Vibrational dynamics (IR, Raman, NRVS) and DFT study of new antitumor tetranuclearstannoxanecluster, Sn(IV)$$-$$oxo$$-$${di$$-$$o$$-$$vanillin} dimethyl dichloride

Journal Article · Tue Jun 21 00:00:00 EDT 2016 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c6cp02914k· OSTI ID:1340298

Arjmand, F. ^[1]; Sharma, S. ^[1]; Usman, M. ^[1]; Leu, B. M. ^[2]; Hu, M. Y. ^[2]; Toupet, L. ^[3]; Gosztola, David J. ^[4]; Tabassum, S. ^[1]

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1. Aligarh Muslim Univ., Aligarh (India). Dept. of Chemistry
2. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
3. Univ. de Rennes, Rennes (France). Inst. de Physique de Rennes
4. Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials

The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity revealed a significant regression selectively against the human pancreatic cell lines.

• Research Organization: Argonne National Lab. (ANL), Argonne, IL (United States)
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• DOE Contract Number: AC02-06CH11357
• OSTI ID: 1340298
• Journal Information: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 18, Issue 27; ISSN 1463-9076
• Publisher: Royal Society of Chemistry
• Country of Publication: United States
• Language: English