Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD)

Jagannathan, Kaushik; Benson, David M.; Robinson, David B.; Stickney, John L.

doi:10.1149/2.0051612jes

Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD)

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0051612jes· OSTI ID:1338320

Jagannathan, Kaushik ^[1]; Benson, David M. ^[1]; Robinson, David B. ^[2]; Stickney, John L. ^[1]

Univ. of Georgia, Athens, GA (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Nanofilms of Pd were grown using an electrochemical form of atomic layer deposition (E-ALD) on 100 nm evaporated Au films on glass. Multiple cycles of surface-limited redox replacement (SLRR) were used to grow deposits. Each SLRR involved the underpotential deposition (UPD) of a Cu atomic layer, followed by open circuit replacement via redox exchange with tetrachloropalladate, forming a Pd atomic layer: one E-ALD deposition cycle. That cycle was repeated in order to grow deposits of a desired thickness. 5 cycles of Pd deposition were performed on the Au on glass substrates, resulting in the formation of 2.5 monolayers of Pd. Those Pd films were then modified with varying coverages of Pt, also formed using SLRR. The amount of Pt was controlled by changing the potential for Cu UPD, and by increasing the number of Pt deposition cycles. Hydrogen absorption was studied using coulometry and cyclic voltammetry in 0.1 M H₂SO₄ as a function of Pt coverage. The presence of even a small fraction of a Pt monolayer dramatically increased the rate of hydrogen desorption. However, this did not reduce the films’ hydrogen storage capacity. The increase in desorption rate in the presence of Pt was over an order of magnitude.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1338320

Report Number(s):: SAND--2016-7191J; 646103

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 12 Vol. 163; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (53)

