Pulsed-field magnetization of frustrated S = 1/2 Cu(pyrimidine)1.5(H2O)(BF4)2
- Eastern Washington Univ., Cheney, WA (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Univ. of Warwick, Coventry (United Kingdom)
Cu(pym)1.5(H2O)(BF4)2 (pym = pyrimidine) was synthesized and its structure determined by synchrotron single crystal X-ray diffraction. The compound contains S = 1/2 Cu(II) ions arranged in a distorted triangular array (Fig. 1). Each Cu(II) ion is coordinated to three pym ligands, two weakly held BF4- anions and one H2O. To get a sense to the extent (i.e., strength) of possible frustrated exchange interactions in this new compound we measured the magnetization of Cu(pym)1.5(H2O)(BF4)2 in pulsed magnetic fields up to 60 T.
- Research Organization:
- Los Alamos National Laboratory (LANL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC52-06NA25396
- OSTI ID:
- 1343723
- Report Number(s):
- LA-UR-17-21119
- Country of Publication:
- United States
- Language:
- English
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