated as Ca₂EDTA(s)] as a function of ionic strength are conducted in NaCl solutions up to I = 5.0 mol•kg^–1 and in MgCl₂ solutions up to I = 7.5 mol•kg^–1, at room temperature (22.5 ± 0.5oC).

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1344455

Alternate ID(s):: OSTI ID: 1344466
OSTI ID: 1397635

Report Number(s):: SAND--2016-1275J; SAND2016-1275J; 619421

Journal Information:: Chemical Geology, Journal Name: Chemical Geology Journal Issue: C Vol. 454; ISSN 0009-2541

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (28)

An aqueous thermodynamic model for a high valence 4?2 electrolyte Th4+?SO 4 2? in the system Na+?K+?Li+?NH 4 + ?Th4+?SO 4 2? ?HSO 4 ? ?H2O to high concentration Felmy, Andrew R.; Rai, Dhanpat Journal of Solution Chemistry, Vol. 21, Issue 5 https://doi.org/10.1007/BF00649695	journal	May 1992
Experimental determination of lead carbonate solubility at high ionic strengths: a Pitzer model description Xiong, Yongliang Monatshefte für Chemie - Chemical Monthly, Vol. 146, Issue 9 https://doi.org/10.1007/s00706-015-1483-y	journal	May 2015
An Aqueous Thermodynamic Model for the Solubility of Potassium Ferrate in Alkaline Solutions to High Ionic Strengths from 283.15 to 333.15 K Xiong, Yongliang Journal of Solution Chemistry, Vol. 42, Issue 7 https://doi.org/10.1007/s10953-013-0038-2	journal	July 2013
Removal of trace and major metals by soil washing with Na2EDTA and oxalate Qiu, Rongliang; Zou, Zeli; Zhao, Zhihao Journal of Soils and Sediments, Vol. 10, Issue 1 https://doi.org/10.1007/s11368-009-0083-z	journal	April 2009
Zur pharmakologischen Wirkung einiger anorganischorganischer Komplexverbindungen Bersin, Th.; Müller, A.; Schwarz, H. Archives of Biochemistry and Biophysics, Vol. 69 https://doi.org/10.1016/0003-9861(57)90515-5	journal	January 1957
The prediction of mineral solubilities in natural waters: The Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O system to high ionic strengths at 25°C Harvie, Charles E.; Møller, Nancy; Weare, John H. Geochimica et Cosmochimica Acta, Vol. 48, Issue 4 https://doi.org/10.1016/0016-7037(84)90098-X	journal	April 1984
New aspects of the reaction of silver(I) cations with the ethylenediaminetetraacetate ion Saran, Luciana; Cavalheiro, Eder; Neves, Eduardo Almeida Talanta, Vol. 42, Issue 12 https://doi.org/10.1016/0039-9140(95)01692-9	journal	December 1995
Speciation and fate of ethylenediaminetetraacetate (EDTA) in municipal wastewater treatment Kari, Franz Guenter; Giger, Walter Water Research, Vol. 30, Issue 1 https://doi.org/10.1016/0043-1354(95)00125-5	journal	January 1996
The dependence of the acidity constants of silicic acid on NaCl concentration using Pitzer's equations Hershey, J. Peter; Millero, Frank J. Marine Chemistry, Vol. 18, Issue 1 https://doi.org/10.1016/0304-4203(86)90079-4	journal	February 1986
Determination of the solubility products of nitrilotriacetic acid, ethylenediaminetetraacetic acid and diethylenetriaminepentaacetic acid Karhu, Jouni; Harju, Leo; Ivaska, Ari Analytica Chimica Acta, Vol. 380, Issue 1 https://doi.org/10.1016/S0003-2670(98)00657-6	journal	January 1999
Contribution to a utilitarian classification of gypsiferous soil Boyadgiev, T. G.; Verheye, W. H. Geoderma, Vol. 74, Issue 3-4 https://doi.org/10.1016/S0016-7061(96)00074-2	journal	December 1996
Experimental investigations of the reaction path in the MgO–CO2–H2O system in solutions with various ionic strengths, and their applications to nuclear waste isolation Xiong, Yongliang; Lord, Anna Snider Applied Geochemistry, Vol. 23, Issue 6 https://doi.org/10.1016/j.apgeochem.2007.12.035	journal	June 2008
Solubility of Fe2(OH)3Cl (pure-iron end-member of hibbingite) in NaCl and Na2SO4 brines Nemer, Martin B.; Xiong, Yongliang; Ismail, Ahmed E. Chemical Geology, Vol. 280, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2010.10.003	journal	January 2011
Recycling EDTA solutions used to remediate metal-polluted soils Zeng, Q. R.; Sauvé, S.; Allen, H. E. Environmental Pollution, Vol. 133, Issue 2 https://doi.org/10.1016/j.envpol.2004.06.006	journal	January 2005
