Soft nanoparticles: nano ionic networks of associated ionic polymers

Aryal, Dipak; Grest, Gary S.; Perahia, Dvora

doi:10.1039/c6nr09206c

Soft nanoparticles: nano ionic networks of associated ionic polymers

Journal Article · Sat Dec 31 23:00:00 EST 2016 · Nanoscale

DOI:https://doi.org/10.1039/c6nr09206c· OSTI ID:1341401

Aryal, Dipak; Grest, Gary S.; Perahia, Dvora

Directing the formation of nanostructures that serve as building blocks of membranes presents an immense step towards engineering controlled polymeric ion transport systems. Here, using the exquisite atomic detail captured by molecular dynamics simulations, we follow the assembly of a co-polymer that consists of polystyrene sulfonate tethered symmetrically to hydrophobic blocks, realizing a new type of long lived solvent-responsive soft nanoparticle.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1341401

Report Number(s):: SAND--2016-12464J; 649801

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 6 Vol. 9; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

Morphological Investigation of Midblock-Sulfonated Block Ionomers Prepared from Solvents Differing in Polarity Mineart, Kenneth P.; Jiang, Xi; Jinnai, Hiroshi Macromolecular Rapid Communications, Vol. 36, Issue 5 https://doi.org/10.1002/marc.201400627	journal	December 2014
Phase Behavior of a Single Structured Ionomer Chain in Solution: Phase Behavior of a Single Structured Ionomer Chain … Aryal, Dipak; Etampawala, Thusitha; Perahia, Dvora Macromolecular Theory and Simulations, Vol. 23, Issue 9 https://doi.org/10.1002/mats.201400046	journal	August 2014
Effect of acidification treatment and morphological stability of sulfonated poly(arylene ether sulfone) copolymer proton-exchange membranes for fuel-cell use above 100 °C: Sulfonated Poly(Arylene Ether Sulfone) Kim, Yu Seung; Wang, Feng; Hickner, Michael Journal of Polymer Science Part B: Polymer Physics, Vol. 41, Issue 22 https://doi.org/10.1002/polb.10496	journal	October 2003
Predicting the solution morphology of a sulfonated pentablock copolymer in binary solvent mixtures Griffin, Philip J.; Salmon, Grace B.; Ford, Jamie Journal of Polymer Science Part B: Polymer Physics, Vol. 54, Issue 2 https://doi.org/10.1002/polb.23914	journal	September 2015
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Raman spectroscopic and gas transport study of a pentablock ionomer complexed with metal ions and its relationship to physical properties Fan, Yanfang; Cornelius, Chris J. Journal of Materials Science, Vol. 48, Issue 3 https://doi.org/10.1007/s10853-012-6853-9	journal	September 2012
Block copolymer ionomers: 2. Viscoelastic and mechanical properties of sulphonated poly(styrene-ethylene/butylene-styrene) Weiss, R. A.; Sen, A.; Pottick, L. A. Polymer, Vol. 32, Issue 15 https://doi.org/10.1016/0032-3861(91)90109-V	journal	January 1991
Block copolymer ionomers: 1. Synthesis and physical properties of sulphonated poly(styrene-ethylene/butylene-styrene) Weiss, R. A.; Sen, Ashish; Willis, C. L. Polymer, Vol. 32, Issue 10 https://doi.org/10.1016/0032-3861(91)90378-V	journal	January 1991
Advanced drug delivery devices via self-assembly of amphiphilic block copolymers Rösler, Annette; Vandermeulen, Guido W. M.; Klok, Harm-Anton Advanced Drug Delivery Reviews, Vol. 64 https://doi.org/10.1016/j.addr.2012.09.026	journal	December 2012
Structure–property relationship in sulfonated pentablock copolymers Choi, Jae-Hong; Willis, Carl L.; Winey, Karen I. Journal of Membrane Science, Vol. 394-395 https://doi.org/10.1016/j.memsci.2011.12.036	journal	March 2012
Effects of neutralization with Et3Al on structure and properties in sulfonated styrenic pentablock copolymers Choi, Jae-Hong; Willis, Carl L.; Winey, Karen I. Journal of Membrane Science, Vol. 428 https://doi.org/10.1016/j.memsci.2012.10.051	journal	February 2013
Free volume characterization of sulfonated styrenic pentablock copolymers using positron annihilation lifetime spectroscopy Geise, Geoffrey M.; Doherty, Cara M.; Hill, Anita J. Journal of Membrane Science, Vol. 453 https://doi.org/10.1016/j.memsci.2013.11.004	journal	March 2014
