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Liquid Catholyte Molecules for Nonaqueous Redox Flow Batteries

Journal Article · · Advanced Energy Materials
 [1];  [2];  [2];  [1];  [1];  [1];  [2];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Material Sciences Division
In this study, a series of dimethoxybenzene-based catholyte molecules, which are electrochemically reversible at high potential (4.0 V vs Li/Li+) and in the form of liquid, is developed. The liquid nature offers the molecules the possibility of being a solo or co-solvent for nonaqueous redox flow batteries. This could dramatically improve the energy density.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1339128
Journal Information:
Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 6 Vol. 5; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (35)

Liquid Quinones for Solvent-Free Redox Flow Batteries journal September 2017
A Two-Electron Storage Nonaqueous Organic Redox Flow Battery journal February 2018
Redox Shuttles with Axisymmetric Scaffold for Overcharge Protection of Lithium-Ion Batteries journal July 2016
Annulated Dialkoxybenzenes as Catholyte Materials for Non-aqueous Redox Flow Batteries: Achieving High Chemical Stability through Bicyclic Substitution journal July 2017
Redox-Flow-Batterien: von metallbasierten zu organischen Aktivmaterialien journal November 2016
Macromolecular Design Strategies for Preventing Active-Material Crossover in Non-Aqueous All-Organic Redox-Flow Batteries journal January 2017
Porphyrin-Based Symmetric Redox-Flow Batteries towards Cold-Climate Energy Storage journal February 2018
A pH‐Neutral, Metal‐Free Aqueous Organic Redox Flow Battery Employing an Ammonium Anthraquinone Anolyte journal September 2019
Redox-Flow Batteries: From Metals to Organic Redox-Active Materials journal November 2016
Macromolecular Design Strategies for Preventing Active-Material Crossover in Non-Aqueous All-Organic Redox-Flow Batteries journal January 2017
Porphyrin-Based Symmetric Redox-Flow Batteries towards Cold-Climate Energy Storage journal February 2018
A pH‐Neutral, Metal‐Free Aqueous Organic Redox Flow Battery Employing an Ammonium Anthraquinone Anolyte journal November 2019
Toward High‐Voltage, Energy‐Dense, and Durable Aqueous Organic Redox Flow Batteries: Role of the Supporting Electrolytes journal September 2018
A bipolar nitronyl nitroxide small molecule for an all-organic symmetric redox-flow battery journal January 2017
Material design and engineering of next-generation flow-battery technologies journal November 2016
An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries journal January 2015
Overcharge protection of lithium-ion batteries above 4 V with a perfluorinated phenothiazine derivative journal January 2016
The rise of organic electrode materials for energy storage journal January 2016
High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries journal January 2016
Molecular engineering of organic electroactive materials for redox flow batteries journal January 2018
Bioinspired, high-stability, nonaqueous redox flow battery electrolytes journal January 2017
A stable two-electron-donating phenothiazine for application in nonaqueous redox flow batteries journal January 2017
Boosting the energy efficiency and power performance of neutral aqueous organic redox flow batteries journal January 2017
Improved radical stability of viologen anolytes in aqueous organic redox flow batteries journal January 2018
A multi-electron transfer ferrocene derivative positive redox moiety with improved solubility and potential journal January 2018
A systematic study of the co-solvent effect for an all-organic redox flow battery journal January 2018
Pyridyl group design in viologens for anolyte materials in organic redox flow batteries journal January 2018
Orbital-dependent redox potential regulation of quinone derivatives for electrical energy storage journal January 2019
Substituted thiadiazoles as energy-rich anolytes for nonaqueous redox flow cells journal January 2018
A 1.51 V pH neutral redox flow battery towards scalable energy storage journal January 2019
Improved synthesis of N -ethyl-3,7-bis(trifluoromethyl)phenothiazine journal January 2020
Progress and directions in low-cost redox-flow batteries for large-scale energy storage journal January 2017
High–energy density nonaqueous all redox flow lithium battery enabled with a polymeric membrane journal November 2015
2,5-Dimethoxy-1,4-Benzoquinone (DMBQ) as Organic Cathode for Rechargeable Magnesium-Ion Batteries journal January 2016
Redox Species of Redox Flow Batteries: A Review journal November 2015

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