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Title: Catalytic reduction of polar substrates without metals: A thermodynamic and kinetic study of heterolytic activation of hydrogen by vacancies in frustrated Lewis pairs

Journal Article · · Catalysis Today
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Sponsoring Organization:
USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI ID:
1339304
Journal Information:
Catalysis Today, Journal Name: Catalysis Today Vol. 251 Journal Issue: C; ISSN 0920-5861
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English
Citation Metrics:
Cited by: 31 works
Citation information provided by
Web of Science

References (34)

Frustrated Lewis Pair Chemistry of Chiral (+)-Camphor-Based Aminoboranes journal June 2013
Metal‐Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes journal September 2008
Reactions of phosphorus/boron frustrated Lewis pairs with SO 2 journal January 2013
The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited journal January 2010
Thermodynamic functions of the solubilities of gases in liquids at 25.deg. journal February 1973
Reversible, Metal-Free Hydrogen Activation journal November 2006
Computationally Designed Metal-Free Hydrogen Activation Site: Reaching the Reactivity of Metal−Ligand Bifunctional Hydrogenation Catalysts journal December 2009
A thermodynamic and kinetic study of the heterolytic activation of hydrogen by frustrated borane–amine Lewis pairs journal January 2013
Analysis of the Activation and Heterolytic Dissociation of H 2 by Frustrated Lewis Pairs: NH 3 /BX 3 (X = H, F, and Cl) journal June 2012
Correction for instrument time constant and baseline in determination of reaction kinetics journal October 2010
Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field? journal March 2013
Asymmetric hydrogenation of imines with a recyclable chiral frustrated Lewis pair catalyst journal January 2012
Experimental and Theoretical Study of Molecular Response of Amine Bases in Organic Solvents journal April 2014
A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes journal July 2013
Exploiting the Kubas Interaction in the Design of Hydrogen Storage Materials journal May 2009
Association of frustrated phosphine–borane pairs in toluene: molecular dynamics simulations journal January 2012
Metal-free hydrogen activation and hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthalene journal January 2009
Cooperative Catalysis with Acid–Base Bifunctional Mesoporous Silica: Impact of Grafting and Co-condensation Synthesis Methods on Material Structure and Catalytic Properties journal June 2012
Electronic effects of triarylphosphines in metal-free hydrogen activation: a kinetic and computational study journal January 2013
Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs journal December 2011
Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H 2 Activation and the Role of Acid−Base Properties journal August 2009
Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs journal August 2009
Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct journal January 2007
On the Mechanism of B(C 6 F 5 ) 3 -Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration journal February 2009
Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More journal December 2009
Synthesis, Structures, and Reactions of Manganese Complexes Containing Diphosphine Ligands with Pendant Amines journal October 2010
Tuning acid–base cooperativity to create next generation silica-supported organocatalysts journal December 2013
Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions journal July 2005
The Role of Amine–B(C 6 F 5 ) 3 Adducts in the Catalytic Reduction of Imines with H 2 : A Computational Study journal May 2009
Role of Solvents on the Thermodynamics and Kinetics of Forming Frustrated Lewis Pairs journal October 2012
Uncovering the Role of Intra- and Intermolecular Motion in Frustrated Lewis Acid/Base Chemistry: Ab Initio Molecular Dynamics Study of CO2 Binding by Phosphorus/Boron Frustrated Lewis Pair [tBu3P/B(C6F5)3] journal April 2014
Ab initio dynamics trajectory study of the heterolytic cleavage of H2 by a Lewis acid [B(C6F5)3] and a Lewis base [P(tBu)3] journal April 2013
Encumbering the intramolecular π donation by using a bridge: A strategy for designing metal-free compounds to hydrogen activation journal January 2010
Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines journal March 2010

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