Characterization of a sulfonated pentablock copolymer for desalination applications Geise, G. M.; Freeman, B. D.; Paul, D. R. Polymer, Vol. 51, Issue 24 https://doi.org/10.1016/j.polymer.2010.09.072	journal	November 2010
Solvent tunable multi-block ionomer morphology and its relationship to modulus, water swelling, directionally dependent ion transport, and actuator performance Zheng, W.; Cornelius, C. J. Polymer, Vol. 103 https://doi.org/10.1016/j.polymer.2016.09.055	journal	October 2016
Micellization of Ionic Block Copolymers Moffitt, Matthew; Khougaz, Karine; Eisenberg, Adi Accounts of Chemical Research, Vol. 29, Issue 2 https://doi.org/10.1021/ar940080	journal	January 1996
Comparing the Energy Content of Batteries, Fuels, and Materials Balsara, Nitash P.; Newman, John Journal of Chemical Education, Vol. 90, Issue 4 https://doi.org/10.1021/ed3004066	journal	March 2013
Micellar Morphology in Sulfonated Pentablock Copolymer Solutions Choi, Jae-Hong; Kota, Arun; Winey, Karen I. Industrial & Engineering Chemistry Research, Vol. 49, Issue 23 https://doi.org/10.1021/ie1002476	journal	December 2010
Characterization of Aluminum-Neutralized Sulfonated Styrenic Pentablock Copolymer Films Geise, Geoffrey M.; Willis, Carl L.; Doherty, Cara M. Industrial & Engineering Chemistry Research, Vol. 52, Issue 3 https://doi.org/10.1021/ie202546z	journal	April 2012
Optimized intermolecular potential functions for liquid hydrocarbons Jorgensen, William L.; Madura, Jeffry D.; Swenson, Carol J. Journal of the American Chemical Society, Vol. 106, Issue 22 https://doi.org/10.1021/ja00334a030	journal	October 1984
Development and Testing of the OPLS All-Atom Force Field on Conformational Energetics and Properties of Organic Liquids Jorgensen, William L.; Maxwell, David S.; Tirado-Rives, Julian Journal of the American Chemical Society, Vol. 118, Issue 45 https://doi.org/10.1021/ja9621760	journal	January 1996
Refined OPLS All-Atom Force Field Parameters for n -Pentadecane, Methyl Acetate, and Dimethyl Phosphate Murzyn, Krzysztof; Bratek, Maciej; Pasenkiewicz-Gierula, Marta The Journal of Physical Chemistry B, Vol. 117, Issue 51 https://doi.org/10.1021/jp408162d	journal	December 2013
Viscoelastic behavior of lightly sulfonated polystyrene ionomers Weiss, R. A.; Fitzgerald, J. J.; Kim, D. Macromolecules, Vol. 24, Issue 5 https://doi.org/10.1021/ma00005a015	journal	September 1991
Morphological studies of a triblock copolymer ionomer by small-angle x-ray scattering Lu, Xinya; Steckle, W. P.; Weiss, R. A. Macromolecules, Vol. 26, Issue 24 https://doi.org/10.1021/ma00076a033	journal	November 1993
Block Ionomer Micelles in Solution. 1. Characterization of Ionic Cores by Small-Angle X-ray Scattering Nguyen, Diep; Williams, Claudine E.; Eisenberg, Adi Macromolecules, Vol. 27, Issue 18 https://doi.org/10.1021/ma00096a035	journal	August 1994
A new multiplet-cluster model for the morphology of random ionomers Eisenberg, A.; Hird, B.; Moore, R. B. Macromolecules, Vol. 23, Issue 18 https://doi.org/10.1021/ma00220a012	journal	September 1990
The Full Phase Behavior for Block Copolymers in Solvents of Varying Selectivity Lodge, Timothy P.; Pudil, Bryant; Hanley, Kenneth J. Macromolecules, Vol. 35, Issue 12 https://doi.org/10.1021/ma0200975	journal	June 2002
Transport Properties of Sulfonated Poly(styrene- b -isobutylene- b -styrene) Triblock Copolymers at High Ion-Exchange Capacities Elabd, Yossef A.; Napadensky, Eugene; Walker, Charles W. Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma051958n	journal	January 2006
Self-Assembled Polystyrene- b lock -poly(ethylene oxide) Micelle Morphologies in Solution Bhargava, Prachur; Zheng, Joseph X.; Li, Pei Macromolecules, Vol. 39, Issue 14 https://doi.org/10.1021/ma060677s	journal	June 2006
Block Copolymers for Fuel Cells Elabd, Yossef A.; Hickner, Michael A. Macromolecules, Vol. 44, Issue 1 https://doi.org/10.1021/ma101247c	journal	January 2011
