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Comprehensive Isotopic and Elemental Analysis of a Multi-Oxide Glass By Multicollector ICP-MS in Isotope Substitution Studies

Journal Article · · Journal of Chromatography & Separation Techniques

Multicollector ICP-MS was used to comprehensively analyze different types of isotopically-modified glass created in order to investigate the processes of glass corrosion in the water. The analytical methods were developed for the analyses of synthesized, isotopically-modified solid glass and the release of glass constituents upon contact with deionized water. To validate the methods, results from an acid digestion sample of the Analytical Reference Glass (ARG) showed good agreement when compared to data from multiple prior analyses on the same glass [Smith-1]. In this paper, we present the results of this comprehensive analysis from the acid digestion of six types of isotopically-modified glass and the release of glass constituents into water corrosion after one year of aqueous corrosion.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1342318
Report Number(s):
PNNL-SA--111131; AF5805010
Journal Information:
Journal of Chromatography & Separation Techniques, Journal Name: Journal of Chromatography & Separation Techniques Journal Issue: 02 Vol. 07; ISSN 2157-7064
Publisher:
OMICS International
Country of Publication:
United States
Language:
English

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