Synthesis and Characterization of Cerium(IV) Metallocenes

Sutton, Andrew; Clark, David Lewis; Scott, Brian Lindley; Gordon, John Cameron

doi:10.3390/inorganics3040589

Synthesis and Characterization of Cerium(IV) Metallocenes

Journal Article · Thu Dec 10 23:00:00 EST 2015 · Inorganics

DOI:https://doi.org/10.3390/inorganics3040589· OSTI ID:1337096

Sutton, Andrew ^[1]; Clark, David Lewis ^[2]; Scott, Brian Lindley ^[3]; Gordon, John Cameron ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Chemistry Div. - Inorganic, Isotope and Actinide Chemistry (C-IIAC)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National Security Education Centre (NSEC)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Materials Synthesis and Integrated Devices (MPA-11)

In this study, by applying a salt metathesis approach between Ce(OtBu₃)₂(NO₃)₂(THF)₂ and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE; LDRD

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1337096

Report Number(s):: LA-UR--15-29339

Journal Information:: Inorganics, Journal Name: Inorganics Journal Issue: 4 Vol. 3; ISSN 2304-6740; ISSN INORCW

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited By (5)

Ceric Cyclopentadienides Bearing Alkoxy, Aryloxy, Chlorido, or Iodido Co-Ligands Schneider, David; Harmgarth, Nicole; Edelmann, Frank T. Chemistry - A European Journal, Vol. 23, Issue 50 https://doi.org/10.1002/chem.201700743	journal	May 2017
Reversible Formation of a Cerium-Bound Terminal Hydride: Ce(C ₅ Me ₄ SiMe ₃ ) ₂ (H)(thf) : Reversible Formation of a Cerium-Bound Terminal Hydride: Ce(C Summerscales, Owen T.; Batista, Enrique R.; Scott, Brian L. European Journal of Inorganic Chemistry, Vol. 2016, Issue 28 https://doi.org/10.1002/ejic.201600737	journal	September 2016
Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes: Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes Schneider, David; Anwander, Reiner European Journal of Inorganic Chemistry, Vol. 2017, Issue 8 https://doi.org/10.1002/ejic.201601404	journal	February 2017
Synthesis and derivatisation of ceric tris(tert-butoxy)siloxides Friedrich, Jochen; Maichle-Mössmer, Cäcilia; Anwander, Reiner Chemical Communications, Vol. 53, Issue 88 https://doi.org/10.1039/c7cc06499c	journal	January 2017
Synthesis and molecular structure of pentadienyl complexes of the rare-earth metals Raeder, Jan; Reiners, Matthias; Baumgarten, Robert Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/c8dt03123a	journal	January 2018

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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crystal structure
cyclopentadiene
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Synthesis and Characterization of Cerium(IV) Metallocenes

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