Surface/interface effects on high-performance thin-film all-solid-state Li-ion batteries

Gong, Chen; Ruzmetov, Dmitry; Pearse, Alexander; Ma, Dakang; Munday, Jeremy N.; Rubloff, Gary; Talin, A. Alec; Leite, Marina S.

doi:10.1021/acsami.5b07058

Title: Surface/interface effects on high-performance thin-film all-solid-state Li-ion batteries

Journal Article · Mon Oct 05 00:00:00 EDT 2015 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.5b07058· OSTI ID:1341747

Gong, Chen ^[1]; Ruzmetov, Dmitry ^[2]; Pearse, Alexander ^[1]; Ma, Dakang ^[1]; Munday, Jeremy N. ^[1]; Rubloff, Gary ^[1]; Talin, A. Alec ^[3]; Leite, Marina S. ^[1]

Univ. of Maryland, College Park, MD (United States)
U.S. Army Research Lab., Adelphi, MD (United States); National Institute of Standards and Technology, Gaithersburg, MD (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)

The further development of all-solid-state batteries is still limited by the understanding/engineering of the interfaces formed upon cycling. Here, we correlate the morphological, chemical, and electrical changes of the surface of thin-film devices with Al negative electrodes. The stable Al–Li–O alloy formed at the stress-free surface of the electrode causes rapid capacity fade, from 48.0 to 41.5 μAh/cm² in two cycles. Surprisingly, the addition of a Cu capping layer is insufficient to prevent the device degradation. Furthermore, Si electrodes present extremely stable cycling, maintaining >92% of its capacity after 100 cycles, with average Coulombic efficiency of 98%.

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Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC04-94AL85000; SC0001160

OSTI ID:: 1341747

Report Number(s):: SAND-2016-12381J; 649746

Journal Information:: ACS Applied Materials and Interfaces, Vol. 7, Issue 47; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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