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Title: Polaron Stabilization by Cooperative Lattice Distortion and Cation Rotations in Hybrid Perovskite Materials

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [4]; ORCiD logo [2];  [4];  [5];  [6];  [6]; ORCiD logo [3];  [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Theoretical Physics adn Chemistry of Materials
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Materials Physics and Application
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Physical Chemistry and Applied Spectroscopy
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
  5. Univ. of Rennes (France). Inst. of Chemical Sciences
  6. National Center for Scientific Research (CNRS), Rennes (France). Optical Functions for Information Technology
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1336128
Alternate Identifier(s):
OSTI ID: 1357115
Report Number(s):
BNL-112594-2016-JA; LA-UR-16-21882
Journal ID: ISSN 1530-6984; R&D Project: 16063; 16058; KC0403020
Grant/Contract Number:  
SC00112704; AC52-06NA25396
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 16; Journal Issue: 6; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; cation rotations; Organic and #8722; inorganic perovskite; photovoltaic; polaron; Center for Functional Nanomaterials; Energy Sciences; Inorganic and Physical Chemistry; Material Science; organic-inorganic perovskite

Citation Formats

Neukirch, Amanda J., Nie, Wanyi, Blancon, Jean-Christophe, Appavoo, Kannatassen, Tsai, Hsinhan, Sfeir, Matthew Y., Katan, Claudine, Pedesseau, Laurent, Even, Jacky, Crochet, Jared J., Gupta, Gautam, Mohite, Aditya D., and Tretiak, Sergei. Polaron Stabilization by Cooperative Lattice Distortion and Cation Rotations in Hybrid Perovskite Materials. United States: N. p., 2016. Web. doi:10.1021/acs.nanolett.6b01218.
Neukirch, Amanda J., Nie, Wanyi, Blancon, Jean-Christophe, Appavoo, Kannatassen, Tsai, Hsinhan, Sfeir, Matthew Y., Katan, Claudine, Pedesseau, Laurent, Even, Jacky, Crochet, Jared J., Gupta, Gautam, Mohite, Aditya D., & Tretiak, Sergei. Polaron Stabilization by Cooperative Lattice Distortion and Cation Rotations in Hybrid Perovskite Materials. United States. doi:10.1021/acs.nanolett.6b01218.
Neukirch, Amanda J., Nie, Wanyi, Blancon, Jean-Christophe, Appavoo, Kannatassen, Tsai, Hsinhan, Sfeir, Matthew Y., Katan, Claudine, Pedesseau, Laurent, Even, Jacky, Crochet, Jared J., Gupta, Gautam, Mohite, Aditya D., and Tretiak, Sergei. Wed . "Polaron Stabilization by Cooperative Lattice Distortion and Cation Rotations in Hybrid Perovskite Materials". United States. doi:10.1021/acs.nanolett.6b01218. https://www.osti.gov/servlets/purl/1336128.
@article{osti_1336128,
title = {Polaron Stabilization by Cooperative Lattice Distortion and Cation Rotations in Hybrid Perovskite Materials},
author = {Neukirch, Amanda J. and Nie, Wanyi and Blancon, Jean-Christophe and Appavoo, Kannatassen and Tsai, Hsinhan and Sfeir, Matthew Y. and Katan, Claudine and Pedesseau, Laurent and Even, Jacky and Crochet, Jared J. and Gupta, Gautam and Mohite, Aditya D. and Tretiak, Sergei},
abstractNote = {},
doi = {10.1021/acs.nanolett.6b01218},
journal = {Nano Letters},
issn = {1530-6984},
number = 6,
volume = 16,
place = {United States},
year = {2016},
month = {5}
}

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Works referencing / citing this record:

Excited-state vibrational dynamics toward the polaron in methylammonium lead iodide perovskite
journal, June 2018

  • Park, Myeongkee; Neukirch, Amanda J.; Reyes-Lillo, Sebastian E.
  • Nature Communications, Vol. 9, Issue 1
  • DOI: 10.1038/s41467-018-04946-7

Relaxor-like and switchable dielectric behavior in a rare noncentrosymmetric 3D iodoargentate hybrid
journal, January 2017

  • Yu, Shan-Shan; Liu, Shao-Xian; Zhu, Yi-Xiao
  • RSC Advances, Vol. 7, Issue 89
  • DOI: 10.1039/c7ra11033b

Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
journal, July 2017


Large polarons in lead halide perovskites
journal, August 2017

  • Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan
  • Science Advances, Vol. 3, Issue 8
  • DOI: 10.1126/sciadv.1701217

Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation
journal, October 2017

  • Miyata, Kiyoshi; Atallah, Timothy L.; Zhu, X. -Y.
  • Science Advances, Vol. 3, Issue 10
  • DOI: 10.1126/sciadv.1701469

Excited-state vibrational dynamics toward the polaron in methylammonium lead iodide perovskite
journal, June 2018

  • Park, Myeongkee; Neukirch, Amanda J.; Reyes-Lillo, Sebastian E.
  • Nature Communications, Vol. 9, Issue 1
  • DOI: 10.1038/s41467-018-04946-7

Relaxor-like and switchable dielectric behavior in a rare noncentrosymmetric 3D iodoargentate hybrid
journal, January 2017

  • Yu, Shan-Shan; Liu, Shao-Xian; Zhu, Yi-Xiao
  • RSC Advances, Vol. 7, Issue 89
  • DOI: 10.1039/c7ra11033b

Influence of π -conjugated cations and halogen substitution on the optoelectronic and excitonic properties of layered hybrid perovskites
journal, October 2018


Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation
text, January 2017

  • Miyata, Kiyoshi; Atallah, Timothy Luke; Zhu, Xiaoyang
  • Columbia University
  • DOI: 10.7916/d8281kg3

Large polarons in lead halide perovskites
text, January 2017

  • Miyata, Kiyoshi; Trinh, M. Tuan; Joshi, Prakriti Pradhan
  • Columbia University
  • DOI: 10.7916/d89s32wc

Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
text, January 2017

  • Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe
  • Columbia University
  • DOI: 10.7916/d8sr0bbc

Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
journal, July 2017


Large polarons in lead halide perovskites
journal, August 2017

  • Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan
  • Science Advances, Vol. 3, Issue 8
  • DOI: 10.1126/sciadv.1701217