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Title: New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

Journal Article · · Crystal Growth and Design
;  [1]
  1. Critical Materials Institute, Ames Laboratory, Ames, Iowa 50011, United States

Sponsoring Organization:
USDOE
OSTI ID:
1341468
Journal Information:
Crystal Growth and Design, Journal Name: Crystal Growth and Design Vol. 16 Journal Issue: 4; ISSN 1528-7483
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
France
Language:
English
Citation Metrics:
Cited by: 39 works
Citation information provided by
Web of Science

References (166)

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Silver(I) diaquanickel(II) catena -borodiphosphate(V) hydrate, (Ag 0.57 Ni 0.22 )Ni(H 2 O) 2 [BP 2 O 8 ]·0.67H 2 O journal July 2011
Synthesis, Crystal Structure and Characterization of a new Protonated Magnesium Borophosphate: (H3O)Mg(H2O)2[BP2O8]·H2O journal December 2010
[Ga 2 (DETA)(PO 4 ) 2 ]·2H 2 O (DETA = Diethylenetriamine):  A Novel Porous Gallium Phosphate Containing 24-Ring Channels journal May 2001
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Low-temperature flux syntheses and characterizations of two 1-D anhydrous borophosphates: Na3B6PO13 and Na3BP2O8 journal January 2007
Rapid growth of KDP-type crystals journal January 2001
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Spontaneous crystallization of a new chiral open-framework borophosphate in the ionothermal system journal January 2010
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Ionothermal Synthesis of Oriented Zeolite AEL Films and Their Application as Corrosion-Resistant Coatings journal January 2008
The molten hydrated flux synthesis of a novel open-framework copper borophosphate and its structural relation with the precursors journal October 2014
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Hydrothermal synthesis, characterization and magnetic properties of three isostructural chain borophosphates; NH4M(III)[BP2O8(OH)] with MV or Fe and NH4(Fe(III)0.53V(III)0.47)[BP2O8(OH)] journal August 2001
Synthesis and characterization of metalloborophosphates with zeotype ANA framework by the boric acid ‘flux’ method journal December 2005
Microporous Magnesium Aluminophosphate STA-1: Synthesis with a Rationally Designed Template and Structure Elucidation by Microcrystal Diffraction journal February 1997
Crystal structure of cobalt manganese monoaqua catena-[monohydrogenborate- tris(hydrogenphosphate)], (Co0.6Mn0.4)2(H2O)[BP3O9(OH)4] journal September 2009
Open-Framework Borophosphates:  (NH 4 ) 0.4 Fe II 0.55 Fe III 0.5 (H 2 O) 2 [BP 2 O 8 ]·0.6H 2 O and NH 4 Fe III [BP 2 O 8 (OH)] journal November 2001
A new organically-templated cobalt borophosphate with a novel borophosphatic anionic partial structure journal September 2011
New nonlinear-optical crystal: LiB_3O_5 journal January 1989
Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: PbII4{Co2[B(OH)2P2O8](PO4)2}Cl  journal June 2010
Ionothermal synthesis of β-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases journal January 2007
Borophosphates—A Neglected Class of Compounds: Crystal Structures of MII[BPO5](MII Ca, Sr) and Ba3[BP3O12] journal April 1994
Thermochemical properties for a series of microporous borophosphates of MI[ZnBP2O8] (MI=Na, K, Rb, Cs) journal September 2014
(NH 4 )[B 3 PO 6 (OH) 3 ]·0.5H 2 O journal October 2007
