Competing exchange interactions in multiferroic and ferrimagnetic CaBaCo4O7

Fishman, R. S.; Bordács, S.; Kocsis, V.; Kézsmárki, I.; Viirok, J.; Nagel, U.; Rõõm, T.; Puri, A.; Zeitler, U.; Tokunaga, Y.; Taguchi, Y.; Tokura, Y.

doi:10.1103/PhysRevB.95.024423

Title: Competing exchange interactions in multiferroic and ferrimagnetic ${CaBaCo}_{4} O_{7}$

Journal Article · Mon Jan 23 00:00:00 EST 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.95.024423· OSTI ID:1341532

Fishman, R. S. ^[1]; Bordács, S. ^[2]; Kocsis, V. ^[2]; Kézsmárki, I. ^[2]; Viirok, J. ^[3]; Nagel, U. ^[3]; Rõõm, T. ^[3]; Puri, A. ^[4]; Zeitler, U. ^[4]; Tokunaga, Y. ^[5]; Taguchi, Y. ^[5]; Tokura, Y. ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Budapest University of Technology and Economics and MTA-BME Lendulet Magneto-optical Spectroscopy Research Group (Hungary)
National Institute of Chemical Physics and Biophysics (Estonia)
Radboud University Nijmegen (The Netherlands). High Field Magnet Laboratory (HFML-EMFL)
RIKEN Center for Emergent Matter Science (CEMS), Wako (Japan)

Competing exchange interactions can produce complex magnetic states together with spin-induced electric polarizations. With competing interactions on alternating triangular and kagome layers, the swedenborgite CaBaCo₄O₇ may have one of the largest measured spin-induced polarizations of ~1700 nC/cm² below its ferrimagnetic transition temperature at 70 K. Upon rotating our sample about c = [0,0,1] while the magnetic field is fixed along [1,0,0], the threefold splitting of the spin-wave frequencies indicates that our sample is hexagonally twinned. In addition, magnetization measurements then suggest that roughly 20% of the sample is in a domain with the a axis along [1,0,0] and that 80% of the sample is in one of two other domains with the a axis along either [-1/2,√3/2, 0] or [-1/2, -√3/2, 0] . Powder neutron-diffraction data, magnetization measurements, and terahertz (THz) absorption spectroscopy reveal that the complex spin order in each domain can be described as a triangular array of bitetrahedral c-axis chains ferrimagnetically coupled to each other in the ab plane. In conclusion, the electric-field dependence of bonds coupling those chains produces the large spin-induced polarization of CaBaCo₄O₇ .

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1341532

Alternate ID(s):: OSTI ID: 1341276

Journal Information:: Physical Review B, Vol. 95, Issue 2; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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Title: Competing exchange interactions in multiferroic and ferrimagnetic ${CaBaCo}_{4} O_{7}$