Experimental determination of the solubility constant for magnesium chloride hydroxide hydrate (Mg3Cl(OH)5·4H2O, phase 5) at room temperature, and its importance to nuclear waste isolation in geological repositories in salt formations Xiong, Yongliang; Deng, Haoran; Nemer, Martin Geochimica et Cosmochimica Acta, Vol. 74, Issue 16 https://doi.org/10.1016/j.gca.2010.05.029	journal	August 2010
Improved thermodynamic model for interaction of EDTA with trivalent actinides and lanthanide to ionic strength of 6.60m Thakur, Punam; Xiong, Yongliang; Borkowski, Marian Geochimica et Cosmochimica Acta, Vol. 133 https://doi.org/10.1016/j.gca.2013.09.040	journal	May 2014
The Ca2+–EDTA chelation as standard reaction to validate Isothermal Titration Calorimeter measurements (ITC) Ràfols, Clara; Bosch, Elisabeth; Barbas, Rafael Talanta, Vol. 154 https://doi.org/10.1016/j.talanta.2016.03.075	journal	July 2016
Persistence and Potential Effects of Complex Organic Contaminant Mixtures in Wastewater-Impacted Streams Barber, Larry B.; Keefe, Steffanie H.; Brown, Greg K. Environmental Science & Technology, Vol. 47, Issue 5 https://doi.org/10.1021/es303720g	journal	February 2013
Thermodynamic Quantities Associated with the Interaction between Ethylenediaminetetraacetate and Alkaline Earth Ions Carini, Francis F.; Martell, Arthur E. Journal of the American Chemical Society, Vol. 76, Issue 8 https://doi.org/10.1021/ja01637a032	journal	April 1954
Additivity and the Physical Basis of Multivalency Effects: A Thermodynamic Investigation of the Calcium EDTA Interaction Christensen, Trine; Gooden, David M.; Kung, Joyce E. Journal of the American Chemical Society, Vol. 125, Issue 24 https://doi.org/10.1021/ja021240c	journal	June 2003
Solubility of Alkali and Alkali Earth Salts of Dihydrogen Ethylenediaminetetraacetate in Aqueous Solutions Fiorucci, Antonio R.; de Paula, Leonardo R.; Neves, Eduardo A. Journal of Chemical & Engineering Data, Vol. 47, Issue 6 https://doi.org/10.1021/je025550m	journal	November 2002
Removal of Heavy Metals from Calcareous Contaminated Soils by EDTA Leaching Papassiopi, N.; Tambouris, S.; Kontopoulos, A. Water, Air, and Soil Pollution, Vol. 109, Issue 1/4, p. 1-15 https://doi.org/10.1023/A:1005089515217	journal	January 1999
Selective Removal of Lead from Calcareous Polluted Soils using the Ca-EDTA Salt Theodoratos, P.; Papassiopi, N.; Georgoudis, T. Water, Air, and Soil Pollution, Vol. 122, Issue 3/4, p. 351-368 https://doi.org/10.1023/A:1005295119231	journal	January 2000
Study on Optimal Conditions for Recovery of EDTA from Soil Washing Effluents Lo, Irene M.; Zhang, Weihua Journal of Environmental Engineering, Vol. 131, Issue 11 https://doi.org/10.1061/(ASCE)0733-9372(2005)131:11(1507)	journal	November 2005
The aqueous geochemistry of thallium: speciation and solubility of thallium in low temperature systems Xiong, Yongliang Environmental Chemistry, Vol. 6, Issue 5 https://doi.org/10.1071/EN08086	journal	January 2009
Extractability of Zinc, Cadmium, and Nickel in Soils Amended with edta Li, Zhenbin; Shuman, Larry M. Soil Science, Vol. 161, Issue 4 https://doi.org/10.1097/00010694-199604000-00003	journal	January 1996
Experimental determination of solubilities of sodium tetraborate (borax) in NaCl solutions, and a thermodynamic model for the Na-B(OH)3-Cl-SO4 system to high-ionic strengths at 25 C Xiong, Y.; Kirkes, L.; Westfall, T. American Mineralogist, Vol. 98, Issue 11-12 https://doi.org/10.2138/am.2013.4398	journal	November 2013
Waste Isolation Pilot Plant Actinide Source Term Test Program: Solubility Studies and Development of Modeling Parameters Choppin, Gregory; Bond, Andrew; Borkowski, Marian https://doi.org/10.2172/782587	report	April 2001

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Experimental determination of solubilities of di-calcium ethylenediaminetetraacetic acid hydrate [Ca2C10H12N2O8·7H2O(s)] in NaCl and MgCl2 solutions to high ionic strengths and its Pitzer model: Applications to geological disposal of nuclear waste and other low temperature environments

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