Refinement of the crystal structures of praseodymium- and samariumoxoborate- bis(oxophosphate)-oxide, Ln7O6[BO3][PO4]2, (Ln = Pr, Sm) journal April 2004
A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters journal January 2010
Influence of Hydrogen Bonding on the Assembly of Six-Membered Vanadium Borophosphate Cluster Anions:  Synthesis and Structures of (NH 4 ) 2 (C 2 H 10 N 2 ) 6 [Sr(H 2 O) 5 ] 2 [V 2 P 2 BO 12 ] 6 ·10H 2 O, (NH 4 ) 2 (C 3 H 12 N 2 ) 6 [Sr(H 2 O) 4 ] 2 [V 2 P 2 BO 12 ] 6 ·17H 2 O, and (NH 4 ) 3 (C 4 H 14 N 2 ) 4.5 [Sr(H 2 O) 5 ] 2 [Sr(H 2 O) 4 ][V 2 P 2 BO 12 ] 6 ·10H 2 O journal September 2000
MCuB7O12·nH2O (M = Na, K ): A new copper borate with 14-ring channels journal January 2005
Fabrication and characterization of optical waveguides in KTiOPO 4 journal May 1987
Lithium manganese(II) diaquaborophosphate monohydrate journal July 2008
Crystal structure of sodium nickel diaqua catena-[monoboro-diphosphate] monohydrate, NaNi(H2O)2[BP2O8] · H2O, at 293 Κ and 198 Κ journal April 2001
Structure−Property Relationships in Lithium, Silver, and Cesium Uranyl Borates journal November 2010
Thermodynamic properties of microporous materials for two borophosphates, K[ZnBP2O8] and NH4[ZnBP2O8] journal February 2014
Explorations of New Types of Second-Order Nonlinear Optical Materials in Cd(Zn)-VV-TeIV-O Systems journal February 2008
Redetermination of Fe 2 [BP 3 O 12 ] journal August 2010
Crystallization of a Large-Pore Three-Dimensional Gallium Fluorophosphate under Mild Conditions journal December 2000
Fe(H 2 O) 2 BP 2 O 8 ·H 2 O, a First Zeotype Ferriborophosphate with Chiral Tetrahedral Framework Topology journal November 2000
Synthesis and structural characterisation of a new ferrous-ferric borophosphate: (NH4)0.5FeII0.5FeIII0.5(H2O)2BP2O8 0.5H2O journal October 2003
Preparation and characterization of the layered borophosphates MII(H2O)2[B2P2O8(OH)2]·H2O (MII=Fe, Co, Ni) journal December 2010
KCo(H 2 O) 2 BP 2 O 8 ·0.48H 2 O and K 0.17 Ca 0.42 Co(H 2 O) 2 BP 2 O 8 ·H 2 O: two cobalt borophosphates with helical ribbons and disordered (K,Ca)/H 2 O schemes journal July 2012
The mixed glass former effect in twin-roller quenched lithium borophosphate glasses journal February 2012
Synthesis, structure and magnetic property of a new organo-templated mixed-valent iron(ii, iii) borophosphate journal January 2009
Chiral Symmetry Breaking in Sodium Chlorate Crystallizaton journal November 1990
The Ionothermal Synthesis of Cobalt Aluminophosphate Zeolite Frameworks journal February 2006
Ionothermal Synthesis of Unusual Choline-Templated Cobalt Aluminophosphates journal October 2007
26-Ring-Channel Structure Constructed from Bimetal Phosphite Helical Chains journal May 2007
Studies in Lithium Oxide Systems: XI, Li2O-B2O3-P2O5 journal August 1961
[Co(en) 3 ][B 2 P 3 O 11 (OH) 2 ]:  A Novel Borophosphate Templated by a Transition-Metal Complex journal May 2001
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density journal December 2001
Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes journal July 2010
A new zincoborophosphate templated by diethylenetriamine (DETA): Synthesis and characterizations of (C4N3H16)[Zn3B3P6O24]·H2O journal January 2004
Synthesis and Structural Characterization of 0D Vanadium Borophosphate [Co(en) 3 ] 2 [V 3 P 3 BO 19 ][H 2 PO 4 ]·4H 2 O and 1D Vanadium Oxides [Co(en) 3 ][V 3 O 9 ]·H 2 O and [Co(dien) 2 ][V 3 O 9 ]·H 2 O Templated by Cobalt Complexes:  Cooperative Organization of the Complexes and the Inorganic Networks journal January 2004