Electrochemical Atomic Layer Deposition (E-ALD) of Palladium Nanofilms by Surface Limited Redox Replacement (SLRR), with EDTA Complexation Sheridan, Leah B.; Czerwiniski, Justin; Jayaraju, Nagarajan Electrocatalysis, Vol. 3, Issue 2 https://doi.org/10.1007/s12678-012-0080-7	journal	February 2012
A hydrogen adsorption and absorption study with ultrathin Pd overlayers on Au(111) and Au(100) Baldauf, M.; Kolb, D. M. Electrochimica Acta, Vol. 38, Issue 15 https://doi.org/10.1016/0013-4686(93)80091-D	journal	October 1993
A hydrogen adsorption and absorption study with ultrathin Pd overlayers on Au(111) and Au(100) Baldauf, M.; Kolb, D. M. Electrochimica Acta, Vol. 38, Issue 15 https://doi.org/10.1016/0013-4686(93)80091-d	journal	October 1993
Electrochemical atomic layer epitaxy (ECALE) Gregory, Brian W.; Stickney, John L. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 300, Issue 1-2 https://doi.org/10.1016/0022-0728(91)85415-L	journal	February 1991
Electrochemical atomic layer epitaxy (ECALE) Gregory, Brian W.; Stickney, John L. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 300, Issue 1-2 https://doi.org/10.1016/0022-0728(91)85415-l	journal	February 1991
The influence of carbon monoxide on hydrogen absorption by thin films of palladium Czerwiński, A.; Zamponi, S.; Marassi, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 304, Issue 1-2 https://doi.org/10.1016/0022-0728(91)85505-J	journal	April 1991
The influence of carbon monoxide on hydrogen absorption by thin films of palladium Czerwiński, A.; Zamponi, S.; Marassi, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 304, Issue 1-2 https://doi.org/10.1016/0022-0728(91)85505-j	journal	April 1991
Hydrogen electrosorption in Pd–Pt alloys Grdeń, M.; Piaścik, A.; Koczorowski, Z. Journal of Electroanalytical Chemistry, Vol. 532, Issue 1-2 https://doi.org/10.1016/S0022-0728(02)00750-7	journal	September 2002
The study of hydrogen sorption in palladium limited volume electrodes (Pd-LVE) Czerwiński, Andrzej; Kiersztyn, Iwona; Grdeń, Michał Journal of Electroanalytical Chemistry, Vol. 471, Issue 2 https://doi.org/10.1016/S0022-0728(99)00276-4	journal	August 1999
Metal monolayer deposition by replacement of metal adlayers on electrode surfaces Brankovic, S. R.; Wang, J. X.; Adžić, R. R. Surface Science, Vol. 474, Issue 1-3, p. L173-L179 https://doi.org/10.1016/S0039-6028(00)01103-1	journal	March 2001
Initial stages of Pd deposition on Au(hkl) Part I: Pd on Au(111) Kibler, L. A.; Kleinert, M.; Randler, R. Surface Science, Vol. 443, Issue 1-2 https://doi.org/10.1016/S0039-6028(99)00968-1	journal	December 1999
Pd–Pt alloys: correlation between electronic structure and hydrogenation properties Moysan, I.; Paul-Boncour, V.; Thiébaut, S. Journal of Alloys and Compounds, Vol. 322, Issue 1-2 https://doi.org/10.1016/S0925-8388(01)01202-6	journal	June 2001
Theory meets experiment: Electrocatalysis of hydrogen oxidation/evolution at Pd–Au nanostructures Quaino, P.; Santos, E.; Wolfschmidt, H. Catalysis Today, Vol. 177, Issue 1 https://doi.org/10.1016/j.cattod.2011.05.004	journal	November 2011
Correlations between hydrogen electrosorption properties and composition of Pd-noble metal alloys Łukaszewski, M.; Żurowski, A.; Grdeń, M. Electrochemistry Communications, Vol. 9, Issue 4 https://doi.org/10.1016/j.elecom.2006.10.055	journal	April 2007
Pd deposition onto Au(111) electrodes from sulphuric acid solution Tang, J.; Petri, M.; Kibler, L. A. Electrochimica Acta, Vol. 51, Issue 1 https://doi.org/10.1016/j.electacta.2005.04.009	journal	October 2005
Formation of PbTe nanofilms by electrochemical atomic layer deposition (ALD) Banga, Dhego O.; Vaidyanathan, Raman; Xuehai, Liang Electrochimica Acta, Vol. 53, Issue 23 https://doi.org/10.1016/j.electacta.2008.02.108	journal	October 2008
Growth of Pt by surface limited redox replacement of underpotentially deposited hydrogen Nutariya, J.; Fayette, M.; Dimitrov, N. Electrochimica Acta, Vol. 112 https://doi.org/10.1016/j.electacta.2013.01.052	journal	December 2013
