Morphological Consequences of Frustration in ABC Triblock Polymers

Radlauer, Madalyn R.; Sinturel, Christophe; Asai, Yusuke; Arora, Akash; Bates, Frank S.; Dorfman, Kevin D.; Hillmyer, Marc A.

doi:10.1021/acs.macromol.6b02112

Morphological Consequences of Frustration in ABC Triblock Polymers

Journal Article · Mon Dec 19 00:00:00 EST 2016 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.6b02112· OSTI ID:1343138

^[1]; Sinturel, Christophe ^[2]; Asai, Yusuke ^[3]; Arora, Akash ^[1]; ^[1]; Dorfman, Kevin D. ^[1]; ^[1]

Univ. of Minnesota, Minneapolis, MN (United States)
Univ. d’Orléans (France)
Nagoya Univ. (Japan)

In this work, three poly(styrene)-block-poly(isoprene)-block-poly(lactide) (PS-b-PI-b-PLA, SIL) triblock terpolymers were synthesized and characterized in the bulk and as thin films. The pronounced incompatibility of the covalently connected PI and PLA led to significant frustration and the tendency to minimize their intermaterial dividing surface area. This resulted in the formation of a core–shell cylinder morphology with exaggerated nonconstant mean curvature from triblock polymers with equal block volume fractions rather than the more typical lamellar morphology. The effect of frustration was magnified in thin films by both confinement and interfacial interactions such that the PI domains became discontinuous. Self-consistent field theory (SCFT) calculations emphasize that the marked difference in the PS/PI and PI/PLA interaction parameters promotes the formation of nonlamellar morphologies. However, SCFT predicts that lamellar morphology is more stable than the observed cylindrical morphology, demonstrating a limitation that arises from the underlying assumptions.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Camille and Henry Dreyfus Foundation; Ministry of Education, Culture, Sports, Science and Technology (MEXT); National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1343138

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 1 Vol. 50; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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