KMBP 2 O 8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework journal July 2009
Crystal Structures and Magnetic Properties of New Europium Melilites Eu 2 MSi 2 O 7 (M = Mg, Mn) and Their Strontium Analogues journal December 2010
Heteroatom-Stabilized Chiral Framework of Aluminophosphate Molecular Sieves journal January 2009
Structure of the First Silicate Molecular Sieve with 18-Ring Pore Openings, ECR-34 journal December 2003
Structural Chemistry of Borophosphates, Metalloborophosphates, and Related Compounds journal August 2007
Lithium diaquamagnesium catena -borodiphosphate(V) monohydrate, LiMg(H 2 O) 2 [BP 2 O 8 ]·H 2 O, at 173 K journal May 2008
A novel chlorine-containing borophosphate based on (4,3)-connected 3-D borophosphate anion [B6P11O42(OH)2]13− with unique B : P ratio and 22-tetrahedral cages journal January 2013
Li2O–B2O3–P2O5 solid electrolyte for thin film batteries journal December 2006
Ti[BP2O7(OH)3]: The first titanium borophosphate containing novel anionic partial structure journal January 2011
Syntheses and Magnetic Properties Study of Isostructural BiM 2 BP 2 O 10 (M = Co, Ni) Containing a Quasi-1D Linear Chain Structure journal August 2012
The ionothermal synthesis of SIZ-6—a layered aluminophosphate journal January 2006
The first oxometalate borophosphate polyanion: hydrothermal synthesis and structure of (H3NCH2CH2NH3)2[Na(VO)10{HO3POB(O)2OPO3H}5]·22.5H2O journal January 1998
Oxyfluorinated Microporous Compounds journal August 1994
(NH 4 ) 0.75 Fe(H 2 O) 2 [BP 2 O 8 ]·0.25H 2 O, a Fe 3+ /Fe 2+ Mixed Valence Cathode Material for Na Battery Exhibiting a Helical Structure journal February 2015
Observation of magneto-chiral dichroism journal December 1997
Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure journal January 2006
A novel synthesis route to rare earth polyborates journal January 2001
A new 3-D open-framework cadmium borovanadate with plane-shaped channels and high catalytic activity for the oxidation of cyclohexanol journal January 2015
Ordered porous materials for emerging applications journal June 2002
Role of boron-containing ionic liquid in the synthesis of manganese borophosphate with extra-large 16-ring pore openings journal January 2012
Syntheses and Characterizations of Cs 2 Cr 3 (BP 4 O 14 )(P 4 O 13 ) and CsFe(BP 3 O 11 ) Compounds with Novel Borophosphate Anionic Partial Structures journal March 2010
High‐efficiency and narrow‐linewidth operation of a two‐crystal β‐BaB 2 O 4 optical parametric oscillator journal November 1989
Synthesis and Crystal Structure of CaCo(H 2 O)[BP 2 O 8 (OH)]·H 2 O journal April 2009
Two Three-Dimensional Metal−Organic Frameworks Containing One-Dimensional Hydroxyl/Carboxylate Mixed Bridged Metal Chains:  Syntheses, Crystal Structures, and Magnetic Properties journal February 2006
Experimental Evidence of α-Olefin Readsorption in Fischer–Tropsch Synthesis on Ruthenium-Supported ETS-10 Titanium Silicate Catalysts journal May 1997
1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves journal October 2006
An open-framework borophosphate, LiCu 2 BP 2 O 8 (OH) 2 journal April 2009
Templated Synthesis of Vanadium Borophosphate Cluster Anions journal July 1999
Na 3 Cd 3 B(PO 4 ) 4 : A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units journal September 2012
