Impact of hydrogen bonding on dynamics of hydroxyl-terminated polydimethylsiloxane

Xing, Kunyue; Chatterjee, Sabornie; Saito, Tomonori; Gainaru, Catalin P.; Sokolov, Alexei P.

doi:10.1021/acs.macromol.6b00262

Impact of hydrogen bonding on dynamics of hydroxyl-terminated polydimethylsiloxane

Journal Article · Wed Apr 06 00:00:00 EDT 2016 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.6b00262· OSTI ID:1342694

Xing, Kunyue ^[1]; Chatterjee, Sabornie ^[1]; Saito, Tomonori ^[2]; Gainaru, Catalin P. ^[3]; Sokolov, Alexei P. ^[4]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Technische Univ. Dortmund, Dortmund (Germany)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Dielectric spectroscopy, rheology, and differential scanning calorimetry were employed to study the effect of chain-end hydrogen bonding on the dynamics of hydroxylterminated polydimethylsiloxane. We demonstrate that hydrogen bonding has a strong influence on both segmental and slower dynamics in the systems with low molecular weights. In particular, the decrease in the chain length leads to an increase of the glass transition temperature, viscosity, and fragility index, at variance with the usual behavior of nonassociating polymers. The supramolecular association of hydroxylterminated chains leads to the emergence in dielectric and mechanical relaxation spectra of the so-called Debye process traditionally observed in monohydroxy alcohols. Our analysis suggests that the hydroxyl-terminated PDMS oligomers may associate in brush-like or chain-like structures, depending on the size of their covalent chains. Finally, the effective length of the linear-associated chains was estimated from the rheological measurements.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1342694

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 8 Vol. 49; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Debye process
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Impact of hydrogen bonding on dynamics of hydroxyl-terminated polydimethylsiloxane

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