Influence of the Degree of Sulfonation on the Structure and Dynamics of Sulfonated Polystyrene Copolymers Castagna, Alicia M.; Wang, Wenqin; Winey, Karen I. Macromolecules, Vol. 43, Issue 24 https://doi.org/10.1021/ma102206f	journal	December 2010
Effect of Macromolecular Architecture on the Morphology of Polystyrene–Polyisoprene Block Copolymers Dyer, C.; Driva, P.; Sides, S. W. Macromolecules, Vol. 46, Issue 5 https://doi.org/10.1021/ma202650a	journal	February 2013
Nonlinear Rheology of Lightly Sulfonated Polystyrene Ionomers Qiao, Xiuying; Weiss, R. A. Macromolecules, Vol. 46, Issue 6 https://doi.org/10.1021/ma3026496	journal	March 2013
Phase Behavior of Symmetric Sulfonated Block Copolymers Park, Moon Jeong; Balsara, Nitash P. Macromolecules, Vol. 41, Issue 10 https://doi.org/10.1021/ma702733f	journal	May 2008
Effect of Knotting on the Shape of Polymers Rawdon, Eric J.; Kern, John C.; Piatek, Michael Macromolecules, Vol. 41, Issue 21 https://doi.org/10.1021/ma801389c	journal	November 2008
Aqueous Micellar Solutions of Hydrophobically Modified Polyelectrolytes Guenoun, Patrick; Davis, H. Ted; Tirrell, Matthew Macromolecules, Vol. 29, Issue 11 https://doi.org/10.1021/ma946438z	journal	January 1996
Quantifying the “Neutrality” of Good Solvents for Block Copolymers: Poly(styrene- b -isoprene) in Toluene, Benzene, and THF Huang, Ching-i; Chapman, Bryan R.; Lodge, Timothy P. Macromolecules, Vol. 31, Issue 26 https://doi.org/10.1021/ma981259t	journal	December 1998
Asymmetrical self-assembly from fluorinated and sulfonated block copolymers in aqueous media Wang, Xiaojun; Hong, Kunlun; Baskaran, Durairaj Soft Matter, Vol. 7, Issue 18 https://doi.org/10.1039/c1sm06040f	journal	January 2011
Temperature-dependent micellar structures in poly(styrene-b-isoprene) diblock copolymer solutions near the critical micelle temperature Bang, Joona; Viswanathan, Karthik; Lodge, Timothy P. The Journal of Chemical Physics, Vol. 121, Issue 22 https://doi.org/10.1063/1.1812753	journal	January 2004
A general purpose model for the condensed phases of water: TIP4P/2005 Abascal, J. L. F.; Vega, C. The Journal of Chemical Physics, Vol. 123, Issue 23 https://doi.org/10.1063/1.2121687	journal	December 2005
Solvent controlled ion association in structured copolymers: Molecular dynamics simulations in dilute solutions Aryal, Dipak; Perahia, Dvora; Grest, Gary S. The Journal of Chemical Physics, Vol. 143, Issue 12 https://doi.org/10.1063/1.4931657	journal	September 2015
Association of a multifunctional ionic block copolymer in a selective solvent Etampawala, Thusitha N.; Aryal, Dipak; Osti, Naresh C. The Journal of Chemical Physics, Vol. 145, Issue 18 https://doi.org/10.1063/1.4967291	journal	November 2016
Ionomer design for augmented charge transport in novel ionic polymer transducers Duncan, Andrew J.; Akle, Barbar J.; Long, Timothy E. Smart Materials and Structures, Vol. 18, Issue 10 https://doi.org/10.1088/0964-1726/18/10/104005	journal	September 2009
Clustering effects in ionic polymers: Molecular dynamics simulations Agrawal, Anupriya; Perahia, Dvora; Grest, Gary S. Physical Review E, Vol. 92, Issue 2 https://doi.org/10.1103/PhysRevE.92.022601	journal	August 2015
Cluster Morphology-Polymer Dynamics Correlations in Sulfonated Polystyrene Melts: Computational Study Agrawal, Anupriya; Perahia, Dvora; Grest, Gary S. Physical Review Letters, Vol. 116, Issue 15 https://doi.org/10.1103/PhysRevLett.116.158001	journal	April 2016

Similar Records

Phase Behavior of a Single Structured Ionomer Chain in Solution

Journal Article · Thu Aug 14 00:00:00 EDT 2014 · Macromolecular Theory and Simulations · OSTI ID:1182990

Association of a multifunctional ionic block copolymer in a selective solvent

Journal Article · Sun Nov 13 23:00:00 EST 2016 · Journal of Chemical Physics · OSTI ID:1332952

Effect of Solvent Quality and Monomer Water Solubility on Soft Nanoparticle Morphology

Book · Sun Dec 31 23:00:00 EST 2017 · OSTI ID:1465029

Related Subjects

36 MATERIALS SCIENCE

Soft nanoparticles: nano ionic networks of associated ionic polymers

Citation Formats

References (44)

Similar Records

Related Subjects