Crystal structure of dilithium scandium (monophosphatemonohydrogenmonophosphate), Li2Sc[(PO4)(HPO4)] journal December 2008
Crystal Structure and Thermochemical Properties of a First Scandium Borophosphate, Sc(H 2 O) 2 [BP 2 O 8 ]·H 2 O journal February 2006
Crystal structure of potassium vanadium (monophosphatehydrogenmonoborate- monophosphate), KV[BP2O8(OH)] journal December 2008
CHEMISTRY: Ionic Liquids--Solvents of the Future? journal October 2003
Synthesis and Crystal Structure of SrFe[BP 2 O 8 (OH) 2 ] journal July 2009
Crystal structure of the gallophosphate framework: X-ray characterization of Ga 9 P 9 O 36 OH·HNEt 3 journal January 1987
Die Kristallstruktur von [Na4(OSiPh3)4(H2O)3] / The Crystal Structure of [Na4(OSiPh3)4(H2O)3] journal November 1996
LiCu2[BP2O8(OH)2]: A Lithium Copper Borophosphate with Chains of distorted CuO5 Square Pyramids journal September 2006
Na 8 [Cr 4 B 12 P 8 O 44 (OH) 4 ][P 2 O 7 ]⋅ n H 2 O: A 3D Borophosphate Framework with Spherical Cages journal August 2008
Some gallium phosphate frameworks related to the aluminium phosphate molecular sieves: X-ray structural characterization of {(Pr i NH 3 )[Ga 4 (PO 4 ) 4 ·OH]}·H 2 O journal January 1985
Synthesis, crystal structure and lithium ion conduction of Li 3 BP 2 O 8 journal January 2014
NaSc[BP 2 O 6 (OH) 3 ][(HO)PO 3 ]: Synthesis and Crystal Structure of an Alkali-Metal Scandium Borophosphate Hydrogenphosphate journal January 2010
Silver(I) diaquamagnesium catena -borodiphosphate(V) monohydrate, AgMg(H 2 O) 2 [BP 2 O 8 ]·H 2 O journal May 2011
Chirality and ferromagnetism in NiBPO4(OH)2 containing helix edge-sharing NiO6 chains journal May 2008
Chirality and Magnetism in a Novel Series of Isotypic Borophosphates:  M II [BPO 4 (OH) 2 ] (M II = Mn, Fe, Co) journal September 2006
Synthesis and Characterization of Non-centrosymmetric TeSeO 4 journal March 2001
Ionothermal Synthesis of the First Luminescent Open-Framework Manganese Borophosphate with Switchable Magnetic Properties journal May 2012
Na(H2O)[Mn(H2O)2(BP2O8)]: Crystal structure refinement journal January 2009
(NH4)6[Mn3B6P9O36(OH)3]·4H2O: A new open-framework manganese borophosphate synthesized by using boric acid flux method journal January 2011
Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 5 journal January 2015
Crystal structure of dicaesium diaquatricobalt(II) (phosphate-borate-hydrogenphosphate), Cs2Co3(H2O)2[B4P6O24(OH)2] journal January 2009
K 7 B 2 P 5 O 19 : a novel alkali metal borophosphate with zero dimensional [B 2 P 5 O 19 ] 7− anionic units journal January 2014
Composition and structure dependence of the properties of lithium borophosphate glasses showing boron anomaly journal December 2009
Phosphonoacetic acid as a building block in supramolecular chemistry: salts with organic polyamines journal January 2003
Structure and Reactivity of Sodium Phenoxide - Following the Course of the Kolbe-Schmitt Reaction journal October 1997
Na 2 [VB 3 P 2 O 12 (OH)]·2.92H 2 O: A New Open-Framework Vanadium Borophosphate Containing Extra-Large 16-Ring Pore Openings and 12 8 16 6 Super Cavities Synthesized by Using the Boric Acid Flux Method journal August 2008
Structure and magnetism of Cr 2 [BP 3 O 12 ]: Towards the quantum-classical crossover in a spin- 3 2 alternating chain journal February 2013
(UO 2 ) 2 [UO 4 (trz) 2 ](OH) 2 : A U(VI) Coordination Intermediate between a Tetraoxido Core and a Uranyl Ion with Cation–Cation Interactions journal June 2012
Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li 2 Cs 2 B 2 P 4 O 15 , LiK 2 BP 2 O 8 , and Li 3 M 2 BP 4 O 14 (M=K, Rb) journal August 2012
Synthesis and characterization of the open-framework magnesium aluminophosphate UiO-28 journal January 2001
Synthesis and characterization of zinc borophosphates with ANA-zeotype framework by the microwave method journal June 2013
Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels journal January 2010
The Observation of Superparamagnetic Behavior in Molecular Nanowires journal July 2004
X-ray powder diffraction and IR study of NaMg(H2O)2[BP2O8]·H2O and NH4Mg(H2O)2[BP2O8]·H2O journal January 2000
Growth, Structure, and Properties of Single Crystals of SrBPO 5 journal June 2003
Synthesis and Structure of CoB2P3O12(OH)·C2H10N2: The First Metal Borophosphate with an Open Framework Structure journal December 1996
Synthesis and crystal structure of NH4[(Zn1−xCox)BP2O8] (0⩽x⩽0.14), a metallo-borophosphate analogue of the zeolite gismondine journal December 2000
Chemical Strategies To Design Textured Materials:  from Microporous and Mesoporous Oxides to Nanonetworks and Hierarchical Structures journal November 2002
Magnetic and Neutron Diffraction Study on Melilite-Type Oxides Sr 2 MGe 2 O 7 (M = Mn, Co) journal February 2012
Low-temperature flux synthesis of a novel one-dimensional copper (II) chlorophosphate: crystal structure and magnetic property of Na3[CuO(HPO4)Cl] journal March 2005
Control of Channel Shapes in a Microporous Manganese(II)–Borophosphate Framework by Variation of Size and Shape of Organic Template Cations journal February 2007
The templated synthesis and structure determination by synchrotron microcrystal diffraction of the novel small pore magnesium aluminophosphate STA-2 † journal January 1997
Novel Fundamental Building Blocks and Site Dependent Isomorphism in the First Actinide Borophosphates journal June 2013
Synthesis and Characterization of a Borophosphate Anion Containing a Single Vanadium Atom:  [N 2 C 6 H 14 ] 2 VO(PO 3 OH) 4 (B 3 O 3 OH)·4H 2 O journal May 1999
Hydrothermal synthesis of isostructural open-framework manganese and iron borophosphates: Effect of the organic templates in determining the pore shapes journal April 2011
A new copper borophosphate with novel polymeric chains and its structural correlation with raw materials in molten hydrated flux synthesis journal February 2014
The crystal structure of Li 2 B 3 PO 8 with the 2D-linkage of BO 3 , BO 4 and PO 4 groups journal January 2014
Rb[B2P2O8(OH)] und Cs[B2P2O8(OH )]: Die ersten Borophosphate mit dreidimensional vernetzter Anionenteilstruktur /Rb[B2P2O8(OH)] and Cs[B2P2O8(OH )]: The First Borophosphates with a Threedimensional Anionic Tetrahedral Structure journal November 1997
Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O8 journal January 2013
Lithium diaquanickel(II) catena -borodiphosphate(V) monohydrate journal May 2009
Investigation of crystal structure and associated electronic structure of Sr6BP5O20 journal April 2006
PKU-5: An Aluminoborate with Novel Octahedral Framework Topology journal August 2004
Structural Patterns and Dimensionality in Magnesium Borophosphates: The Crystal Structures of Mg2(H2O)[BP3O9(OH)4] and Mg(H2O)2[B2P2O8(OH)2]·H2O journal July 2005
Hydrothermal synthesis and crystal structure of the microporous gallophosphate [NH 4 ] 4 [Ga 8 P 8 O 32 (OH) 4 (H 2 O) 4 ]·4H 2 O·0.64PrOH with an octahedral–tetrahedral framework journal January 1995
