High conducting oxide--sulfide composite lithium superionic conductor

Liang, Chengdu; Rangasamy, Ezhiylmurugan; Dudney, Nancy J.; Keum, Jong Kahk; Rondinone, Adam Justin

High conducting oxide--sulfide composite lithium superionic conductor

Patent · Tue Jan 17 04:00:00 EST 2017

OSTI ID:1339534

Liang, Chengdu; Rangasamy, Ezhiylmurugan; Dudney, Nancy J.; Keum, Jong Kahk; Rondinone, Adam Justin

A solid electrolyte for a lithium-sulfur battery includes particles of a lithium ion conducting oxide composition embedded within a lithium ion conducting sulfide composition. The lithium ion conducting oxide composition can be Li.sub.7La.sub.3Zr.sub.2O.sub.12 (LLZO). The lithium ion conducting sulfide composition can be .beta.-Li.sub.3PS.sub.4 (LPS). A lithium ion battery and a method of making a solid electrolyte for a lithium ion battery are also disclosed.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Number(s):: 9,548,512

Application Number:: 14/104,803

OSTI ID:: 1339534

Country of Publication:: United States

Language:: English

References (29)

Effect of Interfacial Space-Charge Polarization on the Ionic Conductivity of Composite Electrolytes Dudney, N. J. Journal of the American Ceramic Society, Vol. 68, Issue 10, p. 538-545 https://doi.org/10.1111/j.1151-2916.1985.tb11520.x	journal	October 1985
The effect of 24c-site (A) cation substitution on the tetragonal–cubic phase transition in Li_7−xLa_3−xA_xZr₂O₁₂ garnet-based ceramic electrolyte Rangasamy, Ezhiylmurugan; Wolfenstine, Jeff; Allen, Jan Journal of Power Sources, Vol. 230, p. 261-266 https://doi.org/10.1016/j.jpowsour.2012.12.076	journal	May 2013
Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor Geiger, Charles A.; Alekseev, Evgeny; Lazic, Biljana Inorganic Chemistry, Vol. 50, Issue 3, p. 1089-1097 https://doi.org/10.1021/ic101914e	journal	February 2011
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification Ohta, N.; Takada, K.; Zhang, L. Advanced Materials, Vol. 18, Issue 17, p. 2226-2229 https://doi.org/10.1002/adma.200502604	journal	September 2006
Effect of substitution (Ta, Al, Ga) on the conductivity of Li₇La₃Zr₂O₁₂ Allen, J. L.; Wolfenstine, J.; Rangasamy, E. Journal of Power Sources, Vol. 206, p. 315-319 https://doi.org/10.1016/j.jpowsour.2012.01.131	journal	May 2012
Progress and prospective of solid-state lithium batteries Takada, Kazunori Acta Materialia, Vol. 61, Issue 3, p. 759-770 https://doi.org/10.1016/j.actamat.2012.10.034	journal	February 2013
Inorganic solid Li ion conductors: An overview Knauth, Philippe Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916 https://doi.org/10.1016/j.ssi.2009.03.022	journal	June 2009
Anomalous High Ionic Conductivity of Nanoporous β-Li₃PS₄ Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978 https://doi.org/10.1021/ja3110895	journal	January 2013
Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery Liang, Chengdu; Dudney, Nancy J.; Howe, Jane Y. Chemistry of Materials, Vol. 21, Issue 19, p. 4724-4730 https://doi.org/10.1021/cm902050j	journal	October 2009
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
High lithium ionic conductivity in the garnet-type oxide Li_7−XLa₃(Zr_2−X, Nb_X)O₁₂ (X=0–2) Ohta, Shingo; Kobayashi, Tetsuro; Asaoka, Takahiko Journal of Power Sources, Vol. 196, Issue 6, p. 3342-3345 https://doi.org/10.1016/j.jpowsour.2010.11.089	journal	March 2011
High conductivity of dense tetragonal Li₇La₃Zr₂O₁₂ Wolfenstine, Jeff; Rangasamy, Ezhiyl; Allen, Jan L. Journal of Power Sources, Vol. 208, p. 193-196 https://doi.org/10.1016/j.jpowsour.2012.02.031	journal	June 2012
Composite polyether based solid electrolytes Wieczorek, W.; Florjanczyk, Z.; Stevens, J. R. Electrochimica Acta, Vol. 40, Issue 13-14, p. 2251-2258 https://doi.org/10.1016/0013-4686(95)00172-B	journal	October 1995
First Principles Study of the Li₁₀GeP₂S₁₂ Lithium Super Ionic Conductor Material Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand Chemistry of Materials, Vol. 24, Issue 1, p. 15-17 https://doi.org/10.1021/cm203303y	journal	December 2011
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/B925751A	journal	January 2010
Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System Kanno, Ryoji; Murayama, Masahiro Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746 https://doi.org/10.1149/1.1379028	journal	January 2001
Space Charge Regions in Solid Two Phase Systems and Their Conduction Contribution - II Contact Equilibrium at the Interface of Two Ionic Conductors and the Related Conductivity Effect Maier, Joachim Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 89, Issue 4, p. 355-362 https://doi.org/10.1002/bbpc.19850890402	journal	April 1985
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
Synthesis and structure analysis of tetragonal Li₇La₃Zr₂O₁₂ with the garnet-related type structure Awaka, Junji; Kijima, Norihito; Hayakawa, Hiroshi Journal of Solid State Chemistry, Vol. 182, Issue 8, p. 2046-2052 https://doi.org/10.1016/j.jssc.2009.05.020	journal	August 2009
Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂ Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781 https://doi.org/10.1002/anie.200701144	journal	October 2007
Enhanced ionic conductivity in composite electrolytes Dudney, Nancy J. Solid State Ionics, Vol. 28-30, Issue Part 2, p. 1065-1072 https://doi.org/10.1016/0167-2738(88)90332-3	journal	September 1988
Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet Ni, Jennifer E.; Case, Eldon D.; Sakamoto, Jeffrey S. Journal of Materials Science, Vol. 47, Issue 23, p. 7978-7985 https://doi.org/10.1007/s10853-012-6687-5	journal	July 2012
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
Al-doped Li₇La₃Zr₂O₁₂ synthesized by a polymerized complex method Jin, Ying; McGinn, Paul J. Journal of Power Sources, Vol. 196, Issue 20, p. 8683-8687 https://doi.org/10.1016/j.jpowsour.2011.05.065	journal	October 2011
Lithium Superionic Sulfide Cathode for All-Solid Lithium–Sulfur Batteries Lin, Zhan; Liu, Zengcai; Dudney, Nancy J. ACS Nano, Vol. 7, Issue 3, p. 2829-2833 https://doi.org/10.1021/nn400391h	journal	March 2013
Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes Liang, C. C. Journal of The Electrochemical Society, Vol. 120, Issue 10, p. 1289-1292 https://doi.org/10.1149/1.2403248	journal	October 1973
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Size-Controlled AgI/Ag Heteronanowires in Highly Ordered Alumina Membranes: Superionic Phase Stabilization and Conductivity Zhang, Hemin; Tsuchiya, Takashi; Liang, Changhao Nano Letters, Vol. 15, Issue 8, p. 5161-5167 https://doi.org/10.1021/acs.nanolett.5b01388	journal	July 2015
The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂ Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey Solid State Ionics, Vol. 206, p. 28-32 https://doi.org/10.1016/j.ssi.2011.10.022	journal	January 2012

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