Mechanistic study of shape-anisotropic nanomaterials synthesized via spontaneous galvanic displacement

Strand, Matthew B.; Leong, G. Jeremy; Tassone, Christopher J.; Larsen, Brian; Neyerlin, K. C.; Gorman, Brian; Diercks, David R.; Pylypenko, Svitlana; Pivovar, Bryan; Richards, Ryan M.

doi:10.1021/acs.jpcc.6b07363

Title: Mechanistic study of shape-anisotropic nanomaterials synthesized via spontaneous galvanic displacement

Journal Article · Thu Oct 13 00:00:00 EDT 2016 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b07363· OSTI ID:1339514

Strand, Matthew B. ^[1]; Leong, G. Jeremy ^[2]; Tassone, Christopher J. ^[3]; Larsen, Brian ^[4]; Neyerlin, K. C. ^[4]; Gorman, Brian ^[1]; Diercks, David R. ^[1]; Pylypenko, Svitlana ^[1]; Pivovar, Bryan ^[4]; Richards, Ryan M. ^[2]

Colorado School of Mines, Golden, CO (United States)
Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
Stanford Synchrotron Radiation Lightsource, Menlo Park, CA (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Among the broad portfolio of preparations for nanoscale materials, spontaneous galvanic displacement (SGD) is emerging as an important technology because it is capable of creating functional nanomaterials that cannot be obtained through other routes and may be used to thrift precious metals used in a broad range of applications including catalysis. With advances resulting from increased understanding of the SGD process, materials that significantly improve efficiency and potentially enable widespread adoption of next generation technologies can be synthesized. In this work, PtAg nanotubes synthesized via displacement of Ag nanowires by Pt were used as a model system to elucidate the fundamental mechanisms of SGD. Furthermore, characterization by X-ray diffraction (XRD), small-angle X-ray scattering (SAXS), and atom probe tomography (APT) indicates nanotubes are formed as Ag is oxidized first from the surface and then from the center of the nanowire, with Pt deposition forming a rough, heterogeneous surface on the PtAg nanotube.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); NREL Laboratory Directed Research and Development (LDRD)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1339514

Report Number(s):: NREL/JA-5900-67712

Journal Information:: Journal of Physical Chemistry. C, Vol. 120, Issue 43; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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