Hydrogen sorption properties of bare and Rh-modified Pd nanofilms grown via surface limited redox replacement reactions Sheridan, Leah B.; Yates, Veronica M.; Benson, David M. Electrochimica Acta, Vol. 128 https://doi.org/10.1016/j.electacta.2013.10.096	journal	May 2014
Kinetics and mechanism of hydrogen electrosorption in palladium-based alloys Łukaszewski, M.; Klimek, K.; Żurowski, A. Solid State Ionics, Vol. 190, Issue 1 https://doi.org/10.1016/j.ssi.2010.03.009	journal	May 2011
Electrochemical properties of palladium adlayers on Pt(100) substrates Álvarez, B.; Berná, A.; Rodes, A. Surface Science, Vol. 573, Issue 1 https://doi.org/10.1016/j.susc.2004.03.074	journal	December 2004
The study of hydrogen sorption in palladium limited volume electrodes (Pd-LVE) Czerwiński, Andrzej; Kiersztyn, Iwona; Grdeń, Michał Journal of Electroanalytical Chemistry, Vol. 492, Issue 2 https://doi.org/10.1016/s0022-0728(00)00291-6	journal	October 2000
Hydrogen electrosorption in Pd–Pt alloys Grdeń, M.; Piaścik, A.; Koczorowski, Z. Journal of Electroanalytical Chemistry, Vol. 532, Issue 1-2 https://doi.org/10.1016/s0022-0728(02)00750-7	journal	September 2002
The study of hydrogen sorption in palladium limited volume electrodes (Pd-LVE) Czerwiński, Andrzej; Kiersztyn, Iwona; Grdeń, Michał Journal of Electroanalytical Chemistry, Vol. 471, Issue 2 https://doi.org/10.1016/s0022-0728(99)00276-4	journal	August 1999
Metal monolayer deposition by replacement of metal adlayers on electrode surfaces Brankovic, S. R.; Wang, J. X.; Adžić, R. R. Surface Science, Vol. 474, Issue 1-3, p. L173-L179 https://doi.org/10.1016/s0039-6028(00)01103-1	journal	March 2001
Initial stages of Pd deposition on Au(hkl) Part I: Pd on Au(111) Kibler, L. A.; Kleinert, M.; Randler, R. Surface Science, Vol. 443, Issue 1-2 https://doi.org/10.1016/s0039-6028(99)00968-1	journal	December 1999
Pd–Pt alloys: correlation between electronic structure and hydrogenation properties Moysan, I.; Paul-Boncour, V.; Thiébaut, S. Journal of Alloys and Compounds, Vol. 322, Issue 1-2 https://doi.org/10.1016/s0925-8388(01)01202-6	journal	June 2001
Surface-Enhanced Raman Scattering on Uniform Platinum-Group Overlayers: Preparation by Redox Replacement of Underpotential-Deposited Metals on Gold Mrozek, Melissa F.; Xie, Yong; Weaver, Michael J. Analytical Chemistry, Vol. 73, Issue 24 https://doi.org/10.1021/ac0106391	journal	December 2001
Electrochemical Applications of in Situ Scanning Probe Microscopy Gewirth, Andrew A.; Niece, Brian K. Chemical Reviews, Vol. 97, Issue 4 https://doi.org/10.1021/cr960067y	journal	June 1997
Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys Greeley, Jeff; Mavrikakis, Manos The Journal of Physical Chemistry B, Vol. 109, Issue 8 https://doi.org/10.1021/jp046540q	journal	March 2005
Platinum Nanofilm Formation by EC-ALE via Redox Replacement of UPD Copper: Studies Using in-Situ Scanning Tunneling Microscopy Kim, Youn-Geun; Kim, Jay Y.; Vairavapandian, Deepa The Journal of Physical Chemistry B, Vol. 110, Issue 36, p. 17998-18006 https://doi.org/10.1021/jp063766f	journal	September 2006
Two-Dimensional Self-Organization of CdS Ultra Thin Films by Confined Electrochemical Atomic Layer Epitaxy Growth Cavallini, Massimiliano; Facchini, Massimo; Albonetti, Cristiano The Journal of Physical Chemistry C, Vol. 111, Issue 3 https://doi.org/10.1021/jp0668908	journal	December 2006
Hydrogen Adsorption, Absorption, and Desorption at Palladium Nanofilms formed on Au(111) by Electrochemical Atomic Layer Deposition (E-ALD): Studies using Voltammetry and In Situ Scanning Tunneling Microscopy Sheridan, Leah B.; Kim, Youn-Geun; Perdue, Brian R. The Journal of Physical Chemistry C, Vol. 117, Issue 30 https://doi.org/10.1021/jp404723a	journal	July 2013
Optical Properties of Ultrathin Electrodeposited CdS Films Probed by Resonance Raman Spectroscopy and Photoluminescence Boone, B. Edward; Shannon, Curtis The Journal of Physical Chemistry, Vol. 100, Issue 22 https://doi.org/10.1021/jp960222c	journal	January 1996
Electrochemical Atomic Layer Epitaxy Deposition of CdS on Ag(111): An Electrochemical and STM Investigation Foresti, M. L.; Pezzatini, G.; Cavallini, M. The Journal of Physical Chemistry B, Vol. 102, Issue 38 https://doi.org/10.1021/jp9811777	journal	September 1998
