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Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage

Journal Article · · Renewable Energy
 [1];  [2]
  1. Univ. of Antofagasta, Antofagasta (Chile); National Renewable Energy Lab. (NREL), Golden, CO (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)

In recent years, lithium containing salts have been studied for thermal energy storage (TES) applications because of their excellent thermophysical properties. In solar power plants, lithium is seen as a way to improve the properties of state-of-the art molten salts used today. Lithium nitrate is a good candidate for sensible heat storage, because of its ability to increase the salt mixture's working temperature range. In the present research, thermophysical properties characterization of lithium nitrate containing salts, produced in Chile, have been carried out. Corrosion evaluations at 390° and 565 °C for 1000 h were performed for low chromium steel T22 and stainless steels (AISI 430 and AISI 316), respectively. Chemical composition of the salts including identification of corrosion products and impurities was determined and an estimation of the Chilean production costs is reported. The study shows a loss of thermal properties after the corrosion tests. The heat capacity was reduced, possibly caused by the formation of oxides at high temperatures. As a result, the partial thermal decomposition of the salt was probably produced by the incorporation of corrosion products from the steel.

Research Organization:
NREL (National Renewable Energy Laboratory (NREL), Golden, CO (United States))
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1339513
Alternate ID(s):
OSTI ID: 1359820
Report Number(s):
NREL/JA--5500-67720
Journal Information:
Renewable Energy, Journal Name: Renewable Energy Journal Issue: C Vol. 101; ISSN 0960-1481
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English