Emission lifetimes of a fluorescent dye under shock compression

Liu, Wei-long; Bassett, Will P.; Christensen, James M.; Dlott, Dana D.

doi:10.1021/acs.jpca.5b09695

Emission lifetimes of a fluorescent dye under shock compression

Journal Article · Thu Oct 15 00:00:00 EDT 2015 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory

DOI:https://doi.org/10.1021/acs.jpca.5b09695· OSTI ID:1335495

Liu, Wei-long ^[1]; Bassett, Will P. ^[2]; Christensen, James M. ^[2]; Dlott, Dana D. ^[2]

Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States); Carnegie Institution of Washington
Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)

The emission lifetimes of rhodamine 6G (R6G), were measured under shock compression to 9.1 GPa, with the dual intent of better understanding molecular photophysics in extreme environments and assessing the usefulness of fluorescence lifetime microscopy to measure spatially-dependent pressure distributions in shocked microstructured media. R6G was studied as free dye dissolved in poly-methyl methacrylate (PMMA), or dye encapsulated in silica microparticles suspended in PMMA. Thin layers of these materials in impedance-matched geometries were subjected to planar single-stage shocks created by laser-driven flyer plates. A synchronized femtosecond laser excited the dye at selected times relative to flyer plate arrival and the emission lifetimes were measured with a streak camera. Lifetimes decreased when shocks arrived. The lifetime decrease was attributed to a shock-induced enhancement of R6G nonradiative relaxation. At least part of the relaxation involved shock-enhanced intersystem crossing. For free dye in PMMA, the lifetime decrease during the shock was shown to be a linear function of shock pressure from 0-9 GPa, with a slope of -0.22 ns·GPa^-1. Furthermore, the linear relationship makes it simple to convert lifetimes into pressures. Lifetime measurements in shocked microenvironments may be better than emission intensity measurements, since lifetimes are sensitive to the surrounding environment, but insensitive to intensity variations associated with the motion and optical properties of a dynamically changing structure.

View Accepted Manuscript (DOE)

Research Organization:: Carnegie Institution of Washington, Washington, D.C. (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0002006

OSTI ID:: 1335495

Journal Information:: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 44 Vol. 119; ISSN 1089-5639

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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High-Speed Laser-Launched Flyer Impacts Studied with Ultrafast Photography and Velocimetry Banishev, Alexandr A.; Shaw, William L.; Bassett, Will P. Journal of Dynamic Behavior of Materials, Vol. 2, Issue 2 https://doi.org/10.1007/s40870-016-0058-2	journal	February 2016
Exploration of CdTe quantum dots as mesoscale pressure sensors via time-resolved shock-compression photoluminescent emission spectroscopy Kang, Zhitao; Banishev, Alexandr A.; Lee, Gyuhyon Journal of Applied Physics, Vol. 120, Issue 4 https://doi.org/10.1063/1.4959257	journal	July 2016
Shock compression dynamics under a microscope Dlott, Dana D. SHOCK COMPRESSION OF CONDENSED MATTER - 2015: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/1.4971456	conference	January 2017
Fluorescence temperature sensing based on thermally activated singlet-triplet intersystem crossing in crystalline anthracene Tang, Cheng; Zhu, Xiaojun; Song, Yunfei Journal of Applied Physics, Vol. 126, Issue 5 https://doi.org/10.1063/1.5099292	journal	August 2019

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