Oligomere Tetraeder-Anionen in Borophosphaten: Sechserringe mit offenen und cyclischen Phosphat-Verzweigungen in der Kristallstruktur von K6Cu2[B4P8O28(OH)6] / Oligomeric Tetrahedral Anions in Borophosphates: Six-Membered Rings with Open and Cyclic Phosphate Branchings in the Crystal Structure of K6Cu2[B4P8O28(OH)6] journal December 1998
Na 5 (NH 4 )Mn 3 [B 9 P 6 O 33 (OH) 3 ]·1.5H 2 O journal November 2008
Crystal structure of trilithium divanadium(III) borophosphate hydrogenphosphate, Li3V2[BP3O12(OH)][HPO4] journal March 2010
A New Open-framework Iron Borophosphate from Ionic Liquids: KFe[BP2O8(OH)] journal April 2011
Crystal structure of lithium catena-[monoboro-mono-dihydrogendiboratemonohydrogenphosphate), Li[B3PO6(OH)3] journal January 1997
Quantum Criticality in an Ising Chain: Experimental Evidence for Emergent E 8 Symmetry journal January 2010
Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues journal August 2004
Aluminoborate-Based Molecular Sieves with 18-Octahedral-Atom Tunnels journal November 2003
Ionothermal Syntheses and Characterizations of New Open-Framework Metal Borophosphates journal February 2011
Hydrothermal synthesis of new berylloborophosphates MIBeBPO (MI=K+, Na+ and NH4+) with zeolite ANA framework topology journal February 2003
Synthesis and Structure of KPbBP 2 O 8 - A Congruent Melting Borophosphate with Nonlinear Optical Properties journal May 2013
Isotype Borophosphate MII(C2H10N2)[B2P3O12(OH)] (MII = Mg, Mn, Fe, Ni, Cu, Zn): Verbindungen mit Tetraeder-Schichtverbänden journal January 2000
Hydrothermal Synthesis and Characterization of Two Organically Templated Cadmium Borophosphates with Novel Structures journal May 2004
Silver diaquacobalt(II) catena -borodiphosphate(V) hydrate, (Ag 0.79 Co 0.11 )Co(H 2 O) 2 [BP 2 O 8 ]·0.67H 2 O journal December 2011
NH4[BPO4F]: A novel open-framework ammonium fluorinated borophosphate with a zeolite-like structure related to gismondine topology journal January 2004
K[ZnBP2O8] and A[ZnBP2O8] (A=NH4+, Rb+, Cs+): Zincoborophosphates as a New Class of Compounds with Tetrahedral Framework Structures journal December 1999
Rb2Co3(H2O)2[B4P6O24(OH)2]: Ein Borophosphat mit∞2-Tetraeder-Anionenteilstruktur und Oktaeder-Trimeren (Co3IIO12(H2O)2) journal June 2000
Crystal structure of lithium copper(II) monoaqua catena-[monoborodiphosphate] dihydrate, LiCu(H2o)[BP2O8] · 2H2O journal April 2001
LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization journal January 2013
Synthesis and Crystal Structure of {(NH4)xCo((3-x)/2)}(H2O)2[BP2O8] · (1 -x) H2O (x ≈ 0.5) journal January 2002
A First Approach to Borophosphate Structural Chemistry journal October 1998
Se 2 (B 2 O 7 ):  A New Type of Second-Order NLO Material journal June 2006
NaZn(H2O)2[BP2O8]⋅H2O: A Novel Open-Framework Borophosphate and its Reversible Dehydration to Microporous Sodium Zincoborophosphate Na[ZnBP2O8]⋅H2O with CZP Topology journal February 2001
Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries journal August 2011
Impetus for solvothermal synthesis technique: synthesis and structure of a novel 1-D borophosphate using ionic liquid as medium journal November 2003
Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids journal April 2009
Synthesis and Characterization of the Layered Vanadium Borophosphate (Imidazolium) 3.8 (H 3 O) 1.2 [(VO) 4 (BO) 2 (PO 4 ) 5 ]·0.3H 2 O journal July 2000