Formation of Palladium Nanofilms Using Electrochemical Atomic Layer Deposition (E-ALD) with Chloride Complexation Sheridan, Leah B.; Gebregziabiher, Daniel K.; Stickney, John L. Langmuir, Vol. 29, Issue 5 https://doi.org/10.1021/la303816z	journal	January 2013
The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases Bartlett, P. N.; Gollas, B.; Guerin, S. Physical Chemistry Chemical Physics, Vol. 4, Issue 15 https://doi.org/10.1039/b201845d	journal	June 2002
The effect of surface species on the rate of H sorption into nanostructured Pd Bartlett, P. N.; Marwan, J. Physical Chemistry Chemical Physics, Vol. 6, Issue 11 https://doi.org/10.1039/b404028g	journal	January 2004
Palladium in fuel cell catalysis Antolini, Ermete Energy & Environmental Science, Vol. 2, Issue 9 https://doi.org/10.1039/b820837a	journal	January 2009
Electrochemical absorption and oxidation of hydrogen on palladium alloys with platinum, gold and rhodium Łukaszewski, Mariusz; Hubkowska, Katarzyna; Czerwiński, Andrzej Physical Chemistry Chemical Physics, Vol. 12, Issue 43 https://doi.org/10.1039/c0cp00542h	journal	January 2010
Hydrogen absorption by palladium in aqueous solution Flanagan, Ted B.; Lewis, F. A. Transactions of the Faraday Society, Vol. 55 https://doi.org/10.1039/tf9595501400	journal	January 1959
The Hydrogen Economy Crabtree, George W.; Dresselhaus, Mildred S.; Buchanan, Michelle V. Physics Today, Vol. 57, Issue 12 https://doi.org/10.1063/1.1878333	journal	December 2004
The palladium-hydrogen system Owen, E. A.; Jones, John Idwal Proceedings of the Physical Society, Vol. 49, Issue 5 https://doi.org/10.1088/0959-5309/49/5/314	journal	September 1937
Lattice dynamics of metal hydrides Rafizadeh, Hamid A. Physical Review B, Vol. 23, Issue 4 https://doi.org/10.1103/PhysRevB.23.1628	journal	February 1981
Lattice dynamics of metal hydrides Rafizadeh, Hamid A. Physical Review B, Vol. 23, Issue 4 https://doi.org/10.1103/physrevb.23.1628	journal	February 1981
The hydrogen economy Crabtree, George W.; Dresselhaus, Mildred S.; V. Buchanan, And Michelle IEEE Engineering Management Review, Vol. 34, Issue 4 https://doi.org/10.1109/emr.2006.261397	journal	January 2006
Hydrogen Sensors and Switches from Electrodeposited Palladium Mesowire Arrays Favier, Frederic; Walter, Erich C.; Zach, Michael P. Science, Vol. 293, Issue 5538, p. 2227-2231 https://doi.org/10.1126/science.1063189	journal	September 2001
The Palladium-Hydrogen System Flanagan, T. B.; Oates, W. A. Annual Review of Materials Science, Vol. 21, Issue 1 https://doi.org/10.1146/annurev.ms.21.080191.001413	journal	August 1991
Electrodeposition of InAs Wade, Travis L. Electrochemical and Solid-State Letters, Vol. 2, Issue 12 https://doi.org/10.1149/1.1390925	journal	January 1999
Investigation of Hydrogen Adsorption and Absorption in Palladium Thin Films Gabrielli, C.; Grand, P. P.; Lasia, A. Journal of The Electrochemical Society, Vol. 151, Issue 11 https://doi.org/10.1149/1.1797035	journal	January 2004
Investigation of Hydrogen Adsorption and Absorption in Palladium Thin Films Gabrielli, C.; Grand, P. P.; Lasia, A. Journal of The Electrochemical Society, Vol. 151, Issue 11 https://doi.org/10.1149/1.1797037	journal	January 2004
Comparison of Hydrogen Electroadsorption from the Electrolyte with Hydrogen Adsorption from the Gas Phase Jerkiewicz, Gregory Journal of The Electrochemical Society, Vol. 143, Issue 4 https://doi.org/10.1149/1.1836623	journal	January 1996
Epitaxial Growth by Monolayer-Restricted Galvanic Displacement Vasilic, R.; Dimitrov, N. Electrochemical and Solid-State Letters, Vol. 8, Issue 11 https://doi.org/10.1149/1.2063267	journal	January 2005
Electrochemical Atomic Layer Deposition (E-ALD) of Pt Nanofilms Using SLRR Cycles Jayaraju, Nagarajan; Vairavapandian, Deepa; Kim, Youn Guen Journal of The Electrochemical Society, Vol. 159, Issue 10 https://doi.org/10.1149/2.053210jes	journal	January 2012

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